Methyl 3-(bromomethyl)benzoate
- Product Name
- Methyl 3-(bromomethyl)benzoate
- CAS No.
- 1129-28-8
- Chemical Name
- Methyl 3-(bromomethyl)benzoate
- Synonyms
- TIMTEC-BB SBB005793;METHYL ALPHA-BROMO-M-TOLUATE;M-CARBOMETHOXYBENZYL BROMIDE;3-CARBOMETHOXYBENZYL BROMIDE;Methyl 3-(bromomethyl)benzoat;METHYL 3-(BROMOMETHYL)BENZOATE;Methyle3-(bromomethyl)benzoate;Methyl 3-aMino-4-fluorobezoate;Methyl m-(Bromomethyl)benzoate;3-(BROMOMETHYL)PHENYLACETICACID
- CBNumber
- CB0331184
- Molecular Formula
- C9H9BrO2
- Formula Weight
- 229.07
- MOL File
- 1129-28-8.mol
Methyl 3-(bromomethyl)benzoate Property
- Melting point:
- 46-47 °C(lit.)
- Boiling point:
- 112-114 °C3 mm Hg(lit.)
- Density
- 1,47 g/cm3
- Flash point:
- 115°C/0.8mm
- storage temp.
- 2-8°C
- form
- Crystals or Crystalline Powder
- color
- White
- Water Solubility
- Slightly soluble in water.
- BRN
- 638569
- InChI
- InChI=1S/C9H9BrO2/c1-12-9(11)8-4-2-3-7(5-8)6-10/h2-5H,6H2,1H3
- InChIKey
- YUHSMQQNPRLEEJ-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=CC(CBr)=C1
- CAS DataBase Reference
- 1129-28-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Methyl 3-bromomethylbenzoate(1129-28-8)
Safety
- Hazard Codes
- C,Xi
- Risk Statements
- 22-34-43
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 2
- F
- 19
- Hazard Note
- Irritant/Corrosive
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29163990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H317May cause an allergic skin reaction
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 648116
- Product name
- Methyl 3-(bromomethyl)benzoate
- Purity
- 97%
- Packaging
- 5g
- Price
- $54.7
- Updated
- 2025/07/31
- Product number
- 648116
- Product name
- Methyl 3-(bromomethyl)benzoate
- Purity
- 97%
- Packaging
- 25g
- Price
- $232.75
- Updated
- 2025/07/31
- Product number
- B2224
- Product name
- Methyl 3-(Bromomethyl)benzoate
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $47
- Updated
- 2025/07/31
- Product number
- B2224
- Product name
- Methyl 3-(Bromomethyl)benzoate
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $142
- Updated
- 2025/07/31
- Product number
- M294015
- Product name
- Methyl 3-(Bromomethyl)benzoate
- Packaging
- 1g
- Price
- $50
- Updated
- 2021/12/16
Methyl 3-(bromomethyl)benzoate Chemical Properties,Usage,Production
Chemical Properties
white crystalline powder or crystals
Uses
Methyl 3-(bromomethyl)benzoate is used in organic synthesis of other chemicals.
Synthesis
99-36-5
1129-28-8
General procedure for the synthesis of methyl 3-bromomethylbenzoate from methyl m-methylbenzoate: 30 mL of carbon tetrachloride (CCl4) and 7.9 g of methyl m-methylbenzoate were added to a dry 100 mL three-necked flask, and after dissolution, 0.23 g of AIBN (azobisisobutyronitrile) and 9.36 g of NBS (N-bromosuccinimide) were sequentially added in three additions (with an interval of about 2-3 hours). The reaction system was heated to 70°C and the color of the reaction solution was observed to change gradually from yellow to orange and finally to white. The reaction was monitored by TLC (eluent: cyclohexane/ethyl acetate = 5:1) until the reaction was almost complete. At the end of the reaction, the resulting succinimide and unreacted N-bromosuccinimide were removed by filtration. The filtrate was rotary evaporated to give 11.5 g of a yellow oily product, methyl 3-bromomethylbenzoate, in 95% yield.
References
[1] Organic and Biomolecular Chemistry, 2003, vol. 1, # 14, p. 2506 - 2511
[2] Patent: CN106146413, 2016, A. Location in patent: Paragraph 0027; 0028
[3] European Journal of Medicinal Chemistry, 2009, vol. 44, # 1, p. 7 - 17
[4] Molecules, 2016, vol. 21, # 12,
[5] Patent: WO2018/169777, 2018, A1. Location in patent: Paragraph 0227
Methyl 3-(bromomethyl)benzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 3-(bromomethyl)benzoate manufacturers
- Product
- Methyl 3-(bromomethyl)benzoate 1129-28-8
- Price
- US $5.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10000
- Release date
- 2024-09-10
- Product
- Methyl 3-(bromomethyl)benzoate 1129-28-8
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 5tons
- Release date
- 2024-12-02
- Product
- Methyl 3-(bromomethyl)benzoate 1129-28-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000MT
- Release date
- 2024-07-17