ChemicalBook > CAS DataBase List > Methyl 5-fluoro-2-methylbenzoate

Methyl 5-fluoro-2-methylbenzoate

Product Name
Methyl 5-fluoro-2-methylbenzoate
CAS No.
175278-29-2
Chemical Name
Methyl 5-fluoro-2-methylbenzoate
Synonyms
METHYL 5-FLUORO-2-METHYLBENZOATE;RARECHEM AL BF 0505;5-fluoro-2-methylbenzoate;METHYL 2-METHYL-5-FLUOROBENZOATE;Benzoic acid, 5-fluoro-2-methyl-, methyl ester
CBNumber
CB0334796
Molecular Formula
C9H9FO2
Formula Weight
168.16
MOL File
175278-29-2.mol
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Methyl 5-fluoro-2-methylbenzoate Property

Boiling point:
90-92°C 15mm
Density 
1.137±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
liquid
color 
Brown
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
Hazard Note 
Irritant
HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
M219378
Product name
Methyl5-Fluoro-2-MethylBenzoate
Packaging
10mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
2723-3-25
Product name
Methyl 5-fluoro-2-methylbenzoate
Purity
97%
Packaging
2g
Price
$10
Updated
2021/12/16
Oakwood
Product number
006817
Product name
Methyl5-fluoro-2-methylbenzoate
Purity
98%
Packaging
1g
Price
$10
Updated
2021/12/16
SynQuest Laboratories
Product number
2723-3-25
Product name
Methyl 5-fluoro-2-methylbenzoate
Purity
97%
Packaging
5G
Price
$20
Updated
2021/12/16
Apolloscientific
Product number
PC5114D
Product name
Methyl5-fluoro-2-methylbenzoate
Packaging
5g
Price
$25
Updated
2021/12/16
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Methyl 5-fluoro-2-methylbenzoate Chemical Properties,Usage,Production

Uses

Methyl 5-fluoro-2-methylbenzoate was used for the preparation of derivatives of piperidinedione.

Synthesis

33184-16-6

74-88-4

175278-29-2

5-Fluoro-2-methylbenzoic acid (2.3 g) was dissolved in tetrahydrofuran (THF, 50 ml). To the solution, iodomethane (0.95 ml) and N,N-diisopropylethylamine (3.2 ml) were added sequentially. The reaction mixture was stirred at room temperature for 2 hours. After completion of the reaction, the mixture was filtered and the filtrate concentrated to give methyl 5-fluoro-2-methylbenzoate (2.3 g; 90% yield).1H-NMR (CDCl3) δ: 2.6 (s, 3H), 3.9 (s, 3H), 7.0-7.2 (m, 2H), 7.6-7.7 (m, 1H).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 17, p. 5286 - 5289
[2] Patent: WO2006/116157, 2006, A2. Location in patent: Page/Page column 83-84

Methyl 5-fluoro-2-methylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 5-fluoro-2-methylbenzoate Suppliers

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View Lastest Price from Methyl 5-fluoro-2-methylbenzoate manufacturers

Career Henan Chemical Co
Product
METHYL 2-METHYL-5-FLUOROBENZOATE 175278-29-2
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-02-13

175278-29-2, Methyl 5-fluoro-2-methylbenzoateRelated Search:

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  • METHYL 2-METHYL-5-FLUOROBENZOATE
  • METHYL 5-FLUORO-2-METHYLBENZOATE
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  • Benzoic acid, 5-fluoro-2-methyl-, methyl ester
  • 175278-29-2