ChemicalBook > CAS DataBase List > 2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE

2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE

Product Name
2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE
CAS No.
198205-95-7
Chemical Name
2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE
Synonyms
AKOS BAR-1774;4-[2-(TRIFLUOROMETHYL)PHENYL]BENZALDEHYDE;2'-trifluoromethyl diphenyl-4-carbaldehyde;2'-Trifluoromethyl-biphenyl-4-carbaldehyde;2'-(TRIFLUOROMETHYL)[1,1'-BIPHENYL]-4-CARBALDEHYDE;2'-(Trifluoromethyl)-[1,1'-biphenyl]-4-carbaldehyde;2'-(Trifluoromethyl)[1,1'-biphenyl]-4-carboxaldehyde;[1,1'-Biphenyl]-4-carboxaldehyde, 2'-(trifluoromethyl)-;2′-Trifluoromethyl-biphenyl-4-carbaldehyde, CAS 198205-95-7
CBNumber
CB0381341
Molecular Formula
C14H9F3O
Formula Weight
250.22
MOL File
198205-95-7.mol
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2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE Property

Boiling point:
338.8±42.0 °C(Predicted)
Density 
1.251±0.06 g/cm3(Predicted)
CAS DataBase Reference
198205-95-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
T797218
Product name
2''-(Trifluoromethyl)-[1,1''-biphenyl]-4-carbaldehyde
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
T797218
Product name
2''-(Trifluoromethyl)-[1,1''-biphenyl]-4-carbaldehyde
Packaging
100mg
Price
$60
Updated
2021/12/16
Usbiological
Product number
291331
Product name
2'-Trifluoromethylbiphenyl-4-carbaldehyde
Packaging
250mg
Price
$340
Updated
2021/12/16
AK Scientific
Product number
W4205
Product name
2'-Trifluoromethyl-biphenyl-4-carbaldehyde
Packaging
25g
Price
$691
Updated
2021/12/16
Matrix Scientific
Product number
071873
Product name
2'-Trifluoromethyl-biphenyl-4-carbaldehyde
Purity
95+%
Packaging
5g
Price
$759
Updated
2021/12/16
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2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE Chemical Properties,Usage,Production

Synthesis

392-83-6

87199-17-5

198205-95-7

A solution of tetrakis(triphenylphosphine)palladium (0.05 g) and sodium carbonate (0.7 g) in water (5 mL) was sequentially added to a stirred solution of o-bromobenzotrifluorotoluene (0.7 g, 2.75 mmol) and 4-formylbenzeneboronic acid (0.5 g, 3.3 mmol) in dioxane (20 mL) under nitrogen protection and at 80 °C. The reaction mixture was stirred at 100±5°C for 6 hours. Upon completion of the reaction, the solvent was removed by evaporation and the residue was diluted to 50 mL with ethyl acetate and washed with deionized water. The solvent was again removed by evaporation and the residue was purified by silica gel column chromatography (FCC) to afford 2'-(trifluoromethyl)-[1,1'-biphenyl]-4-carbaldehyde (0.61 g, 88% yield) as a milky white solid.1H-NMR (CDCl3) δ: 7.49 (d, 1H, J = 7.41 Hz); 7.48 (d, 2H, J = 8.13 Hz); 7.61-7.53 (m, 2H); 7.76 (d, 1H, J = 7.8 Hz); 7.91 (d, 2H, J = 8.34 Hz); 10.07 (s, 1H).

References

[1] Patent: WO2010/42998, 2010, A1. Location in patent: Page/Page column 95

2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE Suppliers

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View Lastest Price from 2'-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
2"-TRIFLUOROMETHYL-BIPHENYL-4-CARBALDEHYDE 198205-95-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11