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ChemicalBook > CAS DataBase List > (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE

Reaction
Product Name
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
CAS No.
250611-13-3
Chemical Name
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
Synonyms
R-SALEN-AL;(R,R)Salen AI;Cyclohexanediaminobisdibutylsalicyliden;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride;(R,R)-N,N'-Bis(3,5-dibutylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) Chloride;(R,R)-N,N'-Bis(3,5-dibutylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) Chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINIUM(III) CHLORIDE;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
CBNumber
CB0401371
Molecular Formula
C36H52AlClN2O2
Formula Weight
607.24
MOL File
250611-13-3.mol
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE Property

Melting point:
250-255 °C(lit.)
form 
Powder
color 
yellow
CAS DataBase Reference
250611-13-3
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
26-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531960
Product name
(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Packaging
1g
Price
$206
Updated
2024/03/01
Strem Chemicals
Product number
13-5800
Product name
(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
Packaging
1g
Price
$186
Updated
2024/03/01
Strem Chemicals
Product number
13-5800
Product name
(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
Packaging
5g
Price
$741
Updated
2024/03/01
TRC
Product number
B426170
Product name
(R,R)-N,N''-Bis(3,5-dibutylsalicylidene)-1,2-cyclohexanediaminoaluminum(III)Chloride
Packaging
2.5g
Price
$385
Updated
2021/12/16
TRC
Product number
B426170
Product name
(R,R)-N,N''-Bis(3,5-dibutylsalicylidene)-1,2-cyclohexanediaminoaluminum(III)Chloride
Packaging
250mg
Price
$85
Updated
2021/12/16
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE Chemical Properties,Usage,Production

Reaction

  1. Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
  2. Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
  3. Catalyst used for the asymmetric hydrocyanation of nitroolefins.
  4. Catalyst used in the reaction of epoxides with heterocumulenes.

Uses

Catalyst for:

  • Asymmetric iodolactonizations
  • Cyanosilylation reactions
  • Phospho-aldol catalysis

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE Suppliers

J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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86-10-82849933
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jkinfo@jkchemical.com
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China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
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021-61259108 18621169109
Fax
86-21-61259102
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market03@meryer.com
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China
ProdList
40228
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62
Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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China
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Chengdu Forest Science and Technology Development Co., Ltd.
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18030648795 18030648795
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028-61777050
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sales@cdforestchem.com
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China
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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
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025-66099280 17798518460
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(1)02557626880
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cfzhang@aikonchem.com
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307593986@qq.com
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Bide Pharmatech Ltd.
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400-164-7117 13681763483
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+86-21-61629029
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product02@bidepharm.com
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China
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Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
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15523000485
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xingcanyaoye@sina.com
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China
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1686
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Sigma-Aldrich
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021-61415566 800-8193336
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orderCN@merckgroup.com
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China
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LaaJoo
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021-60702684 18516024827
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huang.jiayi@sinocompound.com
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View Lastest Price from (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(R,R)-N,N"-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride 250611-13-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE 250611-13-3
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

250611-13-3, (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDERelated Search:


  • (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINIUM(III) CHLORIDE
  • (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
  • Cyclohexanediaminobisdibutylsalicyliden
  • (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]aluminum(III)chloride
  • (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%
  • (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
  • (1R,2R)-(-)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluMinuM(III) chloride,98% (R,R)-Salen-Al
  • (R,R)Salen AI
  • R-SALEN-AL
  • (R,R)-N,N'-Bis(3,5-dibutylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) Chloride
  • (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride
  • (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
  • (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINIUM(III) CHLORIDE
  • (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride,98%
  • (R,R)-N,N'-Bis(3,5-dibutylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) Chloride
  • 250611-13-3
  • C36H52AlClN2O2
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Other Chiral Catalysts
  • Jacobsen Metal