METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE

Product Name: METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE
CAS No.: 34918-57-5
Chemical Name: METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE
Synonyms: METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE;Benzeneacetic acid, 3-bromo-4-hydroxy-, methyl ester
CBNumber: CB13561567
Molecular Formula: C9H9BrO3
Formula Weight: 245.07
MOL File: 34918-57-5.mol

More

Less

METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Property

Boiling point:: 302.2±27.0 °C(Predicted)
Density: 1.562±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 8.23±0.18(Predicted)
Appearance: Colorless to off-white Solid

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

More

Less

N-Bromosuccinimide Price

Ambeed

Product number: A213006
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 100mg
Price: $30
Updated: 2021/12/16

Ambeed

Product number: A213006
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 250mg
Price: $40
Updated: 2021/12/16

Ambeed

Product number: A213006
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 1g
Price: $98
Updated: 2021/12/16

Ambeed

Product number: A213006
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 5g
Price: $327
Updated: 2021/12/16

Chemenu

Product number: CM252396
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 1g
Price: $385
Updated: 2021/12/16

More

Less

METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Chemical Properties,Usage,Production

Synthesis

67-56-1

38692-80-7

34918-57-5

Step 1: Synthesis of methyl 2-(3-bromo-4-hydroxyphenyl)acetate 3-Bromo-4-hydroxyphenylacetic acid (0.3 g, 1.3 mmol, 1.0 equiv) and concentrated H2SO4 (2.77 μL, 0.05 mmol, 0.04 equiv) were dissolved in methanol (10 mL). The reaction mixture was stirred for 1 h at room temperature. Upon completion of the reaction, the reaction was quenched with NaOH solution and subsequently extracted with ethyl acetate (EtOAc). The organic layers were combined, dried with anhydrous Na2SO4 and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: hexane/EtOAc = 5:1) to afford the target compound methyl 2-(3-bromo-4-hydroxyphenyl)acetate (0.2 g, 63% yield).LCMS m/z 245.0 [M + 1]+.

References

[1] Patent: WO2004/62661, 2004, A1. Location in patent: Page/Page column 28
[2] Patent: WO2010/138901, 2010, A1. Location in patent: Page/Page column 155
[3] Yakugaku Zasshi, 1933, vol. 53, p. 557,563; dtsch. Ref. S. 92
[4] Chem.Abstr., 1933, p. 4223
[5] Patent: WO2004/50637, 2004, A2. Location in patent: Page 74

METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Suppliers

China 25 India 1 United States 3 Global 29

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 42446
Advantage: 60

Shanghai Na Qian Chemical Technology Co. Ltd.

Tel: 13598610367
Fax: QQ:2468833170
Email: 2841375912@qq.com
Country: China
ProdList: 2786
Advantage: 52

DebyeTec.com Inc.

Tel: 18-086626237 18086626237
Fax: qq:2693528373
Email: 2693528373@qq.com
Country: China
ProdList: 2973
Advantage: 56

Shanghai SuperLan Chemcial Technique Centre

Tel: 0-2022843681 15618226720
Fax: +86-21-51601218
Email: chaolaichem@foxmail.com
Country: China
ProdList: 12476
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Dalian lichuang Chemical Co., Ltd

Tel: 0411-0411-00000000 13644282108
Fax: -
Email: 3500508746@qq.com
Country: China
ProdList: 2896
Advantage: 55

Rhawn Reagent

Tel: 400-400-1332688 18019345275
Fax: 400-133-2688
Email: amy@rhawn.cn
Country: China
ProdList: 14948
Advantage: 58

Jinan Liheng Biotechnology Co., Ltd.

Tel: 0531-18763987518 18763987518
Email: levi@lihengpharm.com
Country: China
ProdList: 1797
Advantage: 58

Shanghai Union Medical Technology Co. Ltd.

Tel: 13120563767
Fax: 15669989863
Email: chemchen925@outlook.com
Country: China
ProdList: 987
Advantage: 58

Henan Lien Chemical Products Co., Ltd.

Tel: 03716091-9097 13383857418
Fax: 03716091-9097
Email: 1520689222@qq.com
Country: China
ProdList: 4862
Advantage: 58

CR Corporation Limited

Tel: +8613062833949
Email: fred.wen@crcorporation.cn
Country: China
ProdList: 8645
Advantage: 58

Shanghai Kaiwei Chemical Technology Co., Ltd.

Tel: 021-58461859 15821823057
Email: service@aiviche.com
Country: China
ProdList: 49312
Advantage: 58

Shanghai Fine Biotech Co.，Ltd

Tel: 18717800556
Email: sales@finebiotech.com
Country: China
ProdList: 2182
Advantage: 58

Energy Chemical

Tel: 021-58432009 400-005-6266
Fax: 021-58436166
Email: marketing@energy-chemical.com
Country: China
ProdList: 44918
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39653
Advantage: 58

Jiangsu Yaoheng Pharmaceutical Technology Co., Ltd.

Tel: 13524761129
Email: 2183470029@qq.com
Country: China
ProdList: 864
Advantage: 58

Shandong Mingde Biotechnology Co., Ltd

Tel: 15553348166
Email: m15553348166@163.com
Country: China
ProdList: 9967
Advantage: 58

Beijing Qinling Pharmaceutical Co., Ltd.

Tel: 010-61241352 18901327973
Email: 834537306@qq.com
Country: China
ProdList: 5860
Advantage: 58

Heze Bona Medical Technology Co., LTD

Tel: 18615487702
Email: 614989876@qq.com
Country: China
ProdList: 3000
Advantage: 58

Shanghai Haohong Scientific Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 39845
Advantage: 58

Beijing Solarbio Science & Tecnology Co., Ltd.

Tel: 010-50973130 17801761073
Email: Gsiyu@solarbio.com
Country: China
ProdList: 50464
Advantage: 58

Xi 'an fanta biotechnology co., LTD

Tel: 19929974101 //1144079830; 19929974101
Fax: QQ:1144079830
Email: 1144079830@qq.com
Country: China
ProdList: 975
Advantage: 58

Jiangsu Aikon Biopharmaceutical R&D Co.,Ltd

Tel: 025-58851090 17714375163
Email: 2881759498@qq.com
Country: China
ProdList: 13011
Advantage: 58

Shandong Liteng Biotechnology Co. , Ltd.

Tel: +86-18663721413 +86-15552573001
Email: rosy@litengpharm.com
Country: China
ProdList: 3283
Advantage: 58

Hangzhou MolCore BioPharmatech Co.,Ltd.

Tel: +86-057181025280; +8617767106207
Fax: 0571-85806285
Email: sales@molcore.com
Country: China
ProdList: 49734
Advantage: 58

34918-57-5, METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATERelated Search:

METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE

Benzeneacetic acid, 3-bromo-4-hydroxy-, methyl ester

34918-57-5