4-(4-NITROPHENYL)MORPHOLINE
- Product Name
- 4-(4-NITROPHENYL)MORPHOLINE
- CAS No.
- 10389-51-2
- Chemical Name
- 4-(4-NITROPHENYL)MORPHOLINE
- Synonyms
- AURORA 1260;BUTTPARK 97\12-12;TIMTEC-BB SBB006371;p-Morpholinonitrobenzene;4-MORPHOLINO NITRO BENZENE;4-Morpholinyl nitrobenzene;4-Morpholino-1-nitrobenzene;4-(P-NITROPHENYL)MORPHOLINE;4-(4-NITROPHENYL)MORPHOLINE;4-(p-nitrophenyl)-morpholin
- CBNumber
- CB2178277
- Molecular Formula
- C10H12N2O3
- Formula Weight
- 208.21
- MOL File
- 10389-51-2.mol
4-(4-NITROPHENYL)MORPHOLINE Property
- Melting point:
- 152 °C
- Boiling point:
- 386.2±37.0 °C(Predicted)
- Density
- 1.265±0.06 g/cm3(Predicted)
- RTECS
- QE7405000
- storage temp.
- Storage temp. 2-8°C
- solubility
- soluble in Dimethylformamide
- form
- powder to crystal
- pka
- 0.81±0.40(Predicted)
- color
- Light yellow to Yellow to Orange
- λmax
- 375nm(Dioxane)(lit.)
- InChI
- InChI=1S/C10H12N2O3/c13-12(14)10-3-1-9(2-4-10)11-5-7-15-8-6-11/h1-4H,5-8H2
- InChIKey
- IAJDSUYFELYZCS-UHFFFAOYSA-N
- SMILES
- N1(C2=CC=C([N+]([O-])=O)C=C2)CCOCC1
- CAS DataBase Reference
- 10389-51-2(CAS DataBase Reference)
- EPA Substance Registry System
- Morpholine, 4-(4-nitrophenyl)- (10389-51-2)
Safety
- Risk Statements
- 40-42/43-63
- Safety Statements
- 26-36
- RIDADR
- 1662
- TSCA
- Yes
- HS Code
- 2934999090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- S447625
- Product name
- 4-(4-NITROPHENYL)MORPHOLINE
- Purity
- Aldrich<sup>CPR</sup>
- Packaging
- 1 unit
- Price
- $185
- Updated
- 2025/07/31
- Product number
- S447625
- Product name
- 4-(4-NITROPHENYL)MORPHOLINE
- Purity
- Aldrich
- Packaging
- 1g
- Price
- $179
- Updated
- 2024/03/01
- Product number
- N1124
- Product name
- 4-(4-Nitrophenyl)morpholine
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $22
- Updated
- 2025/07/31
- Product number
- N1124
- Product name
- 4-(4-Nitrophenyl)morpholine
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $62
- Updated
- 2025/07/31
- Product number
- N926080
- Product name
- 4-(4-Nitrophenyl)morpholine
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
4-(4-NITROPHENYL)MORPHOLINE Chemical Properties,Usage,Production
Synthesis Reference(s)
Synthesis, p. 1145, 1990 DOI: 10.1055/s-1990-27118
Synthesis
110-91-8
636-98-6
10389-51-2
GENERAL METHODS: Aryl halides (1.0 mmol), morpholine (1 mmol), sodium tert-butoxide (2 mmol) and 0.2 mol% of Pd/Nf-G catalyst were sequentially added to 1 mL of dimethyl sulfoxide (DMSO). The reaction mixture was stirred at 110 °C for 12 h. The reaction process was monitored by gas chromatography (GC). Upon completion of the reaction, the mixture was cooled to room temperature and extracted with ethyl acetate. The catalyst was recovered by simple filtration and subsequently washed with ethanol, dried and stored for subsequent use. The crude product was purified by column chromatography with the eluent being a mixed petroleum ether/ethyl acetate solvent. The recovered catalyst was reused in subsequent recyclability studies. The conversion of the reactants was determined by gas chromatography (GC).
References
[1] Bulletin of the Chemical Society of Japan, 1991, vol. 64, # 1, p. 42 - 49
[2] Applied Organometallic Chemistry, 2013, vol. 27, # 12, p. 704 - 706
[3] RSC Advances, 2014, vol. 4, # 96, p. 53387 - 53396
[4] Tetrahedron Letters, 2015, vol. 56, # 30, p. 4463 - 4467
[5] Tetrahedron Letters, 2016, vol. 57, # 14, p. 1532 - 1536
4-(4-NITROPHENYL)MORPHOLINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-(4-NITROPHENYL)MORPHOLINE manufacturers
- Product
- 4-(4-NITROPHENYL)MORPHOLINE 10389-51-2
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2019-07-01