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ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylate

Product Name
ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylate
CAS No.
16078-63-0
Chemical Name
ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylate
Synonyms
ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylate;ethyl 3-amino-1-phenylpyrazole-4-carboxylate - [AC77927];3-Amino-1-phenyl-1H-pyrazole-4-carboxylic acid ethyl ester;1H-Pyrazole-4-carboxylic acid, 3-amino-1-phenyl-, ethyl ester
CBNumber
CB22595591
Molecular Formula
C12H13N3O2
Formula Weight
231.25
MOL File
16078-63-0.mol
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ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylate Property

Boiling point:
385.1±22.0 °C(Predicted)
Density 
1.25±0.1 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
1.26±0.10(Predicted)
Appearance
White to off-white Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
CHM0392396
Product name
ETHYL-3-AMINO-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLATE
Purity
95.00%
Packaging
5MG
Price
$497.52
Updated
2021/12/16
AK Scientific
Product number
8116AA
Product name
Ethyl3-amino-1-phenyl-1H-pyrazole-4-carboxylate
Packaging
1g
Price
$1197
Updated
2021/12/16
Alichem
Product number
16078630
Product name
Ethyl3-amino-1-phenyl-1H-pyrazole-4-carboxylate
Packaging
1g
Price
$610.98
Updated
2021/12/16
Crysdot
Product number
CD11244638
Product name
Ethyl3-amino-1-phenyl-1H-pyrazole-4-carboxylate
Purity
95%
Packaging
100mg
Price
$87
Updated
2021/12/16
Crysdot
Product number
CD11244638
Product name
Ethyl3-amino-1-phenyl-1H-pyrazole-4-carboxylate
Purity
95%
Packaging
250mg
Price
$139
Updated
2021/12/16
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ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylate Chemical Properties,Usage,Production

Synthesis

100-63-0

94-05-3

16078-63-0

Synthesis of 155-1. Sodium acetate trihydrate (1.40 g, 10.0 mmol) was added to a mixed acetic acid/water (10 mL/2 mL) solution of ethyl ethoxymethylcyanoacetate (869 mg, 5.1 mmol) and phenylhydrazine (500 mg, 4.6 mmol). The reaction mixture was placed in a microwave reactor and stirred at 130 °C for 30 min. After completion of the reaction, the mixture was cooled to room temperature and quenched by adding ice water. The resulting precipitate was collected by filtration and washed with a solvent mixture of ether and petroleum ether (1:1, v/v) to afford ethyl 3-amino-1-phenyl-1H-pyrazole-4-carboxylate (155-1) (1.03 g, 96% yield) as a yellow solid.

References

[1] Patent: WO2017/7756, 2017, A1. Location in patent: Paragraph 207

ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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16078-63-0, ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylateRelated Search:


  • ethyl 3-aMino-1-phenyl-1H-pyrazole-4-carboxylate
  • 3-Amino-1-phenyl-1H-pyrazole-4-carboxylic acid ethyl ester
  • 1H-Pyrazole-4-carboxylic acid, 3-amino-1-phenyl-, ethyl ester
  • ethyl 3-amino-1-phenylpyrazole-4-carboxylate - [AC77927]
  • 16078-63-0