Tri(1-adamantyl)phosphine

Tri(1-adamantyl)phosphine Property

storage temp. 

2-8°C, protect from light, stored under nitrogen

form 

Powder

color 

white to off-white

Sensitive 

air sensitive

InChI

InChI=1S/C30H45P/c1-19-2-21-3-20(1)11-28(10-19,12-21)31(29-13-22-4-23(14-29)6-24(5-22)15-29)30-16-25-7-26(17-30)9-27(8-25)18-30/h19-27H,1-18H2

InChIKey

BQQJSZUDBXOSAG-UHFFFAOYSA-N

SMILES

P(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)C12CC3CC(CC(C3)C1)C2

CAS DataBase Reference

897665-73-5

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

Tri(1-adamantyl)phosphine Chemical Properties,Usage,Production

Reaction

A stable phosphine ligand which can bind to metals such as palladium to be used in Suzuki-Miyaura couplings in making drug intermediates. Dramatic effects in catalysis are also accessible now by using PAd3 as a ligand during Suzuki-Miyaura cross-coupling of chloro(hetero)arenes.