(S)-1-Methylpiperidine-2-carboxylic acid

Product Name: (S)-1-Methylpiperidine-2-carboxylic acid
CAS No.: 41447-18-1
Chemical Name: (S)-1-Methylpiperidine-2-carboxylic acid
Synonyms: N-Methyl-L-pipecolic acid;Pyrazino[2,3-f][1,15]phenanthroline;(S)-1-methyl-2-Piperidinecarboxylic acid;(S)-1-Methylpiperidine-2-carboxylic acid;(2S)-1-methylpiperidine-2-carboxylic acid;2-Piperidinecarboxylic acid, 1-methyl-, (2S)-; (-)-(2S)-1-methylpiperidine-2-carboxylic acid;Piperidinium,2-carboxy-1-methyl-,innersalt,(2S)-;(S)-1-Methylpiperidine-2-carboxylic acid41447-18-1;Cyclohepta[c]pyrazole-3-carboxylicacid,2,4,5,6,7,10-hexahydro-,ethylester
CBNumber: CB32663307
Molecular Formula: C7H13NO2
Formula Weight: 143.18
MOL File: 41447-18-1.mol

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(S)-1-Methylpiperidine-2-carboxylic acid Property

Melting point:: 213-214 °C (decomp)
Boiling point:: 246.1±33.0 °C(Predicted)
Density: 1.103±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 2.48±0.20(Predicted)
Appearance: White to off-white Solid
optical activity: Consistent with structure

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M725973
Product name: (S)-1-Methylpiperidine-2-carboxylicacid
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Activate Scientific

Product number: AS47031
Product name: (S)-1-Methylpiperidine-2-carboxylic acid
Purity: 97% ee
Packaging: 5G
Price: $878
Updated: 2021/12/16

AK Scientific

Product number: 4845CQ
Product name: (S)-1-Methylpiperidine-2-carboxylicacid
Packaging: 5g
Price: $1298
Updated: 2021/12/16

AK Scientific

Product number: 4845CQ
Product name: (S)-1-Methylpiperidine-2-carboxylicacid
Packaging: 10g
Price: $2335
Updated: 2021/12/16

AK Scientific

Product number: CS-W021154
Product name: (S)-1-Methylpiperidine-2-carboxylicacid
Packaging: 1g
Price: $124
Updated: 2021/12/16

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(S)-1-Methylpiperidine-2-carboxylic acid Chemical Properties,Usage,Production

Synthesis

50-00-0

4043-87-2

7730-87-2

To a 25 mL three-necked round-bottomed flask was added piperidine-2-carboxylic acid (975 mg, 7.56 mmol), aqueous formaldehyde (37 wt%, 2.0 mL) and formic acid (2.6 mL). The reaction mixture was heated to reflux with stirring and the reaction temperature was maintained for 5 hours. The reaction process was monitored by liquid chromatography-mass spectrometry (LCMS). After completion of the reaction, the reaction mixture was concentrated under reduced pressure using a rotary evaporator. The concentrated residue was co-milled with 30 mL of ether (Et2O) to afford 1-methylpiperidine-2-carboxylic acid as a white solid (0.5 g, 41% yield).

References

[1] Patent: WO2007/87442, 2007, A2. Location in patent: Page/Page column 101

(S)-1-Methylpiperidine-2-carboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (S)-1-Methylpiperidine-2-carboxylic acid manufacturers

Career Henan Chemical Co

Product: (-)-(2S)-1-methylpiperidine-2-carboxylic acid 41447-18-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: Min98% HPLC
Supply Ability: g/kg/ton
Release date: 2020-02-12

41447-18-1, (S)-1-Methylpiperidine-2-carboxylic acidRelated Search:

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(S)-1-Methylpiperidine-2-carboxylic acid

(S)-1-methyl-2-Piperidinecarboxylic acid

(S)-1-Methylpiperidine-2-carboxylic acid41447-18-1

(-)-(2S)-1-methylpiperidine-2-carboxylic acid

2-Piperidinecarboxylic acid, 1-methyl-, (2S)-

Piperidinium,2-carboxy-1-methyl-,innersalt,(2S)-

Cyclohepta[c]pyrazole-3-carboxylicacid,2,4,5,6,7,10-hexahydro-,ethylester

Pyrazino[2,3-f][1,15]phenanthroline

N-Methyl-L-pipecolic acid

(2S)-1-methylpiperidine-2-carboxylic acid

41447-18-1