(S)-1-Methylpiperidine-2-carboxylic acid
- Product Name
- (S)-1-Methylpiperidine-2-carboxylic acid
- CAS No.
- 41447-18-1
- Chemical Name
- (S)-1-Methylpiperidine-2-carboxylic acid
- Synonyms
- N-Methyl-L-pipecolic acid;Pyrazino[2,3-f][1,15]phenanthroline;(S)-1-methyl-2-Piperidinecarboxylic acid;(S)-1-Methylpiperidine-2-carboxylic acid;(2S)-1-methylpiperidine-2-carboxylic acid;2-Piperidinecarboxylic acid, 1-methyl-, (2S)-; (-)-(2S)-1-methylpiperidine-2-carboxylic acid;Piperidinium,2-carboxy-1-methyl-,innersalt,(2S)-;(S)-1-Methylpiperidine-2-carboxylic acid41447-18-1;Cyclohepta[c]pyrazole-3-carboxylicacid,2,4,5,6,7,10-hexahydro-,ethylester
- CBNumber
- CB32663307
- Molecular Formula
- C7H13NO2
- Formula Weight
- 143.18
- MOL File
- 41447-18-1.mol
(S)-1-Methylpiperidine-2-carboxylic acid Property
- Melting point:
- 213-214 °C (decomp)
- Boiling point:
- 246.1±33.0 °C(Predicted)
- Density
- 1.103±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 2.48±0.20(Predicted)
- Appearance
- White to off-white Solid
- optical activity
- Consistent with structure
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M725973
- Product name
- (S)-1-Methylpiperidine-2-carboxylicacid
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- AS47031
- Product name
- (S)-1-Methylpiperidine-2-carboxylic acid
- Purity
- 97% ee
- Packaging
- 5G
- Price
- $878
- Updated
- 2021/12/16
- Product number
- 4845CQ
- Product name
- (S)-1-Methylpiperidine-2-carboxylicacid
- Packaging
- 5g
- Price
- $1298
- Updated
- 2021/12/16
- Product number
- 4845CQ
- Product name
- (S)-1-Methylpiperidine-2-carboxylicacid
- Packaging
- 10g
- Price
- $2335
- Updated
- 2021/12/16
- Product number
- CS-W021154
- Product name
- (S)-1-Methylpiperidine-2-carboxylicacid
- Packaging
- 1g
- Price
- $124
- Updated
- 2021/12/16
(S)-1-Methylpiperidine-2-carboxylic acid Chemical Properties,Usage,Production
Synthesis
50-00-0
4043-87-2
7730-87-2
To a 25 mL three-necked round-bottomed flask was added piperidine-2-carboxylic acid (975 mg, 7.56 mmol), aqueous formaldehyde (37 wt%, 2.0 mL) and formic acid (2.6 mL). The reaction mixture was heated to reflux with stirring and the reaction temperature was maintained for 5 hours. The reaction process was monitored by liquid chromatography-mass spectrometry (LCMS). After completion of the reaction, the reaction mixture was concentrated under reduced pressure using a rotary evaporator. The concentrated residue was co-milled with 30 mL of ether (Et2O) to afford 1-methylpiperidine-2-carboxylic acid as a white solid (0.5 g, 41% yield).
References
[1] Patent: WO2007/87442, 2007, A2. Location in patent: Page/Page column 101
(S)-1-Methylpiperidine-2-carboxylic acid Preparation Products And Raw materials
Raw materials
Preparation Products
(S)-1-Methylpiperidine-2-carboxylic acid Suppliers
- Tel
- tp@aladdinsci.com
- Country
- United States
- ProdList
- 52923
- Advantage
- 58
- Tel
- --
- Fax
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- sales@combi-blocks.com
- Country
- United States
- ProdList
- 6618
- Advantage
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View Lastest Price from (S)-1-Methylpiperidine-2-carboxylic acid manufacturers
- Product
- (-)-(2S)-1-methylpiperidine-2-carboxylic acid 41447-18-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- Min98% HPLC
- Supply Ability
- g/kg/ton
- Release date
- 2020-02-12