1,1,1-Trifluoro-2,3-epoxypropane

ChemicalBook > CAS DataBase List > 1,1,1-Trifluoro-2,3-epoxypropane

1,1,1-Trifluoro-2,3-epoxypropane

Product Name: 1,1,1-Trifluoro-2,3-epoxypropane
CAS No.: 359-41-1
Chemical Name: 1,1,1-Trifluoro-2,3-epoxypropane
Synonyms: 2-(TRIFLUOROMETHYL)OXIRANE;uoro-2,3-epoxypropane;(Trifluoromethyl)oxirane;3,3,3-trifluoropropene oxide;Oxirane, 2-(trifluoromethyl)-;3,3,3-Trifluoropropane epoxide;1,2-EPOXY-3,3,3-TRIFLUOROPROPA;3,3,3-Tifluoro-1,2-epoxypropane;3,3,3-TRIFLUORO-1,2-EPOXYPROPANE;1,1,1-TRIFLUORO-2,3-EPOXYPROPANE
CBNumber: CB3368693
Molecular Formula: C3H3F3O
Formula Weight: 112.05
MOL File: 359-41-1.mol

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1,1,1-Trifluoro-2,3-epoxypropane Property

Boiling point:: 38 °C
Density: 1,3 g/cm³
refractive index: 1.2997
Flash point:: -40°C
storage temp.: Inert atmosphere,Store in freezer, under -20°C
Specific Gravity: 1.3068
Water Solubility: Not miscible with water.
Sensitive: Moisture Sensitive
BRN: 103730
InChI: InChI=1S/C3H3F3O/c4-3(5,6)2-1-7-2/h2H,1H2
InChIKey: AQZRARFZZMGLHL-UHFFFAOYSA-N
SMILES: O1CC1C(F)(F)F
CAS DataBase Reference: 359-41-1(CAS DataBase Reference)
NIST Chemistry Reference: 3,3,3-Trifluoro-1,2-epoxypropane(359-41-1)

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Safety

Hazard Codes: F,T
Risk Statements: 11-20/21/22-36/37/38
Safety Statements: 16-26-36-36/37-9
RIDADR: 1993
Hazard Note: Flammable/Toxic/Keep Cold
HazardClass: 3
PackingGroup: II
HS Code: 29109000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar

Product number: L09869
Product name: 1,2-Epoxy-3,3,3-trifluoropropane, 98%
Packaging: 1g
Price: $74.65
Updated: 2024/03/01

Alfa Aesar

Product number: L09869
Product name: 1,2-Epoxy-3,3,3-trifluoropropane, 98%
Packaging: 5g
Price: $249.65
Updated: 2024/03/01

TRC

Product number: T898545
Product name: 1,1,1-Trifluoro-2,3-Epoxypropane
Packaging: 500mg
Price: $60
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2109-3-02
Product name: 2-(Trifluoromethyl)oxirane
Purity: 98%
Packaging: 5G
Price: $35
Updated: 2021/12/16

Apolloscientific

Product number: PC7296
Product name: 3,3,3-Trifluoro-1,2-propenoxide
Purity: 98%
Packaging: 5g
Price: $36
Updated: 2021/12/16

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1,1,1-Trifluoro-2,3-epoxypropane Chemical Properties,Usage,Production

Uses

1,2-Epoxy-3,3,3-trifluoropropane is used for the synthesis of trifluorolactic acid. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.

Synthesis

31g of sodium hydroxide (3.28equiv.: 0.781mol)-water 60ml solution under ice-cooling, 50g bromohydrin form obtained in Example 6 (0.238mol) was added and the internal temperature was raised to 61 oC gas generated was collected outside the reactor, condensed in a trap cooled to -78 oC, 1,1,1-trifluoro-2 ,3-epoxypropane was obtained in 84% yield. This was analyzed by 1H-NMR, 19F-NMR. 19F-NMR: (acetone weight):-86.90ppm (3F, d) 1H-NMR: (acetone weight): 2.90ppm (1H, m) 2.96ppm (1H, d d), 3.40ppm (1H, m)

Synthesis

To an autoclave (stainless steel, volume:1L) equipped with a mixing tank and a stirrer, C4F9I which compound (1) flow rate 25mL/min, CF2=CF2 (tetrafluoroethylene) which compound (2) flow rate 0.37g/min, (C2F5COO)2 (10 and half hour life temperature: 31°C) which compound (4) flow rate 0.052 mmol/min were supplied, the mixture was prepared by mixing at stirrer. Temperature in the autoclave was 10°C, residence time of the mixture in the autoclave was 10 minutes. The molar ratio (C4F9I/CF2=CF2)of C4F9I and CF2=CF2 in the mixed solution was 41, the amount of (C2F5COO)2 with respect to C4F9I was 0.034 mol%. Only the mixture from the bottom of the autoclave was withdrawn in the absence of gas phase, the mixture was fed to the bottom of tubular reactor (Tankan-shiki, volume: 0.5L). The mixture was not seperated by gas-liquid separation, the mixture was flow towards the outlet from the inlet of the reaction tube in the tube reactor. The temperature of the reaction tube, and a 70°C, the residence time of the mixture in the tubular reactor was set to 20 minutes. The mixture containing a compound (3) C6F13I was obtained.

1,1,1-Trifluoro-2,3-epoxypropane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1,1,1-Trifluoro-2,3-epoxypropane manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 1,1,1-Trifluoro-2,3-epoxypropane 359-41-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200KG
Release date: 2024-06-05

Henan Aochuang Chemical Co.,Ltd.

Product: 1,1,1-Trifluoro-2,3-epoxypropane 359-41-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-08

Honest Joy Holdings Limited

Product: 1,1,1-Trifluoro-2,3-epoxypropane 359-41-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.7%
Supply Ability: 100 tons
Release date: 2022-02-18

359-41-1, 1,1,1-Trifluoro-2,3-epoxypropaneRelated Search:

POLY(PERFLUOROPROPYLENE OXIDE) Isobutylene oxide Propylene oxide Hexafluoropropylene oxide Epichlorohydrin (S)-3,3,3-Trifluoro-1,2-epoxypropane99% (S)-(-)-3,3,3-TRIFLUORO-1,2-EPOXYPROPANE R-(+)-3,3,3-TRIFLUORO-1,2-EPOXYPROPANE (R)-(+)-1,1,1-Trifluoro-2,3-epoxypropane 1,1,1-Trifluoro-2,3-epoxypropane

3,3,3-Trifluoro-1,2-epoxypropane~2-(Trifluoromethyl)oxirane

1,2-EPOXY-3,3,3-TRIFLUOROPROPANE: TECH., 85%

1,1,1-TRIFLUORO-2,3-EPOXYPROPANE 98+%

1,2-EPOXY-3,3,3-TRIFLUOROPROPANE

1,1,1-TRIFLUORO-2,3-EPOXYPROPANE

2-(TRIFLUOROMETHYL)OXIRANE

3,3,3-TRIFLUORO-1,2-EPOXYPROPANE

3,3,3-Trifluoro-1,2-epoxypropane, tech

1,2-EPOXY-3,3,3-TRIFLUOROPROPANE, 90+%

1,1,1-Trifluoro-2,3-epoxypropane,tech.

3,3,3-Trifluoropropane epoxide

1,2-EPOXY-3,3,3-TRIFLUOROPROPA

3,3,3-Tifluoro-1,2-epoxypropane

2-(Trifluoromethyl)oxirane, 3,3,3-Trifluoro-1,2-epoxypropane

3,3,3-Trifluoro-1,2-propenoxide 98%

2-(Trifluoromethyl)oxirane, 1,2-Epoxy-3,3,3-trifluoropropane

3,3,3-trifluoropropene oxide

(Trifluoromethyl)oxirane

uoro-2,3-epoxypropane

Oxirane, 2-(trifluoromethyl)-

359-41-1

organic chemical

Fluorochemicals