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PENTAERYTHRITOL TRICHLOROHYDRIN

Product Name
PENTAERYTHRITOL TRICHLOROHYDRIN
CAS No.
813-99-0
Chemical Name
PENTAERYTHRITOL TRICHLOROHYDRIN
Synonyms
Pentaerythrityl trichlorohydrin;PENTAERYTHRITOL TRICHLOROHYDRIN;2,2,2-TRIS-(CHLOROMETHYL)-ETHANOL;3-CHLORO-2,2-DICHLOROMETHYLPROPANOL;3-Chloro-2,2-bis(chloromethyl)propan-1-ol;2,2-bis(chloromethyl)-3-chloro-1-propanol;3- CHLORO-2,2-BIS(CHLOROMETHYL)-1-PROPANOL;1-Propanol,3-chloro-2,2-bis(chloromethyl)-;3-Chloro-2,2-bis(chloromethyl) propan-1-ol (Pentaerythrityl trichlorohydrin)
CBNumber
CB3767117
Molecular Formula
C5H9Cl3O
Formula Weight
191.48
MOL File
813-99-0.mol
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PENTAERYTHRITOL TRICHLOROHYDRIN Property

Melting point:
80 °C
Boiling point:
274.39°C (rough estimate)
Density 
1.4096 (rough estimate)
refractive index 
1.5300 (estimate)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
13.83±0.10(Predicted)
InChI
InChI=1S/C5H9Cl3O/c6-1-5(2-7,3-8)4-9/h9H,1-4H2
InChIKey
VRWHPVMGJTYPLS-UHFFFAOYSA-N
SMILES
C(O)C(CCl)(CCl)CCl
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Safety

HS Code 
2905599890
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S551198
Product name
2,2,2-TRIS-(CHLOROMETHYL)-ETHANOL
Purity
Aldrich<sup>CPR</sup>
Packaging
1 unit
Price
$185
Updated
2025/07/31
Sigma-Aldrich
Product number
S551198
Product name
2,2,2-TRIS-(CHLOROMETHYL)-ETHANOL
Purity
AldrichCPR
Packaging
250MG
Price
$179
Updated
2024/03/01
TRC
Product number
C609745
Product name
3-Chloro-2,2-bis(chloromethyl)propan-1-ol
Packaging
2.5g
Price
$75
Updated
2021/12/16
SynQuest Laboratories
Product number
2101-5-02
Product name
3-Chloro-2,2-bis(chloromethyl)propan-1-ol
Packaging
5G
Price
$100
Updated
2021/12/16
AK Scientific
Product number
0075AF
Product name
3-Chloro-2,2-bis(chloromethyl)propan-1-ol
Packaging
5g
Price
$131
Updated
2021/12/16
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PENTAERYTHRITOL TRICHLOROHYDRIN Chemical Properties,Usage,Production

Synthesis

115-77-5

813-99-0

The general procedure for the synthesis of 3-chloro-2,2-dichloromethylpropan-1-ol from pentaerythritol was as follows: pentaerythritol (15 g, 0.11 mol) was dissolved in pyridine (27 ml) and heated to 65 °C. Thionyl chloride (24.7 ml, 0.33 mol) was added slowly and dropwise over a period of 4 h. The temperature of the reaction was controlled to be between 65°C and 95°C. After completion of the reaction, the reaction mixture was continued to be stirred at 50 °C for 18 hours. Subsequently, the reaction solution was heated to 120 °C-130 °C for concentration and then cooled to room temperature. The concentrated reaction solution was slowly poured into ice water (75 ml) and stirred for 30 minutes. The resulting solid product was collected by filtration, washed well with water and dried to give 3-chloro-2,2-bis(chloromethyl)propan-1-ol (15.4 g, 73% yield).

References

[1] Patent: KR101592370, 2016, B1. Location in patent: Paragraph 0204; 0205; 0206; 0207
[2] Australian Journal of Chemistry, 1988, vol. 41, # 12, p. 1953 - 1962
[3] Patent: US2835709, 1955,
[4] Mededelingen van de Koninklijke Vlaamse Academie voor Wetenschappen, Letteren en Schone Kunsten van Belgie, Klasse der Wetenschappen, 1940, vol. 2, # 5, p. 3,16
[5] Patent: US2835709, 1955,

PENTAERYTHRITOL TRICHLOROHYDRIN Preparation Products And Raw materials

Raw materials

Preparation Products

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PENTAERYTHRITOL TRICHLOROHYDRIN Suppliers

China 40 India 1 United Kingdom 1 United States 8 Global 50
Aladdin Scientific
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Synthonix Inc
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Combi-Blocks Inc.
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SynQuest Laboratories, Inc.
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Matrix Scientific
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Advanced Synthesis Technologies
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3B Scientific Corporation
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Parish Chemical Company
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View Lastest Price from PENTAERYTHRITOL TRICHLOROHYDRIN manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
pentaerythritol trichlorohydrin 813-99-0
Price
US $2.00-6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-08-08

813-99-0, PENTAERYTHRITOL TRICHLOROHYDRINRelated Search:

AURORA KA-1416 3-Chloro-2,2-dimethyl-1-propanol 1-CHLORO-2,2-DIMETHYLPROPANE 2,2-Dimethyl-1,3-dichloropropane 3-CHLORO-2,2-DICHLOROMETHYL PROPIONIC ACID PENTAERYTHRITOL TRICHLOROHYDRIN 1,1,1-TRIS(CHLOROMETHYL)ETHANE

  • 3- CHLORO-2,2-BIS(CHLOROMETHYL)-1-PROPANOL
  • 3-CHLORO-2,2-DICHLOROMETHYLPROPANOL
  • PENTAERYTHRITOL TRICHLOROHYDRIN
  • 2,2-bis(chloromethyl)-3-chloro-1-propanol
  • Pentaerythrityl trichlorohydrin
  • 3-Chloro-2,2-bis(chloromethyl)propan-1-ol
  • 1-Propanol,3-chloro-2,2-bis(chloromethyl)-
  • 3-Chloro-2,2-bis(chloromethyl) propan-1-ol (Pentaerythrityl trichlorohydrin)
  • 2,2,2-TRIS-(CHLOROMETHYL)-ETHANOL
  • 813-99-0
  • C5H9Cl3O