Ethyl benzoylformate

ChemicalBook > CAS DataBase List > Ethyl benzoylformate

Ethyl benzoylformate

Product Name: Ethyl benzoylformate
CAS No.: 1603-79-8
Chemical Name: Ethyl benzoylformate
Synonyms: ETHYL 2-OXO-2-PHENYLACETATE;ETHYL PHENYLGLYOXYLATE;Benzeneacetic acid, .alpha.-oxo-, ethyl ester;Ethyl oxophenyla;RARECHEM AL BI 0384;ETHYL BENZOYLFORMATE;PHENYLETHYLGLYOXYLATE;Ethyloxophenylacetate;Ethyl oxophenylacetate;Ethylα-oxobenzeneacetate
CBNumber: CB4299905
Molecular Formula: C10H10O3
Formula Weight: 178.18
MOL File: 1603-79-8.mol

Less

Ethyl benzoylformate Property

Boiling point:: 138-139 °C/18 mmHg (lit.)
Density: 1.122 g/mL at 25 °C (lit.)
refractive index: 1.515-1.517
Flash point:: 113 °C
storage temp.: Store below +30°C.
form: Liquid
Specific Gravity: 1.122
color: Clear colorless to greenish
Water Solubility: Soluble in water 1143 mg/L @ 25°C .
Sensitive: Moisture Sensitive
InChI: InChI=1S/C10H10O3/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7H,2H2,1H3
InChIKey: QKLCQKPAECHXCQ-UHFFFAOYSA-N
SMILES: C1(C=CC=CC=1)C(=O)C(=O)OCC
LogP: 1.974 (est)
CAS DataBase Reference: 1603-79-8(CAS DataBase Reference)
NIST Chemistry Reference: Benzeneacetic acid, «alpha»-oxo-, ethyl ester(1603-79-8)
EPA Substance Registry System: Benzeneacetic acid, .alpha.-oxo-, ethyl ester (1603-79-8)

Less

Safety

Hazard Codes: Xi
Safety Statements: 24/25
WGK Germany: 3
Hazard Note: Moisture Sensitive
TSCA: Yes
HazardClass: IRRITANT
HS Code: 29183000

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H227Combustible liquid

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 258911
Product name: Ethyl benzoylformate
Purity: 95%
Packaging: 5g
Price: $31.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 258911
Product name: Ethyl benzoylformate
Purity: 95%
Packaging: 25g
Price: $71
Updated: 2024/03/01

TCI Chemical

Product number: B0109
Product name: Ethyl Benzoylformate
Purity: >96.0%(GC)
Packaging: 5mL
Price: $29
Updated: 2024/03/01

TCI Chemical

Product number: B0109
Product name: Ethyl Benzoylformate
Purity: >96.0%(GC)
Packaging: 25mL
Price: $76
Updated: 2024/03/01

Alfa Aesar

Product number: B25292
Product name: Ethyl phenylglyoxylate, 98%
Packaging: 5g
Price: $27.65
Updated: 2024/03/01

Less

Ethyl benzoylformate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to greenish liquid

Uses

Ethyl Benzoylformate is a general chemical reagent used in the preparation of diaminoethanediyl bismethylpyridinium salts for designing recyclable organocatalysts.

Application

Ethyl benzoylformate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.

Definition

ChEBI: Ethyl benzoylformate is the ethyl ester of phenylglyoxylic acid. Metabolite observed in cancer metabolism. It has a role as a human metabolite. It derives from a phenylglyoxylic acid.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 918, 1960
The Journal of Organic Chemistry, 50, p. 3573, 1985 DOI: 10.1021/jo00219a025
Tetrahedron Letters, 23, p. 3661, 1982 DOI: 10.1016/S0040-4039(00)88651-7

General Description

Enantioselective hydrogenation of ethyl benzoylformate on Pt/Al₂O₃ modified with dihydrocinchonidine has been studied.

Ethyl benzoylformate Preparation Products And Raw materials

Raw materials

Nitrogen Diethyl oxalate Bromobenzene Diethyl ether Ammonium chloride Magnesium

Preparation Products

Less

Ethyl benzoylformate Suppliers

Americas 1 Belgium 2 CHINA 159 Europe 3 Germany 8 India 9 Japan 2 Switzerland 2 United Kingdom 15 United States 32 USA 1 Global 234

Wuhan yuqing jiaheng pharmaceutical co. LTD

Tel: 027-83855389 13545340383
Fax: 027-83855389
Email: 2586905842@qq.com
Country: China
ProdList: 1246
Advantage: 58

Henan Guangwo New Materials Co., Ltd

Tel: 15225201380 18336995067
Email: 3656693041@qq.com
Country: China
ProdList: 1552
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35906
Advantage: 56

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18217
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12426
Advantage: 60

Adamas Reagent, Ltd.

Tel: 400-6009262 16621234537
Fax: 021-64823266
Email: zhangsn@titansci.com
Country: China
ProdList: 14113
Advantage: 59

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696;
Email: info@hanhongsci.com
Country: China
ProdList: 42982
Advantage: 64

jiliang chemicals

Tel: 21-62165282 15801962796;
Fax: 021 61153784
Email: bidingchem@163.com
Country: China
ProdList: 1165
Advantage: 60

XiaoGan ShenYuan ChemPharm co,ltd

Tel: 0712-0712-2580635 15527768850
Email: 1791901229@qq.com
Country: China
ProdList: 8849
Advantage: 52

Shandong Xiya Chemical Co., Ltd

Tel: 13355009207 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18739
Advantage: 57

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12990
Advantage: 57

BEST-REAGENT

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11726
Advantage: 57

RYSS TECH LTD

Tel: 400-188-0725 +86 21 34310725 13611771617
Fax: +86 21 34311076
Country: China
ProdList: 2002
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14443
Advantage: 57

Maya High Purity Chemicals

Tel: +86 (573) 82222445 (0)18006601000 452520369
Fax: +86 (573) 82222643
Email: sales@maya-r.com
Country: China
ProdList: 11714
Advantage: 57

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9725
Advantage: 55

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9872
Advantage: 52

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17779
Advantage: 75

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19918
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22519
Advantage: 55

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8033
Advantage: 55

TargetMol Chemicals Inc.

Tel: 021-33632979 15002134094
Fax: 021-33632979
Email: marketing@targetmol.com
Country: China
ProdList: 7934
Advantage: 58

Quzhou Juhua Friendship Co., Ltd

Tel: 0570-3066667
Fax: 0570-3063388
Country: China
ProdList: 3933
Advantage: 58

Hubei XinyuanShun Chemical Co., Ltd.

Tel: 13971561712, 13995564702, 027-50664929
Fax: 027-50664927
Email: hbeixys2001@163.com
Country: China
ProdList: 3123
Advantage: 55

Shanghai JONLN Reagent Co., Ltd.

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: 422131432@qq.com
Country: China
ProdList: 9986
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-1647117 15221909166
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41438
Advantage: 60

Zhengzhou HongSheng Pharmaceutical Co., Ltd.

Tel: 1352-6885213 15637198702
Fax: 0371-63709726
Email: xpkchem@163.com
Country: China
ProdList: 3998
Advantage: 58

Wuhan Dahua Pharmaceutical Co., Ltd.

Tel: 027-59262863 13277907145 3091977954
Fax: 027-59420980
Country: China
ProdList: 4951
Advantage: 58

Shanghai Xingui Biotechnology Co., Ltd.

Tel: 17501653713 17501653715
Email: xingui2022@126.com
Country: China
ProdList: 9992
Advantage: 58

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 15878
Advantage: 55

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51471
Advantage: 80

Giant chemicals

Tel: 028-85434334 18108076537
Fax: QQ：245797092
Email: market@gianthx.com
Country: China
ProdList: 4512
Advantage: 56

Zhengzhou Alfachem Co., Ltd.

Tel: 0371-53765687 18937137882
Fax: QQ:2885373884
Email: 2853979813@qq.com
Country: China
ProdList: 7999
Advantage: 55

Shanghai Xilong Biochemical Technology Co., Ltd.

Tel: 021-52907766-8042
Fax: 021-52906523
Country: China
ProdList: 9947
Advantage: 58

Shandong Xiya Chemical Co., Ltd.

Tel: 4009903999 13395398332
Fax: 0539-6365991
Email: sales@xiyashiji.com
Country: China
ProdList: 20810
Advantage: 60

Grader reagent

Tel: 18221735425
Email: sales@xinpingchem.com
Country: China
ProdList: 9951
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131981
Advantage: 58

Taian Jiaye Biotechnology Co.Ltd

Tel: 13127280945
Email: 285424065@qq.com
Country: China
ProdList: 9980
Advantage: 55

Shanghai Orgchem Co.,Ltd.

Tel: +86-21-5877 1921
Fax: +86-21-5877 1925
Email: info@chemofchina.com
Country: China
ProdList: 9661
Advantage: 55

Amatek Scientific Co. Ltd.

Tel: 0512-56316828
Fax: 0512-56316826
Email: info@amateksci.com
Country: China
ProdList: 28822
Advantage: 58

JinJin Le Chemical Co., Ltd

Tel: 10106090
Email: jjlchem2@163.com
Country: China
ProdList: 9986
Advantage: 58

Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
Country: China
ProdList: 9998
Advantage: 58

Shanghai Darui Fine Chemicals Co., Ltd.

Tel: 021-33922791-0 13816046603
Email: 3368239663@qq.com
Country: China
ProdList: 4292
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 021-021-52271985 17721149837
Fax: +86 (21) 52271987
Email: sales@9dingchem.com
Country: China
ProdList: 19806
Advantage: 60

Shanghai BaiShun Biological Technology Co., Ltd

Tel: 021-37581181
Fax: 021-57456066
Email: sales@chem-mall.com
Country: China
ProdList: 10335
Advantage: 58

Less

View Lastest Price from Ethyl benzoylformate manufacturers

Career Henan Chemical Co

Product: Ethyl benzoylformate 1603-79-8
Price: US $2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2018-12-24

1603-79-8, Ethyl benzoylformateRelated Search:

Benzoyl peroxide Ethanol Ethyl acetate Ethylparaben Ethyl cyanoacetate ETHYL ANTHRANILATE Ethyl benzoate Ethyl acrylate Stearoylbenzoylmethane Ethyl benzoylacetate Ethyl pyruvate Ethyl formate ISOXADIFEN-ETHYL Trinexapac-ethyl ETHYL 4-METHOXYBENZOYLFORMATE ETHYL 4-NITROPHENYLGLYOXYLATE ETHYL MESITYLGLYOXYLATE Ethyl phenylacetate

RARECHEM AL BI 0384

PHENYLETHYLGLYOXYLATE

PHENYLGLYOXYLIC ACID ETHYL ESTER

alpha-oxo-benzeneaceticaciethylester

Benzenaceticacid,-oxoethylester

Benzeneaceticacid,α-oxo-,ethylester

Ethyl oxophenylacetate

Ethyloxophenylacetate

Ethylα-oxobenzeneacetate

Glyoxylic acid, phenyl-, ethyl ester

alpha-oxo-benzeneacetic acid ethyl ester

Ethyl oxo(phenyl)acetate 98%

Ethyl phenylglyoxylate, Ethyl benzoylformate

Benzoylformic Acid Ethyl Ester Ethyl Phenylglyoxylate Phenylglyoxylic Acid Ethyl Ester

ETHYL PHENYLGLYOXYLATE FOR SYNTHESIS

Gloyoxylic acid, phenyl-, ethyl ester

2-Oxo-2-phenylacetic acid ethyl ester

2-Phenylglyoxalic acid ethyl ester

Phenyloxoacetic acid ethyl ester

Ethyl benzoylformate,95%

a-Oxo-benzeneacetic acid ethyl ester

Ethyl oxophenyla

Ethyl BenzoylforMate, 97+%

Glyoxylicacid,phenyl-,ethylester

Oxo-phenyl-aceticacidethylester

α-Oxobenzeneaceticacidethylester

ETHYL 2-OXO-2-PHENYLACETATE

ETHYL BENZOYLFORMATE

ETHYL PHENYLGLYOXYLATE

BENZOYLFORMIC ACID ETHYL ESTER

Benzoylformic acid ethyl ester~Ethyl phenylglyoxylate

BENZENACETIC ACID, -OXO ETHYL ESTER 96%

PhenylglyoxylicAcidEthylEther

Benzeneacetic acid, .alpha.-oxo-, ethyl ester

Ethyl benzoylformate 98%

Benzeneacetic acid, α-oxo-, ethyl ester

1603-79-8

C6H5COCO2C2H5

C6H5COCOOC2H5

Carbonyl Compounds

C10 to C11

Building Blocks

Esters

Organic Building Blocks

Pharmaceutical Intermediates

Aromatic Esters

Esters

Phenyls & Phenyl-Het

API intermediates

Phenyls & Phenyl-Het