CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Reactions

Product Name: CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
CAS No.: 92390-26-6
Chemical Name: CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
Synonyms: Cp*RuCl(cod);Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II);Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM;1,5-Cyclooctadiene, ruthenium complex;CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&;Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...;Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;(1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)
CBNumber: CB4405539
Molecular Formula: C18H27ClRu5*
Formula Weight: 379.93
MOL File: 92390-26-6.mol

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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Property

Melting point:: 143-147℃
storage temp.: -20°C
color: brown microxtls
Stability:: store cold
InChI: InChI=1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
InChIKey: JBVMVFXUVNUNNG-ONEVTFJLSA-M
SMILES: [C]1(C)[C](C)[C]([C](C)[C]1C)C.C1CCC=CCCC=1.[Ru]Cl |c:13,17,^1:0,2,4,5,7|

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Safety

Hazard Codes: F
Risk Statements: 20/21/22-14/15
Safety Statements: 22-36/37/39-43
RIDADR: UN 3395
WGK Germany: 3
TSCA: No
HazardClass: 4.3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H261In contact with water releases flammable gas

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 667234
Product name: Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Packaging: 250mg
Price: $124.2
Updated: 2025/07/31

Sigma-Aldrich

Product number: 667234
Product name: Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Packaging: 1g
Price: $332.12
Updated: 2025/07/31

Strem Chemicals

Product number: 44-0113
Product name: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II), 98%
Packaging: 250mg
Price: $121
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0113
Product name: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II), 98%
Packaging: 1g
Price: $362
Updated: 2024/03/01

TRC

Product number: C371378
Product name: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium
Packaging: 250mg
Price: $125
Updated: 2021/12/16

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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Chemical Properties,Usage,Production

Reactions

Catalyst for regio and stereo-specific ring opening via N-O bond cleavage.
Catalyst for transformation of 1,6-enynes and diazoalkanes into alkenylbicyclo[3.1.0]hexane derivatives.
Catalyst for ring closing enyne metathesis.
Catalyst for [2 + 2 + 2] cocyclization of diene-yne, and cyclodimerization of allenynes.
Catalyst for hydrovinylation of ynamides with ethylene.
Catalyst for C–H insertion reactions of carbenes.

Uses

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:

To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

reaction suitability

core: ruthenium
reagent type: catalyst

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products

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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Suppliers

China 124 Germany 2 Switzerland 1 United States 7 Global 134

SIGMA-RBI

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Country: Switzerland
ProdList: 6896
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View Lastest Price from CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM 92390-26-6
Price: US $2.00-6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-07-29

Longyan Tianhua Biological Technology Co., Ltd

Product: CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) 92390-26-6
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-11

Career Henan Chemical Co

Product: CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) 92390-26-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-07-03

92390-26-6, CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)Related Search:

1,5-Cyclooctadiene Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chloro(1,5-cyclooctadiene)rhodium(I) dimer XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) SPhos Pd G2 Chloro(1,5-cyclooctadiene)iridium(I) dimer SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 XPhos Pd G1 Chloro(1,5-cyclooctadiene)methylpalladium(II) 97% Allylpalladium(II) Chloride Dimer CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) cataCXium A-Pd-G2 XantPhos-Pd-G2 Rubidium chloride

(1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride

Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II),98%

Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-

1,5-Cyclooctadiene, ruthenium complex

Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium

Cp*RuCl(cod)

Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)

Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM

Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM

CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium(Ⅱ)

Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)

Ruthenium, chloro[(1,?2,?5,?6-?η)?-?1,?5-?cyclooctadiene]?[(1,?2,?3,?4,?5-?η)?-?1,?2,?3,?4,?5-?pentamethyl-?2,?4-?cyclopentadien-?1-?yl]?-

chloro-[(1E,5Z)-cycloocta-1,5-dien-1-yl]ruthenium 1,2,3,4,5-pentamethylcyclopenta-1,3-diene

Chloro(pentamethylcyclopentadienyl)(1,5-cyclooctadiene)ruthenium(II)

92390-26-6

C18H28ClRu

RuClC8H12C10H15

C18H27ClRu

Ru Catalysts

Catalysis and Inorganic Chemistry

Ru

organometallic complex