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ChemicalBook > CAS DataBase List > (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

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Product Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
CAS No.
185449-81-4
Chemical Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Synonyms
(S)-MorfPhos;97% (S)-MorfPhos;3,4-a'']dinaphthalen-4-yl)morpholine;3,4-a']dinaphthalen-4-yl)Morpholine (S)-MorfPhos;3,4-a']dinaphthalen-4-yl)morpholine,min.97%(S)-MorfPhos;(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine;4-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylmorpholine;(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-yl)morpholine;4-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylmorpholine;Morpholine, 4-(11bS)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-
CBNumber
CB51180997
Molecular Formula
C24H20NO3P
Formula Weight
401.39
MOL File
185449-81-4.mol
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Property

Boiling point:
613.7±65.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
-0.88±0.20(Predicted)
form 
Powder
color 
white
Sensitive 
moisture sensitive
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-1235
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)morpholine, min. 97% (S)-MorfPhos
Packaging
100mg
Price
$41
Updated
2024/03/01
Strem Chemicals
Product number
15-1235
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)morpholine, min. 97% (S)-MorfPhos
Packaging
500mg
Price
$200
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0001357
Product name
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)MORPHOLINE
Purity
95.00%
Packaging
500MG
Price
$814.97
Updated
2021/12/16
AK Scientific
Product number
9700AA
Product name
(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine
Packaging
250mg
Price
$847
Updated
2021/12/16
Matrix Scientific
Product number
095202
Product name
(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-yl)morpholine
Purity
95+%
Packaging
1g
Price
$1311
Updated
2021/12/16
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties,Usage,Production

Reactions

1. Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
2. Ligand used in iridinium-catalyzed asymmetric hydrogenation of 2-methylindole.

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Suppliers

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185449-81-4, (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-aRelated Search:


  • 3,4-a']dinaphthalen-4-yl)morpholine,min.97%(S)-MorfPhos
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  • 185449-81-4
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