ChemicalBook > CAS DataBase List > 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE

1-PHENYL-1-TRIMETHYLSILOXYETHYLENE

Product Name
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
CAS No.
13735-81-4
Chemical Name
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
Synonyms
Trimethyl[(1-phenylvinyl)oxy]silane;DK071;DKFELEX0126;α-(trimethylsiloxy)styrene;à-(trimethylsiloxy)styrene;α-(Trimethylsilyloxy)styrene;ALPHA-(TRIMETHYLSILOXY)STYRENE;1-Phenyl-1-trimethylsiloxyethene;ALPHA-(TRIMETHYLSILYLOXY)STYRENE;(1-phenylvinyl)oxyTrimethylsilane
CBNumber
CB5740196
Molecular Formula
C11H16OSi
Formula Weight
192.33
MOL File
13735-81-4.mol
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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Property

Melting point:
122-123 °C
Boiling point:
88-89 °C/11 mmHg (lit.)
Density 
0.938 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
refractive index 
n20/D 1.502(lit.)
Flash point:
174 °F
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Light orange to Yellow
Specific Gravity
0.938
Water Solubility 
Reacts with water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
1306914
CAS DataBase Reference
13735-81-4(CAS DataBase Reference)
EPA Substance Registry System
Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
10-21
TSCA 
No
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
235040
Product name
1-Phenyl-1-trimethylsiloxyethylene
Purity
98%
Packaging
5g
Price
$125
Updated
2025/07/31
Sigma-Aldrich
Product number
235040
Product name
1-Phenyl-1-trimethylsiloxyethylene
Purity
98%
Packaging
25g
Price
$291.5
Updated
2025/07/31
TCI Chemical
Product number
P1280
Product name
1-Phenyl-1-trimethylsilyloxyethylene
Purity
>95.0%(GC)
Packaging
10mL
Price
$154
Updated
2025/07/31
ChemScene
Product number
CS-0127818
Product name
Trimethyl((1-phenylvinyl)oxy)silane
Packaging
10g
Price
$232
Updated
2021/12/16
AK Scientific
Product number
4953AL
Product name
1-Phenyl-1-trimethylsiloxyethylene
Packaging
5g
Price
$101
Updated
2021/12/16
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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Chemical Properties,Usage,Production

Uses

1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.

Uses

1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:

  • β-amino ketones in water via Mannich-type reaction
  • cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction

General Description

1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.

1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Suppliers

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View Lastest Price from 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
1-Phenyl-1-trimethylsiloxyethylene 98% 13735-81-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE 13735-81-4
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-10

13735-81-4, 1-PHENYL-1-TRIMETHYLSILOXYETHYLENERelated Search:


  • 1-(Trimethylsilyloxy)-1-phenylethene
  • 1-Phenyl-1-trimethylsiloxyethene
  • 1-Phenylvinyl trimethylsilyl ether
  • (1-Phenylethenyloxy)trimethylsilane
  • [(1-Phenylethenyl)oxy]trimethylsilane
  • à-(trimethylsiloxy)styrene
  • α-(trimethylsiloxy)styrene
  • 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE 97%
  • α-(Trimethylsiloxy)styrene, Acetophenone enol trimethylsilyl ether
  • 1-Phenyl-1-(trimethylsilyloxy)ethene
  • Trimethyl(α-methylenebenzyloxy)silane
  • Trimethyl[(1-phenylethenyl)oxy]silane
  • Silane, trimethyl[(1-phenylethenyl)oxy]-
  • Silane, trimethyl[(1-phenylvinyl)oxy]-
  • trimethyl[(1-phenylethenyl)oxy]-silan
  • Trimethyl[(1-phenylvinyl)oxy]silane
  • ALPHA-(TRIMETHYLSILYLOXY)STYRENE
  • ALPHA-(TRIMETHYLSILOXY)STYRENE
  • ACETOPHENONE ENOL TRIMETHYLSILYL ETHER
  • 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
  • 1-PHENYL-1-TRIMETHYLSILYLOXYETHYLENE
  • (1-phenylvinyl)oxyTrimethylsilane
  • α-(Trimethylsilyloxy)styrene
  • 1-Phenyl-1-trimethylsilyloxyethylene&gt
  • Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-
  • trimethyl(1-phenylethenoxy)silane
  • DK071
  • DKFELEX0126
  • 1-phenyl(trimethylsiloxy)ethylene
  • 13735-81-4
  • 133735-81-4
  • C6H5CCH2OSiCH33
  • CH33SiOCC6H5CH2
  • C11H15OSi
  • Oxygen Compounds
  • Building Blocks
  • Silicon Compounds (for Synthesis)
  • Monoalkoxysilanes
  • Si-O Compounds
  • Si (Classes of Silicon Compounds)
  • Enol Ethers
  • Organic Building Blocks
  • Building Blocks
  • Chemical Synthesis
  • Enol Ethers
  • Organic Building Blocks
  • Oxygen Compounds
  • Monoalkoxysilanes
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Si-O Compounds
  • Synthetic Organic Chemistry