Phenanthridine

ChemicalBook > CAS DataBase List > Phenanthridine

Product Name: Phenanthridine
CAS No.: 229-87-8
Chemical Name: Phenanthridine
Synonyms: PHENANTHRIDIN;9-Azaphenanthrene;5-azaphenanthrene;BENZO[C]QUINOLINE;3,4-BENZOQUINOLINE;3,4-Benzoisoquinoline;Phenathridine;PHENANTHRIDINE;6-Phenanthridine;Phenanthridine>
CBNumber: CB6239037
Molecular Formula: C13H9N
Formula Weight: 179.22
MOL File: 229-87-8.mol

Less

Phenanthridine Property

Melting point:: 104-107 °C (lit.)
Boiling point:: 349 °C/769 mmHg (lit.)
Density: 1.1255 (rough estimate)
refractive index: 1.7270 (estimate)
Flash point:: 100 °C
solubility: phosphate buffer: soluble
pka: 5.58(at 20℃)
form: Powder
color: White to beige
Water Solubility: 0.3g/L(20 ºC)
BRN: 120204
CAS DataBase Reference: 229-87-8(CAS DataBase Reference)
EPA Substance Registry System: Phenanthridine (229-87-8)

Less

Safety

Hazard Codes: Xn
Risk Statements: 22-37/38-41
Safety Statements: 26-39
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: SF7928000
HS Code: 29333990
Toxicity: mic-bac-sat 50 mg/plate 50NNAZ7,73,83

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 157384
Product name: Phenanthridine
Purity: 98%
Packaging: 5g
Price: $170
Updated: 2024/03/01

Sigma-Aldrich

Product number: 262692
Product name: Phenanthridine
Purity: ≥99%, purified by sublimation
Packaging: 1g
Price: $105
Updated: 2023/01/07

TCI Chemical

Product number: P1047
Product name: Phenanthridine
Purity: >98.0%(GC)
Packaging: 10g
Price: $194
Updated: 2024/03/01

Sigma-Aldrich

Product number: 77490
Product name: Phenanthridine
Purity: BioReagent, suitable for fluorescence, ≥98.0% (GC)
Packaging: 1g
Price: $85.9
Updated: 2021/12/16

TRC

Product number: P312653
Product name: Phenanthridine
Packaging: 1g
Price: $110
Updated: 2021/12/16

Less

Phenanthridine Chemical Properties,Usage,Production

Chemical Properties

white to beige powder

History

Phenanthridine was first discovered by Ame Pictet and H. J. Ankersmit in 1891 by pyrolysis of the condensed product of benzaldehyde and aniline. Earlier, phenanathridine and related compounds were prepared using mainly Pictect-Hurbert and modified Morgan-Walls type of condensation reactions.

Uses

Phenanthridine is an isomeric compound of acridine. It is a nitrogen heterocycle that is the basis of DNA-binding fluorescent dyes through intercalation. Ethidium bromide and propidium iodide are the examples of such intercalating dyes. It is used as a dye in biological and chemical sensors. It is also used in the study of ecotoxicity and rotational spectroscopic investigations and radio astronomical searches.

Definition

ChEBI: Phenanthridine is an azaarene that is the 9-aza derivative of phenanthrene. The parent of the class of phenanthridines. It is a mancude organic heterotricyclic parent, a polycyclic heteroarene, a member of phenanthridines and an azaarene.

Preparation

Palladium catalyzed synthesis of phenanthridine has been accomplished by Pritchard and coworkers from imidoyl selenides. This was the first report of palladium insertion into the C-Se bond. The palladium insertion into the imidoyl selenides 3.20 followed by intramolecular cyclization and subsequent aromatization via the elimination of HSePh lead to the formation of substituted phenanthridines 3.21.

Pd-catalysed synthesis of phenanathridine

Synthesis Reference(s)

Journal of the American Chemical Society, 74, p. 6295, 1952 DOI: 10.1021/ja01144a521
Journal of Heterocyclic Chemistry, 26, p. 865, 1989 DOI: 10.1002/jhet.5570260366
Tetrahedron Letters, 29, p. 5463, 1988 DOI: 10.1016/S0040-4039(00)80787-X

General Description

Phenanthridine appears as crystalline needles. Mutagenic.

Air & Water Reactions

Sparingly soluble in water.

Reactivity Profile

PHENANTHRIDINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Fire Hazard

Flash point data are not available for PHENANTHRIDINE, but is probably combustible.

Safety Profile

Mutation data reported. When heated to decomposition it emits toxic vapors of NOx.

Phenanthridine Preparation Products And Raw materials

Raw materials

Preparation Products

Less

Phenanthridine Suppliers

Americas 1 Belgium 1 Canada 1 China 49 Europe 1 Germany 5 India 3 Japan 2 Norway 1 South Korea 1 Switzerland 3 The Netherlands 1 United Kingdom 9 United States 14 Global 92

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94837
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40240
Advantage: 62

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44700
Advantage: 61

Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
Country: China
ProdList: 9816
Advantage: 59

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12990
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14443
Advantage: 57

Maya High Purity Chemicals

Tel: +86 (573) 82222445 (0)18006601000 452520369
Fax: +86 (573) 82222643
Email: sales@maya-r.com
Country: China
ProdList: 11714
Advantage: 57

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17779
Advantage: 75

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6139
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22519
Advantage: 55

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51471
Advantage: 80

ATK CHEMICAL COMPANY LIMITED

Tel: 3429815786 13301662590
Fax: +86-21-51619052
Email: sales@atkchemical.com
Country: China
ProdList: 10004
Advantage: 55

Shandong Xiya Chemical Co., Ltd.

Tel: 4009903999 13395398332
Fax: 0539-6365991
Email: sales@xiyashiji.com
Country: China
ProdList: 20810
Advantage: 60

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131980
Advantage: 58

Guangzhou Jhd Chemical Reagent Co., Ltd.

Tel: 020-84383047
Fax: 020-84380294
Email: sales@jhd.com.cn
Country: China
ProdList: 9190
Advantage: 65

Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
Country: China
ProdList: 10007
Advantage: 58

Sichuan BaiPeng Biotechnology Co., Ltd.

Tel: 028-65791793 18140026355
Fax: QQ568470422
Email: 568470422@qq.com
Country: China
ProdList: 9972
Advantage: 58

Aikon International Limited

Tel: 025-66113011 18112977050
Fax: (5)02557626880
Email: cb6@aikonchem.com
Country: China
ProdList: 15495
Advantage: 58

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400-6387771-6039 18920564737
Email: sales@heowns.com
Country: China
ProdList: 20641
Advantage: 60

Shanghai SPAR pharmaceutical technology co., LTD

Tel: 021000000
Email: admin@jingshipharmatech.com
Country: China
ProdList: 10041
Advantage: 58

Fan De(Beijing) Biotechnology Co., Ltd.

Tel: 15911056312
Email: liming@bio-fount.com
Country: China
ProdList: 9730
Advantage: 58

Zhengzhou Alfa Chemical Co.,Ltd

Tel: +8618530059196
Email: sale04@alfachem.cn
Country: China
ProdList: 12898
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: 571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: CHINA
ProdList: 52861
Advantage: 58

WinWin Chemical CO., Limited

Tel: +86-0577-64498589 +8615325081899
Fax: 0086-577-56994596
Email: sales@win-winchemical.com
Country: China
ProdList: 14146
Advantage: 58

Henan Pusai Chemical Products Co., Ltd.

Tel: 0371-63357898
Fax: 1280786222
Email: 1280786222@qq.com
Country: China
ProdList: 3991
Advantage: 58

career henan chemical co

Tel: +86-0371-86658258 15093356674;
Fax: 0086-371-86658258
Email: factory@coreychem.com
Country: China
ProdList: 29826
Advantage: 58

Fuxin Pharmaceutical

Tel: +86-021-021-50872116 +8613122107989
Email: contact@fuxinpharm.com
Country: China
ProdList: 10297
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 4008210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 55023
Advantage: 58

CHG Opto-Electronic Corporation Limited

Tel: 2537653158 16621191650
Fax: QQ 2537653158
Email: 2537653158@qq.com
Country: China
ProdList: 7321
Advantage: 58

SINO High Goal Chemical Technology Co., Ltd.

Tel: 021-57646680 18306277365
Email: guoxin@chembiobanksh.com
Country: China
ProdList: 2285
Advantage: 58

Shaanxi DIDU pharmaceutical and Chemical Co., Ltd

Tel: 15229059051
Email: 1027@dideu.com
Country: China
ProdList: 9966
Advantage: 58

WEITIXIHAUGONG

Tel: 0371-53370800 18037197114
Email: 2853031799@qq.com
Country: China
ProdList: 10011
Advantage: 58

Changzhou Yanji Biotechnology Co., Ltd.

Tel: 0519-83556355 18015005120
Fax: -
Email: shikewei397@163.com
Country: China
ProdList: 3785
Advantage: 55

Shaoyuan Technology (Shanghai) Co., Ltd.

Tel: 021-50795510 4000665055
Email: sy-c6@accelachem.com
Country: China
ProdList: 9196
Advantage: 58

Shanghai Aladdin Biochemical Technology Co.,Ltd.

Tel: +86-18521732826
Email: market@aladdin-e.com
Country: China
ProdList: 48467
Advantage: 58

ATK CHEMICAL COMPANY LIMITED

Tel: +undefined-21-51877795
Fax: +86 21 5161 9052/ 5187 7796
Email: ivan@atkchemical.com
Country: China
ProdList: 32715
Advantage: 60

Shenzhen Nexconn Pharmatechs Ltd

Tel: +86-755-89396905 +86-15013857715
Email: admin@nexconn.com
Country: China
ProdList: 10246
Advantage: 58

GIHI CHEMICALS CO.,LIMITED

Tel: +8618058761490
Email: info@gihichemicals.com
Country: China
ProdList: 50000
Advantage: 58

PT CHEM GROUP LIMITED

Tel: +86-85511178 +86-85511178
Email: peter68@ptchemgroup.com
Country: China
ProdList: 35451
Advantage: 58

Shaanxi Didu New Materials Co. Ltd

Tel: +86-89586680 +86-13289823923
Email: 1026@dideu.com
Country: China
ProdList: 9020
Advantage: 58

Shanghai Hao Zhun Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: info@zzsrm.com
Country: CHINA
ProdList: 6846
Advantage: 58

Dongguan Biaobiao Experimental Equipment Technology Co., Ltd.

Tel: --
Fax: --
Country: CHINA
ProdList: 6673
Advantage: 58

Shanghai yiji industries Co., Ltd.

Tel: --
Fax: --
Email: yiji01@foxmail.com
Country: China
ProdList: 6294
Advantage: 50

Xiamen Huijia Biological Technology Co., Ltd.

Tel: --
Fax: --
Country: CHINA
ProdList: 6979
Advantage: 58

Xiamen Research Biotechnology Co., Ltd.

Tel: --
Fax: --
Email: 1562893815@qq.com
Country: CHINA
ProdList: 6942
Advantage: 58

Shanghai Hao Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: shxiyuanbio@163.com
Country: CHINA
ProdList: 6921
Advantage: 58

Beijing Yunbang Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: yunbnagbio@163.com
Country: China
ProdList: 6877
Advantage: 50

Less

View Lastest Price from Phenanthridine manufacturers

R&D Scientific Inc.

Product: Phenanthridine 229-87-8
Price: US $2400.00/g
Min. Order: 1g
Purity: 97
Supply Ability: 500 Kg
Release date: 2024-03-19

Career Henan Chemical Co

Product: PHENANTHRIDINE 229-87-8
Price: US $1.80-9.80/KG
Min. Order: 1g
Purity: 90.0%-99.9%
Supply Ability: 800kg
Release date: 2020-03-20

229-87-8, PhenanthridineRelated Search:

FLAVANTHRONE Dimidium bromide Nitidine chloride 3,8-DIAMINO-6-PHENYLPHENANTHRIDINE Macleaya cordata extract SANGUINARINE NITRATE Phenanthridine SANGUINARINE CHLORIDE pyritidium bromide Propidium iodide CHELERYTHRINE CHLORIDE DIMIDIUM BROMIDE MONOHYDRATE Ethidium bromide 6(5H)-Phenanthridone Isometamidium chloride 12,13-Dihydro-1,2-dimethoxy-12-methyl[1,3]benzodioxolo[5,6-c]phenanthridine,12,13-Dihydro-1,2-dimethoxy-12-methyl-[1,3]benzodioxolo[5,6-c]phenanthridine Chelerythrine 3,8-DINITRO-6-PHENYLPHENANTHRIDINE

3,4-Benzoisoquinoline

5-azaphenanthrene

6-Phenanthridine

9-Azaphenanthrene

PHENANTHRIDIN

PHENANTHRIDINE

3,4-BENZOQUINOLINE

BENZO[C]QUINOLINE

Phenanthridine, 98% 1GR

3,4-Benzoquinoline Benzo[c]quinoline

Phenathridine

PHENANTHRIDINE, SUBLIMED, 99+%

PHENANTHRIDINE, FOR FLUORESCENCE

Phenanthridine, 98+%

Phenanthridine&gt

229-87-8

Fluorescent Probes, Labels, Particles and Stains

Detection

Biochemicals and Reagents

BioChemical