ChemicalBook > CAS DataBase List > 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole

1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole

Product Name
1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
CAS No.
69352-04-1
Chemical Name
1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
Synonyms
100170;1-chloro-1,3-dihydro-3,3-dimethyl benz iodoxole;1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole;1,2-Benziodoxole, 1-chloro-1,3-dihydro-3,3-dimethyl-;1-chloro-3,3-dimethyl-1,3-dihydro-1l3-benzo[d][1,2]iodaoxole;1-Chloro-3,3-dimethyl-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole;1-?Chloro-?1,?3-?dihydro-?3,?3-?dimethyl-?1,?2-?benziodioxole
CBNumber
CB62552682
Molecular Formula
C9H10ClIO
Formula Weight
296.53
MOL File
69352-04-1.mol
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1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole Property

Melting point:
143-145 °C(Solv: carbon tetrachloride (56-23-5))
storage temp. 
2-8°C, protect from light
form 
solid
Appearance
Light yellow to green yellow Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CF0001
Product name
1-Chloro-3,3-dimethylbenziodoxole
Packaging
10g
Price
$262
Updated
2025/07/31
TRC
Product number
C365698
Product name
1-​Chloro-​1,​3-​dihydro-​3,​3-​dimethyl-​1,​2-​benziodioxole
Packaging
2.5g
Price
$605
Updated
2021/12/16
Adipogen Life Sciences
Product number
CDX-C0136-M500
Product name
1-Chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole
Purity
≥99%(HPLC)
Packaging
500mg
Price
$329
Updated
2021/12/16
Matrix Scientific
Product number
071221
Product name
1-Chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole
Purity
97%
Packaging
5g
Price
$1035
Updated
2021/12/16
AK Scientific
Product number
8246AE
Product name
1-Chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole
Packaging
5g
Price
$1447
Updated
2021/12/16
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1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole Chemical Properties,Usage,Production

Uses

1-?Chloro-?1,?3-?dihydro-?3,?3-?dimethyl-?1,?2-?benziodioxole is used as a reactant in one-pot preparation of hypervalent iodine(III)-CF3 reagent for the use in electrophilic trifluoromethylation reactions.

Uses

1-Chloro-3,3-dimethylbenziodoxole is a crystalline, air-stable, yellow chloroiodane compound which finds use as a starting material for production of other hypervalent iodine compounds. It can also be used as a mild chlorinating reagent. The compound shows good solubility in polar organic solvents, typically dichloromethane or ethyl acetate.

reaction suitability

reaction type: C-C Bond Formation

1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole Suppliers

China 26 India 1 United States 1 Global 28
Matrix Scientific
Tel
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Fax
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Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80

69352-04-1, 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxoleRelated Search:


  • 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
  • 1,2-Benziodoxole, 1-chloro-1,3-dihydro-3,3-dimethyl-
  • 100170
  • 1-?Chloro-?1,?3-?dihydro-?3,?3-?dimethyl-?1,?2-?benziodioxole
  • 1-chloro-1,3-dihydro-3,3-dimethyl benz iodoxole
  • 1-Chloro-3,3-dimethyl-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole
  • 1-chloro-3,3-dimethyl-1,3-dihydro-1l3-benzo[d][1,2]iodaoxole
  • 69352-04-1