ChemicalBook > CAS DataBase List > Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Reaction- Product Name
- Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
- CAS No.
- 1702744-45-3
- Chemical Name
- Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
- Synonyms
- Nicl(O-Tolyl)(Tmeda);chloro(2-methylphenyl)(N,N,N`,N`-tetramethyl-1,2-ethylenediamine)nickel;Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II);Chloro(2-methylphenyl)(N,N,N'',N''-tetramethyl-1,2-ethylenediamine)nickel(II);CHLORO(2-METHYLPHENYL)(N,N,N',N'-TETRAMETHYL-1,2-ETHYLENEDIAMINE)NICKEL(II),99%(CONTAINSABOUT5%O-CHLOROTOLUENE)NICL(O-TOLYL)(TMEDA);Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 10% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
- CBNumber
- CB63357073
- Molecular Formula
- C13H23ClN2Ni
- Formula Weight
- 301.48152
- MOL File
- 1702744-45-3.mol
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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Property
- form
- Powder
- color
- dark-orange
- Sensitive
- air sensitive
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Safety
- Risk Statements
- 45-42/43
- Safety Statements
- 53-22-36/37/39-45
- TSCA
- No
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H317May cause an allergic skin reaction
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H350May cause cancer
- Precautionary statements
-
P201Obtain special instructions before use.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313IF exposed or concerned: Get medical advice/attention.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 804398
- Product name
- [(TMEDA)Ni(o-tolyl)Cl]
- Purity
- 95%
- Packaging
- 100MG
- Price
- $88.3
- Updated
- 2023/06/20
Strem Chemicals
- Product number
- 28-0165
- Product name
- Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
- Packaging
- 500mg
- Price
- $114
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 28-0165
- Product name
- Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
- Packaging
- 2g
- Price
- $342
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 28-0165
- Product name
- Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
- Packaging
- 10g
- Price
- $1369
- Updated
- 2024/03/01
ChemSupplyAustralia
- Product number
- 300971
- Product name
- N,N,N’,N’-Tetramethylethylenediaminechloro(2-methylphenyl)nickel(II), 97%
- Packaging
- 250mg
- Price
- $60.5
- Updated
- 2021/12/16
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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Chemical Properties,Usage,Production
Reaction
- Air-Stable Nickel precatalyst for cross-coupling
- Precatalyst allowing various ligands to be used (monoand bidendate phosphines, diimines and NHCs)
Uses
Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings.
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Suppliers
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