ChemicalBook > CAS DataBase List > 4-Chloro-3-fluorobenzyl Bromide

4-Chloro-3-fluorobenzyl Bromide

Product Name: 4-Chloro-3-fluorobenzyl Bromide
CAS No.: 206362-80-3
Chemical Name: 4-Chloro-3-fluorobenzyl Bromide
Synonyms: CAS:206362-80-3;4-CHLORO-3-FLUOROBENZYL BROMIDE;4-Chloro-3-fluorobenzylbromide97%;4-Chloro-3-fluorobenzyl Bromide >4-Chloro-3-fluorobenzyl bromide 97%;alpha-Bromo-4-chloro-3-fluorotoluene;1-(Bromomethyl)-4-chloro-3-fluorobenzene;4-(bromomethyl)-1-chloro-2-fluorobenzene;REF DUPL: 4-Chloro-3-fluorobenzyl bromide;Benzene, 4-(bromomethyl)-1-chloro-2-fluoro-
CBNumber: CB6654049
Molecular Formula: C7H5BrClF
Formula Weight: 223.47
MOL File: 206362-80-3.mol

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4-Chloro-3-fluorobenzyl Bromide Property

Melting point:: 30-33℃
Boiling point:: 227.1±25.0 °C(Predicted)
Density: 1.654±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Methanol
form: powder to lump
color: White to Light yellow to Light orange
Sensitive: Lachrymatory
CAS DataBase Reference: 206362-80-3(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: 3261
Hazard Note: Corrosive/Lachrymatory
HazardClass: CORROSIVE
HazardClass: 8
PackingGroup: Ⅱ
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P390Absorb spillage to prevent material damage.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: C2484
Product name: 4-Chloro-3-fluorobenzyl Bromide
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $29
Updated: 2025/07/31

TCI Chemical

Product number: C2484
Product name: 4-Chloro-3-fluorobenzyl Bromide
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $86
Updated: 2025/07/31

TRC

Product number: C584695
Product name: 4-Chloro-3-fluorobenzyl Bromide
Packaging: 250mg
Price: $55
Updated: 2021/12/16

TRC

Product number: C584695
Product name: 4-Chloro-3-fluorobenzyl Bromide
Packaging: 100mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC37294
Product name: 4-Chloro-3-fluorobenzyl bromide
Packaging: 2g
Price: $46
Updated: 2021/12/16

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4-Chloro-3-fluorobenzyl Bromide Chemical Properties,Usage,Production

Chemical Properties

White solid

Synthesis

202925-10-8

206362-80-3

Step 1: Bromine (16.5 g, 0.103 mol) was added dropwise to a solution of triphenylphosphine (27.8 g, 0.103 mol) in dichloromethane (200 mL) at 0°C while stirring. After the dropwise addition was completed, stirring of the reaction mixture was continued for 10 minutes. Subsequently, 4-chloro-3-fluorobenzyl alcohol (15.8 g, 0.098 mol) was added and the reaction mixture was stirred for 30 minutes. Upon completion of the reaction, the reaction was quenched with ethanol and the mixture was poured into saturated sodium bicarbonate solution and extracted with dichloromethane. The organic phases were combined, dried with anhydrous sodium sulfate, filtered and concentrated. Purification by silica gel column chromatography afforded 4-(bromomethyl)-1-chloro-2-fluorobenzene (18.6 g, 85% yield).1H-NMR (400 MHz, CDCl3): δ = 7.27 (t, J = 7.9 Hz, 1H), 7.10 (dd, J = 7.9 Hz, 2.1 Hz, 1H), 7.04-6.99 (m, 1H). 4.32 (s, 2H).

References

[1] Patent: EP2952510, 2015, A1. Location in patent: Paragraph 0185

4-Chloro-3-fluorobenzyl Bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Chloro-3-fluorobenzyl Bromide manufacturers

Career Henan Chemical Co

Product: 4-CHLORO-3-FLUOROBENZYL BROMIDE 206362-80-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98% HPLC
Supply Ability: 10 tons/month
Release date: 2020-01-08

206362-80-3, 4-Chloro-3-fluorobenzyl BromideRelated Search:

5-Chloro-2-fluorobenzyl bromide 2-Fluoro-4-chlorobenzyl bromide 2-Chloro-5-fluorobenzyl bromide 4-CHLORO-2,3,6-TRIFLUOROBENZYL BROMIDE 4-CHLORO-3-FLUOROBENZYL BROMIDE 3-Fluorobenzyl bromide 4-Chlorobenzyl bromide 2,4-DICHLORO-5-FLUOROBENZYL BROMIDE

4-Chloro-3-fluorobenzyl bromide 97%

4-Chloro-3-fluorobenzylbromide97%

4-(bromomethyl)-1-chloro-2-fluorobenzene

REF DUPL: 4-Chloro-3-fluorobenzyl bromide

alpha-Bromo-4-chloro-3-fluorotoluene 1-(Bromomethyl)-4-chloro-3-fluorobenzene

4-(Bromomethyl)-1-chloro-2-fluorobenzene, alpha-Bromo-4-chloro-3-fluorotoluene

4-Chloro-3-fluorobenzyl Bromide &gt

Benzene, 4-(bromomethyl)-1-chloro-2-fluoro-

1-(Bromomethyl)-4-chloro-3-fluorobenzene

alpha-Bromo-4-chloro-3-fluorotoluene

4-CHLORO-3-FLUOROBENZYL BROMIDE

CAS:206362-80-3

206362-80-3

C7H5FClBr