ChemicalBook > CAS DataBase List > 2-BROMO-4-CYANOTHIAZOLE

2-BROMO-4-CYANOTHIAZOLE

Product Name
2-BROMO-4-CYANOTHIAZOLE
CAS No.
848501-90-6
Chemical Name
2-BROMO-4-CYANOTHIAZOLE
Synonyms
2-bromo-1,3-thiazole-4-carbonitrile;2-BROMO-4-CYANOTHIAZOLE;2-bromo-4-thiazolecarbonitrile;4-Thiazolecarbonitrile, 2-broMo-
CBNumber
CB72452776
Molecular Formula
C4HBrN2S
Formula Weight
189.03
MOL File
848501-90-6.mol
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2-BROMO-4-CYANOTHIAZOLE Property

Boiling point:
276.1±13.0 °C(Predicted)
Density 
1.97±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
-3.33±0.10(Predicted)
Appearance
Off-white to light yellow Solid
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Safety

HS Code 
2934100090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B685573
Product name
2-Bromo-4-cyanothiazole
Packaging
100mg
Price
$60
Updated
2021/12/16
Ark Pharm
Product number
P000122417
Product name
2-Bromo-4-cyanothiazole
Purity
95+%
Packaging
1g
Price
$73
Updated
2021/12/16
Matrix Scientific
Product number
072295
Product name
2-Bromo-4-cyanothiazole
Purity
95+%
Packaging
1g
Price
$99
Updated
2021/12/16
Ark Pharm
Product number
P000122417
Product name
2-Bromo-4-cyanothiazole
Purity
95+%
Packaging
100mg
Price
$18
Updated
2021/12/16
Ark Pharm
Product number
P000122417
Product name
2-Bromo-4-cyanothiazole
Purity
95+%
Packaging
250mg
Price
$26
Updated
2021/12/16
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2-BROMO-4-CYANOTHIAZOLE Chemical Properties,Usage,Production

Synthesis

848501-94-0

848501-90-6

The general procedure for synthesizing 2-bromo-4-cyanothiazole using 2-bromothiazole-4-carboxamide as starting material is as follows: General method: after completing the preparation of the amide intermediate (Example A), the state of the reaction vessel is determined according to the boiling point of the amide intermediate. If the boiling point of the amide intermediate at atmospheric pressure is equal to or lower than the set reaction temperature (TB), the reaction vessel is closed; if the boiling point is higher than the TB, the reaction vessel is kept open. Subsequently, stirring is continued at a rate of 600 rpm and the reaction temperature is adjusted to TB. this temperature (TB) is maintained for a continuous period of TD hours until the reaction is nearly complete. Next, the reaction vessel was sealed and connected to a vacuum pump, the vacuum in the reaction vessel was adjusted to 20-50 mbar (depending on the nature of the nitrile product) and the distillate was collected as the nitrile product. The yield of the nitrile product was calculated, and samples were taken for NMR spectroscopy and elemental analysis to characterize the resulting nitrile product. The specific reaction conditions and characterization results are detailed in Tables A-7, A-8, A-9, A-10 and A-11. The characterization results showed that the obtained nitrile product was of very high purity (>99%). In some embodiments of the preparation of the nitrile product, 10 g of phosphorus pentoxide can be selectively added as a catalyst at the initial stage of the reaction.

References

[1] Patent: CN104557357, 2018, B. Location in patent: Paragraph 0150; 0151; 0152; 0162
[2] Patent: WO2011/109799, 2011, A1. Location in patent: Page/Page column 225

2-BROMO-4-CYANOTHIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-4-CYANOTHIAZOLE Suppliers

Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
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View Lastest Price from 2-BROMO-4-CYANOTHIAZOLE manufacturers

Career Henan Chemical Co
Product
2-BROMO-4-CYANOTHIAZOLE 848501-90-6
Price
US $3.00/KG
Min. Order
1KG
Purity
99
Supply Ability
100kg
Release date
2019-07-10