3-PHENOXYBROMOBENZENE
- Product Name
- 3-PHENOXYBROMOBENZENE
- CAS No.
- 6876-00-2
- Chemical Name
- 3-PHENOXYBROMOBENZENE
- Synonyms
- 1-Bromo-3-phenoxybenzene;PBDE 2;BDE No2;NSC 57095;PBDE No. 2;3-PHENOXYBROMOBENZENE;m-Phenoxybromobenzene;m-Bromophenoxybenzene;m-Bromodiphenyl ether;m-Phenoxyphenyl bromide
- CBNumber
- CB7307267
- Molecular Formula
- C12H9BrO
- Formula Weight
- 249.1
- MOL File
- 6876-00-2.mol
3-PHENOXYBROMOBENZENE Property
- Boiling point:
- 200-203℃ (50 Torr)
- Density
- 1.3944 g/cm3 (20℃)
- refractive index
- 1.6076 (589.3 nm 20℃)
- Flash point:
- >110℃
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Sparingly)
- form
- liquid
- color
- Colourless
- EPA Substance Registry System
- PBDE 002 (6876-00-2)
Safety
- Hazard Codes
- Xi,N
- Risk Statements
- 37/38-41-43-51/53
- Safety Statements
- 26-36/37/39-61
- RIDADR
- UN 3077 9 / PGIII
- WGK Germany
- 3
- RTECS
- CY9040554
- Hazard Note
- Irritant
- HS Code
- 2909303890
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H318Causes serious eye damage
H335May cause respiratory irritation
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 728969
- Product name
- 3-Bromodiphenyl ether
- Purity
- 97%
- Packaging
- 1g
- Price
- $34.6
- Updated
- 2025/07/31
- Product number
- B6471
- Product name
- 1-Bromo-3-phenoxybenzene
- Purity
- min. 97.0 %
- Packaging
- 1G
- Price
- $115
- Updated
- 2025/07/31
- Product number
- B6471
- Product name
- 1-Bromo-3-phenoxybenzene
- Purity
- min. 97.0 %
- Packaging
- 5G
- Price
- $345
- Updated
- 2025/07/31
- Product number
- B687225
- Product name
- 1-Bromo-3-phenoxybenzene
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FB153582
- Product name
- 1-Bromo-3-phenoxybenzene
- Packaging
- 2g
- Price
- $100
- Updated
- 2021/12/16
3-PHENOXYBROMOBENZENE Chemical Properties,Usage,Production
Uses
1-Bromo-3-phenoxybenzene is part of a group of compounds called polybrominated diphenyl ethers. 1-Bromo-3-phenoxybenzene, along with other similar compounds, are widely used in industry as brominated flame retardants. Unfortunately, with their release into the environment, they pose significant hazards to the humans and wildlife that live in surrounding areas. 1-Bromo-3-phenoxybenzene is also known to induce toxic effects on the central nervous system, the liver, and kidneys in rats.
Synthesis
108-36-1
108-95-2
6876-00-2
Example 6 Synthesis of 1-bromo-3-phenoxybenzene (A): a mixture of meso-dibromobenzene (3 g, 12.75 mmol), phenol (1 g, 10.6 mmol), copper(I) oxide (152 mg, 1 mmol), and cesium carbonate (3.46 g, 10.6 mmol) was dissolved in 8 mL of N-methylpyrrolidone (NMP). The reaction mixture was microwaved at 195 °C for 20 min. Upon completion of the reaction, the non-homogeneous mixture was filtered through a bed of diatomaceous earth and the residue was washed with ethyl acetate (EtOAc, 1 × 20 mL). The filtrate was diluted with 1N sodium hydroxide solution (200 mL) and subsequently extracted with ethyl acetate (3 × 100 mL). The organic phases were combined, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to give the crude product as a yellow oil. The crude product was purified by column chromatography (100% hexane as eluent) to afford 1-bromo-3-phenoxybenzene as a colorless oil (1.4 g, 53% yield).LCMS m/z 250 (M + 1).
References
[1] Patent: US2005/234042, 2005, A1. Location in patent: Page/Page column 25-26
[2] Bioorganic and Medicinal Chemistry, 2009, vol. 17, # 16, p. 5900 - 5905
[3] Patent: EP1489077, 2004, A1. Location in patent: Page 31
3-PHENOXYBROMOBENZENE Preparation Products And Raw materials
Raw materials
Preparation Products
3-PHENOXYBROMOBENZENE Suppliers
- Tel
- +1(858) 699-3322
- Fax
- +1(858) 876-1948
- marketing@accelachem.com
- Country
- United States
- ProdList
- 6024
- Advantage
- 65
- Tel
- +1-858-6993322
- Fax
- (+1)-858-876-1948
- info@accelachem.com
- Country
- United States
- ProdList
- 21193
- Advantage
- 58
- Tel
- 8485655694
- sales@alchempharmtech.com
- Country
- United States
- ProdList
- 63687
- Advantage
- 58
- Tel
- tp@aladdinsci.com
- Country
- United States
- ProdList
- 57505
- Advantage
- 58
- Tel
- +1-817863-6948 +1-（817）863-6948
- sales@aceschem.com
- Country
- United States
- ProdList
- 19632
- Advantage
- 58
- Tel
- --
- Fax
- --
- info@synthonix.com
- Country
- United States
- ProdList
- 6872
- Advantage
- 58
- Tel
- --
- Fax
- --
- info@bester.nl
- Country
- United States
- ProdList
- 5300
- Advantage
- 76
- Tel
- --
- Fax
- --
- info@synquestlabs.com
- Country
- United States
- ProdList
- 6871
- Advantage
- 62
- Tel
- --
- Fax
- --
- Country
- United States
- ProdList
- 6773
- Advantage
- 87
- Tel
- --
- Fax
- --
- sales@combi-blocks.com
- Country
- United States
- ProdList
- 6618
- Advantage
- 69
- Tel
- --
- Fax
- --
- contact@creative-proteomics.com
- Country
- United States
- ProdList
- 135
- Advantage
- 50
- Tel
- --
- Fax
- --
- sales@waterstonetech.com
- Country
- United States
- ProdList
- 6786
- Advantage
- 30
- Tel
- --
- Fax
- --
- sales@3bsc.com
- Country
- United States
- ProdList
- 6718
- Advantage
- 47