ChemicalBook > CAS DataBase List > 4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN

4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN

Product Name
4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN
CAS No.
88404-25-5
Chemical Name
4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN
Synonyms
4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN;4-(Bromomethyl)-6,7-dimethoxycoumarine;4-Bromomethyl-6,7-dimethoxycoumarin,95%;4-BroMoMethyl-6,7-diMethoxycouMarin 96%;4-Bromomethyl-6,7-dimethoxycoumarin 4-(BROMOMETHYL)-6,7-DIMETHOXYCOUMARIN, 9 7%;4-(Bromomethyl)-6,7-dimethoxy-2H-chromen-2-one;4-(bromomethyl)-6,7-dimethoxy-2-oxo-2H-chromene;4-(Bromomethyl)-6,7-dimethoxy-2H-1-benzopyran-2-one;2H-1-Benzopyran-2-one, 4-(bromomethyl)-6,7-dimethoxy-
CBNumber
CB8200312
Molecular Formula
C12H11BrO4
Formula Weight
299.12
MOL File
88404-25-5.mol
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4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN Property

Melting point:
212-216 °C(lit.)
Density 
1.6176 (rough estimate)
refractive index 
1.4490 (estimate)
storage temp. 
Inert atmosphere,2-8°C
solubility 
Soluble in acetonitrile, dichloromethane, N,N-dimethylformamide, methanol
form 
Powder
color 
Yellow crystals or powder
Water Solubility 
Insoluble in water.
λmax
348 nm (MeOH)
BRN 
4750487
Major Application
Electrostatic imaging process; resists; printed circuit boards; semiconductor devices
Biological Applications
Analyzing bile acid; anticancer agents; identifying bacteria; identifying/measuring lauric acid metabolites; measuring cyclosporine; studying/monitoring early stages of protein folding;treating gastrointestinal diseases; derivatization reagent for carboxylic acids; as a substrate for measuring lauric acid hydroxylase activity
CAS DataBase Reference
88404-25-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,C
Risk Statements 
22-36/37/38
Safety Statements 
26
RIDADR 
1759
WGK Germany 
3
21
Hazard Note 
Corrosive
HazardClass 
8
PackingGroup 
III
HS Code 
29322090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
301450
Product name
4-Bromomethyl-6,7-dimethoxycoumarin
Purity
96%
Packaging
1g
Price
$314
Updated
2024/03/01
TCI Chemical
Product number
A5570
Product name
4-Bromomethyl-6,7-dimethoxycoumarin [for HPLC Labeling]
Purity
>98.0%(HPLC)
Packaging
1g
Price
$417
Updated
2024/03/01
TCI Chemical
Product number
A5570
Product name
4-Bromomethyl-6,7-dimethoxycoumarin [for HPLC Labeling]
Purity
>98.0%(HPLC)
Packaging
100mg
Price
$64
Updated
2024/03/01
Alfa Aesar
Product number
043402
Product name
4-Bromomethyl-6,7-dimethoxycoumarin, 95%
Packaging
0.1g
Price
$32.65
Updated
2024/03/01
Alfa Aesar
Product number
043402
Product name
4-Bromomethyl-6,7-dimethoxycoumarin, 95%
Packaging
2g
Price
$333.65
Updated
2024/03/01
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4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN Chemical Properties,Usage,Production

Chemical Properties

Light Greenish-Yellow Powder

Uses

A fluorescent labeling reagent for the reversed-phase HPLC separation and detection of carboxylic acids

Uses

4-Bromomethyl-6,7-dimethoxycoumarin is used as fluorescent labeling reagent for the reversed-phase HPLC separation and detection of carboxylic acids. It is also used as derivatization reagent: for quantitation of clofibric, bezafibric and fenofibric acids in liver by liquid chromatography, in determination of the concentration of tripeptide glutathione by matrix-assisted laser desorption ionization time-of-flight mass spectrometry and for determination of carboxylic acids in chromatographic detection.

Uses

4-Bromomethyl-6,7-dimethoxycoumarin was used as fluorescent labeling reagent for the reversed-phase HPLC separation and detection of carboxylic acids. It was also used as derivatization reagent:

  • for quantitation of clofibric, bezafibric and fenofibric acids in liver by liquid chromatography
  • in determination of the concentration of tripeptide glutathione by matrix-assisted laser desorption ionization time-of-flight mass spectrometry
  • for determination of carboxylic acids in chromatographic detection

4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from 4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN manufacturers

Dideu Industries Group Limited
Product
4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN 88404-25-5
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-10-29
Shaanxi Dideu Medichem Co. Ltd
Product
4-Bromomethyl-6,7-dimethoxycoumarin 88404-25-5
Price
US $0.01-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50 tons
Release date
2020-04-28
Career Henan Chemical Co
Product
4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN 88404-25-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
KG/T
Release date
2019-12-19

88404-25-5, 4-BROMOMETHYL-6,7-DIMETHOXYCOUMARINRelated Search:


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  • 4-(BROMOMETHYL)-6,7-DIMETHOXYCOUMARIN, 9 7%
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  • 4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN ISO 9001:2015 REACH
  • 88404-25-5
  • C12H11BrO4
  • BioChemical
  • Biochemicals and Reagents
  • Fluorescence Detection (HPLC Labeling Reagents)
  • Carboxyl Group Labeling Reagents for Fluorescence HPLC
  • HPLC Labeling Reagents
  • Other Fluorescent Labels
  • Detection
  • Fluorescent Labels
  • Fluorescent Probes, Labels, Particles and Stains
  • Fluorescent Labels and Indicators
  • Analytical Chemistry
  • Carboxyl Group Labeling Reagents for Fluorescence HPLC
  • Fluorescence Detection (HPLC Labeling Reagents)
  • HPLC Labeling Reagents
  • Fluorescent Labels & Indicators
  • CoumarinsDerivatization Reagents HPLC
  • HalogenatedFluorescent Probes, Labels, Particles and Stains
  • Building Blocks
  • CoumarinsHeterocyclic Building Blocks
  • Fluorescence
  • Fluorescent Labels
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Other Fluorescent Labels