Reaction
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Bis(triphenylphosphine)nickel(II)chloride

Reaction
Product Name
Bis(triphenylphosphine)nickel(II)chloride
CAS No.
14264-16-5
Chemical Name
Bis(triphenylphosphine)nickel(II)chloride
Synonyms
NiCl2(PPh3)2;Bis(triphenylphosphine)nickel dichloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL;phosphine)nickeL;Bis(triphenylphosphine)nick;bis(triphenylphosphine)nickle(II)
CBNumber
CB8433158
Molecular Formula
C36H30Cl2NiP2
Formula Weight
654.17
MOL File
14264-16-5.mol
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Bis(triphenylphosphine)nickel(II)chloride Property

Melting point:
250 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Crystals or Powder
color 
Dark green to dark gray
Water Solubility 
insoluble
Sensitive 
Hygroscopic
Exposure limits
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference
14264-16-5(CAS DataBase Reference)
NIST Chemistry Reference
dichlorobis(triphenylphosphine)nickel(14264-16-5)
EPA Substance Registry System
Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)
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Safety

Hazard Codes 
T
Risk Statements 
45-43-52/53-34-20/21/22
Safety Statements 
53-36/37-45-60-36/37/39-26
RIDADR 
3260
WGK Germany 
3
RTECS 
QR6170000
21
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H350May cause cancer

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
237116
Product name
Bis(triphenylphosphine)nickel(II) dichloride
Purity
synthesis grade
Packaging
10g
Price
$56.8
Updated
2024/03/01
Sigma-Aldrich
Product number
237116
Product name
Bis(triphenylphosphine)nickel(II) dichloride
Purity
synthesis grade
Packaging
50g
Price
$106.8
Updated
2024/03/01
TCI Chemical
Product number
B1571
Product name
Bis(triphenylphosphine)nickel(II) Dichloride
Purity
>96.0%(T)
Packaging
10g
Price
$43
Updated
2024/03/01
TCI Chemical
Product number
B1571
Product name
Bis(triphenylphosphine)nickel(II) Dichloride
Purity
>96.0%(T)
Packaging
100g
Price
$200
Updated
2024/03/01
Alfa Aesar
Product number
013930
Product name
Dichlorobis(triphenylphosphine)nickel(II), 98%
Packaging
10g
Price
$43.65
Updated
2024/03/01
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Bis(triphenylphosphine)nickel(II)chloride Chemical Properties,Usage,Production

Reaction

  1. Catalyst for hydrosilylation of styrene with diphenysilane
  2. Catalyst for carboxylation of various aryl chlorides and other derivatives
  3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
  4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
  5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.

Chemical Properties

dark green to dark grey crystals or powder

Uses

Coordination compund.

Uses

suzuki reaction

Uses

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

Purification Methods

Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]

Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(triphenylphosphine)nickel(II)chloride Suppliers

Zhengzhou Changkuan Technology Co., Ltd
Tel
0371-63769919 18530983798
Fax
0371-55057218
Email
sales5@changkuantech.com
Country
China
ProdList
223
Advantage
55
Wuhan Huahan Dingcheng New Material Technology Co., Ltd
Tel
+86-027-81388558 18963961905
Email
huahandingcheng@sina.com
Country
China
ProdList
97
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2341
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7508
Advantage
55
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View Lastest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers

Hebei Mojin Biotechnology Co., Ltd
Product
Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-23
Shanghai Yunao International Trade Co., Ltd
Product
Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price
US $200.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500t
Release date
2021-09-29
Hebei Guanlang Biotechnology Co., Ltd.
Product
Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2021-10-15

14264-16-5, Bis(triphenylphosphine)nickel(II)chlorideRelated Search:


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