2-BROMOBENZOPHENONE
Application- Product Name
- 2-BROMOBENZOPHENONE
- CAS No.
- 13047-06-8
- Chemical Name
- 2-BROMOBENZOPHENONE
- Synonyms
- o-Bromobenzophenone;2-BROMOBENZOPHENONE;2-BroMobenzophenone 95%;2-Bromobenzophenone >2-Bromophenyl phenyl ketone;Methanone, (2-bromophenyl)phenyl-;(2-Bromo-phenyl)-phenyl-methanone
- CBNumber
- CB8488653
- Molecular Formula
- C13H9BrO
- Formula Weight
- 261.11
- MOL File
- 13047-06-8.mol
2-BROMOBENZOPHENONE Property
- Melting point:
- 42
- Boiling point:
- 345
- Density
- 1.4309 g/mL at 25 °C
- refractive index
- n20/D 1.6254
- Flash point:
- 110 °C
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Toluene
- form
- powder to lump
- color
- White to Yellow to Orange
- InChI
- InChI=1S/C13H9BrO/c14-12-9-5-4-8-11(12)13(15)10-6-2-1-3-7-10/h1-9H
- InChIKey
- ABEVIHIQUUXDMS-UHFFFAOYSA-N
- SMILES
- C(C1=CC=CC=C1Br)(C1=CC=CC=C1)=O
- CAS DataBase Reference
- 13047-06-8(CAS DataBase Reference)
N-Bromosuccinimide Price
- Product number
- 682926
- Product name
- 2-Bromobenzophenone
- Purity
- 95%
- Packaging
- 5g
- Price
- $131
- Updated
- 2025/07/31
- Product number
- 682926
- Product name
- 2-Bromobenzophenone
- Purity
- 95%
- Packaging
- 1g
- Price
- $33
- Updated
- 2023/06/20
- Product number
- B3937
- Product name
- 2-Bromobenzophenone
- Purity
- >97.0%(GC)
- Packaging
- 1g
- Price
- $21
- Updated
- 2025/07/31
- Product number
- B3937
- Product name
- 2-Bromobenzophenone
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $82
- Updated
- 2025/07/31
- Product number
- B680603
- Product name
- 2-Bromobenzophenone
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
2-BROMOBENZOPHENONE Chemical Properties,Usage,Production
Application
2-Bromobenzophenone can be used as an intermediate in organic synthesis and pharmaceutical research and development, and is suitable for laboratory organic synthesis and chemical and pharmaceutical synthesis processes. In organic synthesis, it can be used to prepare compounds such as N-benzoylmethylbromopyridine and unsubstituted ketone methylthiourea thiazole.
Chemical Properties
White solid
Synthesis
59142-47-1
13047-06-8
General procedure for the synthesis of 2-bromobenzyl ketone from 2-bromo-diphenylmethanol: In a pre-dried oven-dried Schlenk tube, 2-bromo-diphenylmethanol (69.0-199.5 mg, 0.5 mmol), CuI (10 mol%), 1,10-phenanthroline (20 mol%), and K3PO4 (2 mmol) were sequentially added, followed by injection of dioxane ( 2 mL). The reaction system was stirred at room temperature and under air atmosphere, and subsequently transferred to an oil bath at 80 °C to heat the reaction for 7-48 h. The reaction was carried out by thin layer chromatography (TLC). The reaction process was monitored by thin layer chromatography (TLC) until the reaction was complete. Upon completion of the reaction, the mixture was cooled to room temperature and quenched with aqueous NH4Cl, followed by extraction with CH2Cl2 (3 × 10 mL). The organic phases were combined, washed with saturated NaCl solution, dried over anhydrous Na2SO4 and filtered. The filtrate was concentrated under reduced pressure, and the resulting crude product was further purified by silica gel column chromatography (eluent: mixed system of petroleum ether/ethyl acetate) to finally obtain the target product 2-bromobenzophenone in 61-97% yields.
References
[1] Synthetic Communications, 2014, vol. 44, # 14, p. 2076 - 2087
[2] Journal of Organic Chemistry, 2014, vol. 79, # 5, p. 2059 - 2074
[3] Tetrahedron Asymmetry, 1992, vol. 3, # 7, p. 841 - 844
[4] Organic and Biomolecular Chemistry, 2018, vol. 16, # 2, p. 208 - 212
[5] Organic Letters, 2006, vol. 8, # 15, p. 3379 - 3381
2-BROMOBENZOPHENONE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-BROMOBENZOPHENONE manufacturers
- Product
- 2-BROMOBENZOPHENONE 13047-06-8
- Price
- US $9.00/KG
- Min. Order
- 1KG
- Purity
- 99.8%
- Supply Ability
- 100tons
- Release date
- 2024-08-20
- Product
- 2-BROMOBENZOPHENONE 13047-06-8
- Price
- US $4480.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 1T
- Release date
- 2020-06-29
- Product
- 2-BROMOBENZOPHENONE 13047-06-8
- Price
- US $4480.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 1T
- Release date
- 2020-06-29