Tert-Butyl 4-Vinylphenyl Carbonate
- Product Name
- Tert-Butyl 4-Vinylphenyl Carbonate
- CAS No.
- 87188-51-0
- Chemical Name
- Tert-Butyl 4-Vinylphenyl Carbonate
- Synonyms
- tbsm;c-1566;4-boc-styrene;p-tert-Butoxycarbonyloxystyrene;4-(tert-Butoxycarbonyloxy)styrene;TERT-BUTYL 4-VINYLPHENYL CARBONATE;tert-Butyl p-vinylphenyl carbonate;p-tert-butoxycarbonyloxystyrenemonomer;TERT-BUTYL 4-VINYLPHENYL CARBONATE 98%;1,1-dimethylethyl4-ethenylphenylcarbonate
- CBNumber
- CB9223114
- Molecular Formula
- C13H16O3
- Formula Weight
- 220.26
- MOL File
- 87188-51-0.mol
Tert-Butyl 4-Vinylphenyl Carbonate Property
- Melting point:
- 27-29 °C(lit.)
- Boiling point:
- 187 °C(lit.)
- Density
- 1.1101 (rough estimate)
- refractive index
- 1.5090 (estimate)
- Flash point:
- >230 °F
- InChI
- InChI=1S/C13H16O3/c1-5-10-6-8-11(9-7-10)15-12(14)16-13(2,3)4/h5-9H,1H2,2-4H3
- InChIKey
- GJWMYLFHBXEWNZ-UHFFFAOYSA-N
- SMILES
- C(OC1=CC=C(C=C)C=C1)(=O)OC(C)(C)C
- EPA Substance Registry System
- Carbonic acid, 1,1-dimethylethyl 4-ethenylphenyl ester (87188-51-0)
Safety
- WGK Germany
- 2
- RTECS
- FG0460000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
Tert-Butyl 4-Vinylphenyl Carbonate Chemical Properties,Usage,Production
Uses
Used as an intermediate in organic synthesis.
Application
Tert-Butyl 4-Vinylphenyl Carbonate (tBVPC) could be used to synthesize a terpolymer, which is a novel chemically amplified positive photoresist with methyl methacrylate (MMA)triphenylsulfonium salt methacrylate (TPSMA). In addition, Lithographic performance of a PAG-bound polymer resist based on tert-butyl 4-vinyl phenyl carbonate, n-[p-(t-butyloxycarbonyloxy) phenyl]maleimide terpolymers as a novel chemically amplified resist exhibited a positive working behavior. They showed 0.18 μm line pattern at electron beam lithography to indicate that the polymer bounded PAG resists have a potential to fabricate nanostructures[1].
Hazard
Moderately toxic by skin contact. A mild skin irritant.
Synthesis
Tert-Butyl 4-Vinylphenyl Carbonate was prepared by reacting 4-Hydroxystyrene with Di-tert-butyl dicarbonate in prestence of Tetramethylammonium hydroxide in water.
References
[1] Jae Beom Yoo . “Triphenylsulfonium salt methacrylate bound polymer resist for electron beam lithography.” Polymer 55 16 (2014): Pages 3599-3604.
Tert-Butyl 4-Vinylphenyl Carbonate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Tert-Butyl 4-Vinylphenyl Carbonate manufacturers
- Product
- p-(tert-Butoxycarbonyloxy)styrene 87188-51-0
- Price
- US $0.00-0.00/g
- Min. Order
- 10g
- Purity
- 97%+
- Supply Ability
- 100000kgs per Month
- Release date
- 2023-04-05
- Product
- Tert-Butyl 4-Vinylphenyl Carbonate 87188-51-0
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 500KG
- Release date
- 2023-01-05