ChemicalBook > CAS DataBase List > Tert-Butyl 4-Vinylphenyl Carbonate

Tert-Butyl 4-Vinylphenyl Carbonate

Product Name
Tert-Butyl 4-Vinylphenyl Carbonate
CAS No.
87188-51-0
Chemical Name
Tert-Butyl 4-Vinylphenyl Carbonate
Synonyms
tbsm;c-1566;4-boc-styrene;p-tert-Butoxycarbonyloxystyrene;4-(tert-Butoxycarbonyloxy)styrene;TERT-BUTYL 4-VINYLPHENYL CARBONATE;tert-Butyl p-vinylphenyl carbonate;p-tert-butoxycarbonyloxystyrenemonomer;TERT-BUTYL 4-VINYLPHENYL CARBONATE 98%;1,1-dimethylethyl4-ethenylphenylcarbonate
CBNumber
CB9223114
Molecular Formula
C13H16O3
Formula Weight
220.26
MOL File
87188-51-0.mol
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Tert-Butyl 4-Vinylphenyl Carbonate Property

Melting point:
27-29 °C(lit.)
Boiling point:
187 °C(lit.)
Density 
1.1101 (rough estimate)
refractive index 
1.5090 (estimate)
Flash point:
>230 °F
InChI
InChI=1S/C13H16O3/c1-5-10-6-8-11(9-7-10)15-12(14)16-13(2,3)4/h5-9H,1H2,2-4H3
InChIKey
GJWMYLFHBXEWNZ-UHFFFAOYSA-N
SMILES
C(OC1=CC=C(C=C)C=C1)(=O)OC(C)(C)C
EPA Substance Registry System
Carbonic acid, 1,1-dimethylethyl 4-ethenylphenyl ester (87188-51-0)
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Safety

WGK Germany 
2
RTECS 
FG0460000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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Tert-Butyl 4-Vinylphenyl Carbonate Chemical Properties,Usage,Production

Uses

Used as an intermediate in organic synthesis.

Application

Tert-Butyl 4-Vinylphenyl Carbonate (tBVPC) could be used to synthesize a terpolymer, which is a novel chemically amplified positive photoresist with methyl methacrylate (MMA)triphenylsulfonium salt methacrylate (TPSMA). In addition, Lithographic performance of a PAG-bound polymer resist based on tert-butyl 4-vinyl phenyl carbonate, n-[p-(t-butyloxycarbonyloxy) phenyl]maleimide terpolymers as a novel chemically amplified resist exhibited a positive working behavior. They showed 0.18 μm line pattern at electron beam lithography to indicate that the polymer bounded PAG resists have a potential to fabricate nanostructures[1].

Hazard

Moderately toxic by skin contact. A mild skin irritant.

Synthesis

Tert-Butyl 4-Vinylphenyl Carbonate was prepared by reacting 4-Hydroxystyrene with Di-tert-butyl dicarbonate in prestence of Tetramethylammonium hydroxide in water.

References

[1] Jae Beom Yoo . “Triphenylsulfonium salt methacrylate bound polymer resist for electron beam lithography.” Polymer 55 16 (2014): Pages 3599-3604.

Tert-Butyl 4-Vinylphenyl Carbonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Tert-Butyl 4-Vinylphenyl Carbonate Suppliers

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View Lastest Price from Tert-Butyl 4-Vinylphenyl Carbonate manufacturers

Shanghai Qyubiotech Co., Ltd.
Product
p-(tert-Butoxycarbonyloxy)styrene 87188-51-0
Price
US $0.00-0.00/g
Min. Order
10g
Purity
97%+
Supply Ability
100000kgs per Month
Release date
2023-04-05
Wuhan Huahan Dingcheng New Material Technology Co., Ltd
Product
Tert-Butyl 4-Vinylphenyl Carbonate 87188-51-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
500KG
Release date
2023-01-05

87188-51-0, Tert-Butyl 4-Vinylphenyl CarbonateRelated Search:

RARECHEM AL BM 0780 3-(4-TERT-BUTOXYCARBONYLOXY-3-METHOXY-PHENYL)-ACRYLIC ACID RARECHEM AL BM 0779 3-(4-TERT-BUTOXYCARBONYLOXY-PHENYL)-ACRYLIC ACID Tert-Butyl 4-Vinylphenyl Carbonate

  • 1,1-dimethylethyl4-ethenylphenylcarbonate
  • 4-boc-styrene
  • c-1566
  • carbonicacid,1,1-dimethylethyl4-ethenylphenylester
  • p-tert-butoxycarbonyloxystyrenemonomer
  • 4-(tert-Butoxycarbonyloxy)styrene
  • 4-(TERT-BUTOXYCARBONYLOXY)STYRENE;TERT-BUTYL P-VINYLPHENYL CARBONATE
  • tert-Butyl p-vinylphenyl carbonate
  • tbsm
  • p-tert-Butoxycarbonyloxystyrene
  • TERT-BUTYL 4-VINYLPHENYL CARBONATE
  • TERT-BUTYL 4-VINYLPHENYL CARBONATE 98%
  • p-tert-butoxycarbonyloxystyreChemicalbooknemonomer
  • 87188-51-0
  • H2CCHC6H4OCO2CCH33