Description
ChemicalBook > CAS DataBase List > 3-Chloro-2-methylpropene

3-Chloro-2-methylpropene

Description
Product Name
3-Chloro-2-methylpropene
CAS No.
563-47-3
Chemical Name
3-Chloro-2-methylpropene
Synonyms
METHALLYL CHLORIDE;Mac;3-chloro-2-methylprop-1-ene;3-CHLORO-2-METHYL-1-PROPENE;Isobutenyl chloride;beta-methylallylchloride;Methylallyl chloride;BETA-METHALLYL CHLORIDE;1-CHLORO-2-METHYL-2-PROPENE;NCI-C54820
CBNumber
CB9402043
Molecular Formula
C4H7Cl
Formula Weight
90.55
MOL File
563-47-3.mol
More
Less

3-Chloro-2-methylpropene Property

Melting point:
-80 °C (lit.)
Boiling point:
71-72 °C (lit.)
Density 
0.925 g/mL at 20 °C (lit.)
vapor density 
3.12 (vs air)
vapor pressure 
102 mm Hg ( 20 °C)
refractive index 
n20/D 1.427(lit.)
Flash point:
9 °F
storage temp. 
2-8°C
solubility 
H2O: insoluble
form 
Liquid
color 
Clear
explosive limit
2.2-10.4%(V)
Water Solubility 
0.5 g/L (20 ºC)
Merck 
14,2148
BRN 
878160
CAS DataBase Reference
563-47-3(CAS DataBase Reference)
IARC
2B (Vol. 63, 115) 2018
NIST Chemistry Reference
1-Propene, 3-chloro-2-methyl-(563-47-3)
EPA Substance Registry System
3-Chloro-2-methyl-1-propene (563-47-3)
More
Less

Safety

Hazard Codes 
F,C,N
Risk Statements 
11-20/22-34-43-51/53
Safety Statements 
9-16-29-36/37/39-45-61-26
RIDADR 
UN 2554 3/PG 2
WGK Germany 
2
RTECS 
UC8050000
Autoignition Temperature
899 °F
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29032900
Hazardous Substances Data
563-47-3(Hazardous Substances Data)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.05905
Product name
3-Chloro-2-methyl-1-propene
Purity
for synthesis
Packaging
100mL
Price
$45.7
Updated
2024/03/01
Sigma-Aldrich
Product number
8.05905
Product name
3-Chloro-2-methyl-1-propene
Purity
for synthesis
Packaging
500mL
Price
$77.3
Updated
2024/03/01
Sigma-Aldrich
Product number
108030
Product name
3-Chloro-2-methyl-1-propene
Purity
technical grade, 90%
Packaging
100ml
Price
$47
Updated
2024/03/01
Sigma-Aldrich
Product number
108030
Product name
3-Chloro-2-methyl-1-propene
Purity
technical grade, 90%
Packaging
1l
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
C0209
Product name
3-Chloro-2-methyl-1-propene
Purity
>98.0%(GC)
Packaging
25mL
Price
$21
Updated
2024/03/01
More
Less

3-Chloro-2-methylpropene Chemical Properties,Usage,Production

Description

3-Chloro-2-methylpropene is used as an intermediate to produce carbofuran, herbicides, plastics, pharmaceuticals and other organics. It is also used as an additive in textile and perfumes. It was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate and cationic polymerization of 3-Chloro-2-methylpropene with AICI3 and AIBr3 as initiators. It is also the reactant for the synthesis of cyclobutanone.

Chemical Properties

clear liquid

Uses

In organic synthesis.

Uses

3-Chloro-2-methylpropene has been used as reactant in the synthesis of cyclobutanone. It is used as an intermediate in the production of plastics, pharmaceuticals and other organic chemicals.

Uses

3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI3 and A3IBr, as initiators.

Definition

ChEBI: 3-Chloro-2-methylpropene is an organochlorine compound.

Biological Functions

MAC is a valuable index for clinical anesthesia, but it is seldom employed without taking other factors into consideration. For example, inhibiting movement in only 50% of patients is not acceptable. Consequently, if an inhalational agent were being used alone—that is, without the administration of other anesthetics or analgesic drugs—the anesthesiologist would employ a multiple of its MAC value to ensure immobility.MAC is frequently multiplied by a factor of 1.3 to achieve nearly 100% clinical efficacy. On the other hand, useful clinical results may be achieved with doses of anesthetics below MAC levels. For example, mild analgesia and amnesia often occur with doses of inhalational agents that are near 0.5 MAC. In this state, it may even be possible to communicate with patients intraoperatively, while their recall is limited.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 824, 1981 DOI: 10.1021/jo00317a041

General Description

A colorless to straw-colored liquid with a sharp penetrating odor. Less dense than water and insoluble in water. Flash point below 0°F. May be toxic by ingestion. Irritating to skin and eyes. Used to make plastics and pharmaceuticals.

Air & Water Reactions

Highly flammable. 3-Chloro-2-methylpropene may react with water at elevated temperatures. . Insoluble in water.

Reactivity Profile

3-Chloro-2-methylpropene is sensitive to light. 3-Chloro-2-methylpropene can react vigorously with oxidizers. 3-Chloro-2-methylpropene is incompatible with strong bases. 3-Chloro-2-methylpropene may react with water at elevated temperatures. .

Hazard

Irritant; poison; anesthetic; questionable carcinogen; toxic.

Health Hazard

Inhalation causes irritation of nose and throat. Contact of vapor or liquid with eyes causes irritation. Liquid irritates skin. Ingestion causes irritation of mouth and stomach.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. An irritant. Human mutation data reported. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately explosive when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and ALLYL COMPOUNDS.

Carcinogenicity

3-Chloro-2-methylpropene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

3-Chloro-2-methylpropene Preparation Products And Raw materials

Raw materials

Isobutylene Oleic acid

Preparation Products

2,3-Dihydro-2,2-dimethyl-7-benzofuranol 3-METHYL-3-BUTEN-1-OL BISPHENOL A DIMETHACRYLATE 2,2,4,6,7-Pentamethyldihydrobenzofuran-5-sulfonyl chloride Carbofuran 2-[(2-METHYL-2-PROPENYL)OXY]-PHENOL Fenbutatin oxide 2,2,4,6,7-Pentamethyldihydrobenzofuran 2-METHYL-2-PROPENE-1-SULFONIC ACID SODIUM SALT Neophyl chloride
More
Less

3-Chloro-2-methylpropene Suppliers

Americas 1 Belgium 2 Canada 1 China 191 Europe 4 France 3 Germany 10 India 6 Japan 5 Slovakia 1 South Korea 2 Switzerland 2 Ukraine 1 United Kingdom 13 United States 36 Global 278
HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10648
Advantage
60
Standardpharm Co. Ltd.
Tel
86-714-3992388
Email
overseasales1@yongstandards.com
Country
United States
ProdList
14332
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Monomer Polymer & Dajac Labs
Tel
--
Fax
--
Email
info@monomerpolymer.com
Country
United States
ProdList
1609
Advantage
58
TCI America, Inc. (Tokyo Chemical Industry Co., Ltd.)
Tel
--
Fax
--
Email
.Crew@tcichemicals.com
Country
United States
ProdList
3164
Advantage
58
MilliporeSigma (Sigma-Aldrich Corp.)
Tel
--
Fax
--
Email
@sial.com
Country
United States
ProdList
5414
Advantage
58
Fluorochem Ltd.
Tel
--
Fax
--
Email
enquiries@fluorochem.co.uk
Country
United States
ProdList
4583
Advantage
58
Advanced Synthesis S.A.
Tel
--
Fax
--
Country
United States
ProdList
249
Advantage
58
Sandrine Corporation
Tel
--
Fax
--
Email
sandrine@earthlink.net
Country
United States
ProdList
26
Advantage
58
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
Leonid Chemicals Private Limited
Tel
--
Fax
--
Email
careers@leonidchemicals.com
Country
United States
ProdList
1700
Advantage
43
VWR International, LLC.
Tel
--
Fax
--
Email
@sargentwelch.com
Country
United States
ProdList
6262
Advantage
58
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
Gelest, Inc.
Tel
--
Fax
--
Email
info@gelest.com
Country
United States
ProdList
3973
Advantage
84
Fisher Scientific
Tel
--
Fax
--
Email
sales@fishersci.com
Country
United States
ProdList
2337
Advantage
86
Ring Specialty Chemicals Inc.
Tel
--
Fax
--
Email
info@ringchemicals.com
Country
United States
ProdList
888
Advantage
39
HBCChem Inc.
Tel
--
Fax
--
Email
sales@hbcchem-inc.com
Country
United States
ProdList
4569
Advantage
30
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
ChemService Inc.
Tel
--
Fax
--
Country
United States
ProdList
6379
Advantage
68
ChemSampCo, Inc.
Tel
--
Fax
--
Email
sales@chemsampco.com
Country
United States
ProdList
3585
Advantage
60
Pfaltz & Bauer, Inc.
Tel
--
Fax
--
Email
sales@pfaltzandbauer.com
Country
United States
ProdList
6828
Advantage
72
Narchem Corporation
Tel
--
Fax
--
Email
sales@narchem.com
Country
United States
ProdList
2813
Advantage
60
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
Aagile Labs Division of Tyger Scientific
Tel
--
Fax
--
Email
tygersci@yahoo.com
Country
United States
ProdList
6568
Advantage
68
Advanced Synthesis Technologies
Tel
--
Fax
--
Email
sales@advancedsynthesis.com
Country
United States
ProdList
4775
Advantage
61
Secant Chemicals Inc.
Tel
--
Fax
--
Email
sales@secantchemicals.com
Country
United States
ProdList
18
Advantage
51
Acros Organics USA
Tel
--
Fax
--
Email
eveleth@fisherchem.com
Country
United States
ProdList
3846
Advantage
81
TimTec Corporation
Tel
--
Fax
--
Country
United States
ProdList
1945
Advantage
58
AB Chem Technologies, LLC
Tel
--
Fax
--
Email
sales@abchemtech.com
Country
United States
ProdList
1101
Advantage
46
City Chemicals Corporation
Tel
--
Fax
--
Country
United States
ProdList
6460
Advantage
72
Monomer-Polymer & Dajac Laboratories, Inc.
Tel
--
Fax
--
Email
monomerpolymer@comcast.net
Country
United States
ProdList
1989
Advantage
60
More
Less

View Lastest Price from 3-Chloro-2-methylpropene manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
3-Chloro-2-methylpropene 563-47-3
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-13
Hebei Chuanghai Biotechnology Co,.LTD
Product
3-Chloro-2-methylpropene 563-47-3
Price
US $50.00-20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-19
Henan Fengda Chemical Co., Ltd
Product
3-Chloro-2-methylpropene 563-47-3
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25

563-47-3, 3-Chloro-2-methylpropeneRelated Search:

Isobutylene Methacryloyl chloride Methacrylamide Sodium chloride 2-METHYL-2-PROPENE-1-SULFONIC ACID SODIUM SALT N,N'-Methylenebisacrylamide Polyvinyl chloride Ferric chloride Choline chloride Sulfuryl chloride Ammonium chloride Potassium chloride Calcium chloride Methacrolein C8-D1A NA Mouse cerebellar granule cells Mouse trabecular mesh cell

  • beta-Methylallyl chloride
  • beta-methylallylchloride
  • chloruedemethallyle(french)
  • Chlorure de methallyle
  • chloruredemethallyle
  • chloruredemethallyle(french)
  • Cloruro di metallile
  • clorurodimetallile
  • gamma-Chloroisobutylene
  • 1-propene,3-chloro-2-methyl-
  • 2-(Chloromethyl)-1-propene
  • 2-methallylchloride
  • 2-Methyl-3-chloro-1-propene
  • 2-Methyl-3-chloropropene
  • 2-Methyl-allylchlorid
  • 1-CHLORO-2-METHYL-2-PROPENE
  • 3-Chloro-2-Methylpropylene
  • 3-CHLORO-2-METHYLPROPENE, TECH., 90%
  • 2-CHLORO-2-METHYL-1-PROPANE
  • 3-CHLORO-2-METHYL-1-PROPENE 97+%
  • 2-Methyl-3-chloroprop-1-ene
  • 3-Chloro-2-methylpropene , 90%,tech
  • 3-Chloro-2-methylpropene ,90%
  • 3-Chloro-2-methyl-1-propene,β-Methallyl chloride
  • 3-Chloro-2-Methylpropene, tech., 90% 1LT
  • 3-Chloro-2-Methylpropene, tech., 90% 50ML
  • 2-Methylallyl chloride, 2-Methylprop-2-en-1-yl chloride
  • 3-Chloroisobutene beta-Methallyl Chloride 2-Methylallyl Chloride 2-Methyl-2-propenyl Chloride
  • 3-CHLORO-2-METHYL-1-PROPENE FOR SYNTHESI
  • METHALLYLCHLORIDEBOTTOMS
  • 3-Chloro-2-Methyl-1-propene contains ~250 ppM Pentaerythritol tetrakis(3,5-di-tert-butyl-4-hydroxyhydrocinnaMate) as stabilizer, 98%
  • 3-Chlor-2-methyl-1-propen
  • 3-Chlor-2-methyl-prop-1-en
  • 3-Chlor-2-methylpropen
  • 3-chloro-2-methyl
  • 3-chloro-2-methyl-1-propen
  • 3-chloro-2-methylprop-1-ene
  • 3-chloro-2-methyl-propen
  • 3-Chloro-2-methylpropene-1
  • 3-chloroisobu
  • 3-Cloro-2-metil-prop-1-ene
  • Mac
  • Methallylchlorid
  • NCI-C54820
  • Propene, 3-chloro-2-methyl-
  • Propene,3-chloro-2-methyl-
  • γ-Chloroisobutylene
  • BETA-METHALLYL CHLORIDE
  • Isobutenyl chloride
  • METHALLYL CHLORIDE
  • Methylallyl chloride
  • 3-CHLORO-2-METHYL-1-PROPENE
  • 3-CHLORO-2-METHYLPROPENE
  • 3-CHLOROISOBUTYLENE
  • 3-CHLOROISOBUTENE
  • AKOS BBS-00004062
  • 2-METHYLALLYL CHLORIDE
  • 2-METHYL-2-PROPENYL CHLORIDE