ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Basic information
- Product Name:
- (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- Synonyms:
-
- (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine)
- (S)-2-Furyl-MeOBIPHEP, SL-A108-2, (S)-(-)-2,2μ-Bis(di-2-furylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
- (S)-(-)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
- (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
- SL-A108-2
- (S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine) >=97%, optical purity ee: >=99%
- [2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]phenyl]-bis(furan-2-yl)phosphane
- CAS:
- 145214-59-1
- MF:
- C30H24O6P2
- MW:
- 542.46
- Product Categories:
-
- Chiral Phosphine
- MeOBIPHEP Series
- Mol File:
- 145214-59-1.mol
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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties
- Boiling point:
- 587.5±50.0 °C(Predicted)
- form
- Powder
- color
- off-white
- Stability:
- store cold
- CAS DataBase Reference
- 145214-59-1
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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Usage And Synthesis
Reaction
In many respects the catalytic profile of the MeO-BIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Stereocontrol in palladium-catalyzed propargylic substitutions: kinetc resolution to give enantioenriched 1,5-enynes and propargyl acetates.
Study of enantioselective catalysis of nitroso-Diels-Alder reaction on solid support.
Chemical Properties
White powder
Uses
Atropisomeric MeOBIPHEP ligands
General Description
sold in collaboration with Solvias AG
(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%Supplier
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