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1H,1H,2H,2H-Perfluorohexyl iodide

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1H,1H,2H,2H-Perfluorohexyl iodide Basic information

Product Name:
1H,1H,2H,2H-Perfluorohexyl iodide
Synonyms:
  • 1,1,1,2,2,3,3,4,4-nonafluoro-6-iodo-hexan
  • 1,1,2,2-Tetrahydroperfluorohexyliodide
  • 2-(NONAFLUOROBUTYL)ETHYL IODIDE
  • 2-(PERFLUOROBUTYL)ETHYL IODIDE
  • 1H,1H,2H,2H-PERFLUOROHEXYL IODIDE
  • 1H,1H,2H,2H-NONAFLUOROHEXYL IODIDE
  • 1H,1H,2H,2H-PERFLUORO-1-IODOHEXANE
  • 1-IODO-1H,1H,2H,2H-NONAFLUOROHEXANE
CAS:
2043-55-2
MF:
C6H4F9I
MW:
373.99
EINECS:
218-055-6
Product Categories:
  • Fluorous Chemistry
  • Fluorous Compounds
  • Synthetic Organic Chemistry
Mol File:
2043-55-2.mol
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1H,1H,2H,2H-Perfluorohexyl iodide Chemical Properties

Melting point:
-25°C
Boiling point:
138 °C
Density 
1.94 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.370
Flash point:
138-140°C
storage temp. 
2-8°C
solubility 
Chloroform (Soluble), Methanol (Slightly)
form 
clear liquid
Specific Gravity
1.940
color 
Colorless to Light yellow to Light red
Sensitive 
Light Sensitive
BRN 
1870862
InChIKey
CXHFIVFPHDGZIS-UHFFFAOYSA-N
CAS DataBase Reference
2043-55-2(CAS DataBase Reference)
EPA Substance Registry System
Hexane, 1,1,1,2,2,3,3,4,4-nonafluoro-6-iodo- (2043-55-2)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
8
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29037800

MSDS

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1H,1H,2H,2H-Perfluorohexyl iodide Usage And Synthesis

Description

1H,1H,2H,2H-Perfluorohexyl iodide is a polyfluorinated iodine alkane (PFI). This compound consists of an even-numbered hydrophobic alkyl chain (typically C4–C12), which is wholly or partially fluorinated and includes an iodine atom at one or both ends. PFIs are reaction products synthesized from the telomerization process by iodine pentafluoride reacting with unsaturated taxogen molecules such as tetrafluoroethylene and ethylene. PFIs are used as critical industrial intermediates for producing various PFCs, such as fluorotelomer alcohols, olefins, and acrylate monomers[1].

Chemical Properties

Red liquid

Uses

1H,1H,2H,2H-Perfluorohexyl iodide has been used for the study for fluorinated phosphonium ionic liquids as a reagent, and in general is used as a reactant in organic reactions.

References

[1] Ruan, Ting , et al. "Trace determination of airborne polyfluorinated iodine alkanes using multisorbent thermal desorption/gas chromatography/high resolution mass spectrometry." Journal of Chromatography A 1217.26(2010):4439-4447.

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