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retronecine

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retronecine Basic information

Product Name:
retronecine
Synonyms:
  • (1R)-2,3,5,7aβ-Tetrahydro-1-hydroxy-1H-pyrrolizine-7-methanol
  • (1R)-2,3,5,7aβ-Tetrahydro-1α-hydroxy-1H-pyrrolizine-7-methanol
  • Retronecin
  • (1R,7aR)-2,3,5,7a-Tetrahydro-1-hydroxy-1H-pyrrolizine-7-methanol
  • 1H-Pyrrolizine-7-methanol, 2,3,5,7a-tetrahydro-1-hydroxy-, (1R,7aR)-
  • (1R,7aR)-7-(Hydroxymethyl)-2,3,5,7a-tetrahydro-1H-pyrrolizin-1-ol
CAS:
480-85-3
MF:
C8H13NO2
MW:
155.19
Mol File:
480-85-3.mol
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retronecine Chemical Properties

Melting point:
119-120°
alpha 
20D +4.95° (c = 0.58 in alc)
Boiling point:
80 °C(Press: 0.01 Torr)
Density 
1.29±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
Ethanol (Slightly), Methanol (Slightly)
pka
14.48±0.40(Predicted)
color 
Off-White to Light Brown
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Safety Information

RIDADR 
1544
WGK Germany 
3
RTECS 
VH7175000
HazardClass 
6.1(b)
PackingGroup 
III
Hazardous Substances Data
480-85-3(Hazardous Substances Data)
Toxicity
LD50 i.v. in mice: 634.0 ±26.0 mg/kg (Harris)
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retronecine Usage And Synthesis

Uses

(+)-Retronecine, is a Pyrrolizidine alkaloid (PA) , which is a hepatotoxic, that is, damaging to the liver. It is also tumorigenic. It can also be used as an intermediate for the synthesis of (+)-Lycopsamine (L487525), and (E325580).

Definition

ChEBI: Retronecine is a member of pyrrolizines.

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