Basic information Safety Supplier Related

HYDROABIETYL ALCOHOL

Basic information Safety Supplier Related

HYDROABIETYL ALCOHOL Basic information

Product Name:
HYDROABIETYL ALCOHOL
Synonyms:
  • dihydro-abietylalcoho
  • dodecahydro-1,4a-dimethyl-7-(1-methylethyl)-1-phenanthrenemethano
  • dodecahydro-1,4a-dimethyl-7-(1-methylethyl)-1-Phenanthrenemethanol
  • [1R-(1alpha,4abeta,4balpha,10aalpha)]-dodecahydro-7-isopropyl-1,4a-dimethylphenanthren-1-methanol
  • ABITOL
  • DIHYDROABIETYL ALCOHOL
  • HYDROABIETYL ALCOHOL
  • ABITOL TECH
CAS:
26266-77-3
MF:
C20H34O
MW:
290.48
EINECS:
247-574-0
Mol File:
26266-77-3.mol
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HYDROABIETYL ALCOHOL Chemical Properties

color 
A colourless viscous liquid with a very faint wood-like odour
Odor
mild woody
LogP
6.789 (est)
EPA Substance Registry System
1-Phenanthrenemethanol, 1,2,3,4,4a,4b,5,6,7,9,10,10a-dodecahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bS,10aR)- (26266-77-3)
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Safety Information

Toxicity
Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Shelanski, 1972).
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HYDROABIETYL ALCOHOL Usage And Synthesis

Chemical Properties

The pure hydroabietyl alcohol is almost white, crystalline plates or powder. M.P. 174-182” C. Lower grade commercial material is usually off-white or pale straw-colored, granular crystals or conglomerated mass with much lower melting point. Insoluble in water, soluble in alcohol and oils. Also soluble in aqueous solution of Sodium hydroxide.

Occurrence

Has apparently not been reported to occur in nature

Uses

for use in adhesives, mascara, inks, sealants, etc.; pasticizer in plastic materials;

Uses

Hydroabietyl alcohol is also the natural source and parent of several solvent-fixatives, used in perfumery: Abitol, Methyl abietate (Abalyn) and hydrogenated Methyl abietate (Hercolyn). Rosin, the natural material, is occasionally used as a fixative in Pine and other fragrance types. It is inexpensive and has at times been popular in certain types of soap perfume. Certain derivatives of Abietic acid are used as emulsifiers and “cloudificators” in carbonated beverages - to give visual impression of fruit juice content in beverages made with little or no “cloudy” natural juice. “Cloudy” Orange sodas are popular in certain countries.

Preparation

From hydrogenated rosin acids (Arctander, 1969).

Preparation

By distillation of Rosin (from American Turpentine, e. g.) or by treatment with acid to isomenze the natural Levopimaric acid. Purification over the Diamylammonium salt.

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