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ChemicalBook >  Product Catalog >  Organic Chemistry >  Phosphines >  4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE

4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE

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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Basic information

Product Name:
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
Synonyms:
  • 4,6-Bis(diphenylphosphino)phenoxazine 97%
  • N-XantPhos 97%
  • 4,6-Bis(diphenylphosphino)phenoxazine, min. 98%
  • NIXANTPHOS
  • 4,6-BIS(DIPHENYLPHOSPHINO)-10H-PHENOXAZINE
  • 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
  • 4,6-Bis(diphenylphosphino)phenoxazine, NIXANTPHOS
  • 4,6-Bis(diphenylphosphino)phenoxazine,min.98%NIXANTPHOS
CAS:
261733-18-0
MF:
C36H27NOP2
MW:
551.55
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • organophosphine ligand
Mol File:
261733-18-0.mol
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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Chemical Properties

Melting point:
256-262 °C
Boiling point:
662.1±55.0 °C(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
1.34±0.20(Predicted)
form 
Powder
color 
white to off-white
Water Solubility 
Miscible with water.
InChIKey
HSWZLYXRAOXOLL-UHFFFAOYSA-N
CAS DataBase Reference
261733-18-0
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
22-24/25
WGK Germany 
3
TSCA 
No
HS Code 
2934.99.4400

MSDS

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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Usage And Synthesis

Reactions

  1. A large bite-angle chelating bisphosphine that provides high levels of linear-to-branched selectivity in the hydroformylation of alkenes.
  2. A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides.

Uses

4,6-Bis(diphenylphosphino)phenoxazine used as an intermediate in the manufacture of pharmaceuticals, agrochemicals, dyestuffs, fine chemicals, medical and material synthesis.

Uses

N-XantPhos is a deprotonatable chelating aryldiphosphine ligand that can be used in:

  • The preparation of Pd-NiXantphos catalyst system for the room temperature cross-coupling reactions of unactivated aryl chlorides.
  • The synthesis of cinchonine iridium(III) cyclometalated complex that exhibits luminescence and good quantum efficiency.
  • N-XantPhos and N-modified counterparts are also used in the preparation of rhodium based catalysts for hydroformylation reaction.

Uses

4,6-Bis(Diphenylphosphino)phenoxazine is used as a palladium catalyst in reactions involving the synthesis of triarylmethanes.

4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINESupplier

Xinxiang Runyu Material Co., Ltd. Gold
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