1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Chemical Properties

Melting point:

280-286 °C

storage temp. 

Inert atmosphere,Room Temperature

form 

Powder

color 

Beige to pink-brown

Sensitive 

air sensitive

InChIKey

COGMCBFILULEOS-UHFFFAOYSA-M

CAS DataBase Reference

173035-10-4

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

37/39-26-36

WGK Germany 

3

TSCA 

No

HS Code 

29332990

MSDS

• Language:English Provider:ACROS

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Usage And Synthesis

Chemical Properties

beige to pink-brown powder

Uses

N-Heterocyclic Carbene Ligands Precursor to an N-heterocyclic carbene catalysts

Uses

N-Heterocyclic Carbene Ligands

Precursor to an N-heterocyclic carbene catalysts used for:

• A regioselective cycloadditon of terminal acetylenes with azides leading to 1,4-disubstitutedtriazoles. Internal acetylenes can also be used with this catalyst.
• Markovnikov-type hydration of terminal alkynes
• Hydrosilylation of ketones and cycloaddition of azides and alkynes
• Suzuki-Miyaura reactions
• Luminescence experiments

General Description

1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride is an NHC (N-heterocyclic carbene) ligand which can bind with metal pre-catalysts to form complexes that show high catalytic activity.

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE(173035-10-4)Related Product Information

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• 1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
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• GRUBBS CATALYST 2ND GENERATION
• 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
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• Umicore M41
• (1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDA&
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• [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II)