N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea
N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Basic information
- Product Name:
- N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea
- Synonyms:
-
- K ACID
- EUROPEAN K-ACID
- 1 AMINO 8 HYDROXY 4:6 DISULFONIC ACID
- 1-AMINO-8-NAPHTHOL-4,6-DISULFONIC ACID
- 4-amino-5-hydroxynaphthalene-1,7-disulfonic acid
- 4-amino-5-hydroxynaphthalene-1,7-disulphonic acid
- 1-amino-8-naphtho-4,6-Disulfonic acid
- 1-Amino-8-Naphthol-4£6-disulfonic acid/European K Acid
- CAS:
- 130-23-4
- MF:
- C10H9NO7S2
- MW:
- 319.31
- EINECS:
- 204-982-3
- Product Categories:
-
- Intermediates of Dyes and Pigments
- Mol File:
- 130-23-4.mol
N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Chemical Properties
- Density
- 1.880±0.06 g/cm3(Predicted)
- pka
- -0.83±0.40(Predicted)
- Water Solubility
- 20g/L at 26.4℃
- LogP
- -2.33
- CAS DataBase Reference
- 130-23-4(CAS DataBase Reference)
N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Usage And Synthesis
Chemical Properties
1-Amino-8-hydroxynaphthalene-4,6-disulfonic acid [130-23-4]. (4-amino-5-hydroxynaphthalene-1,7-disulfonic acid), K acid, C10H9NO7S2, Mr 319.3: the acid sodium salt of 1-Amino-8-hydroxynaphthalene-4,6-disulfonic acid is very soluble in water, but the acid potassium salt is less soluble and is more easily salted out. K acid couples under acid and alkaline conditions in a similar manner to H acid.
Uses
Azo dye intermediate.
Uses
The N-substituted derivatives of K acid, such as N-acetyl, N-benzoyl, N-(2,5-dichlorobenzoyl), and N-benzyl, are used as monoazo coupling components in special cases where an improvement in dye properties over the H acid analogue is demonstrable.
Production Methods
1-Aminonaphthalene-4,6,8-trisulfonic acid paste is heated with sodium hydroxide liquor in an autoclave at 170℃ for 12 h, after which the mixture is added to excess dilute hydrochloric acid. After heating to remove sulfur dioxide, the product (including ca. 8 % of the isomeric 5-amino-2-hydroxynaphthalene-4,8-disulfonic acid) is completely precipitated by cooling and is isolated in 86 % yield. Purification of crude K acid may be effected by dissolving it in aqueous alkali and filtering off the less soluble 5,2,4,8-isomer before reprecipitating.
Flammability and Explosibility
Not classified
N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Preparation Products And Raw materials
Raw materials
N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl ureaSupplier
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N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea(130-23-4)Related Product Information
- Nickel bis(sulphamidate)
- Molasses
- Glycine
- Ammonium sulfamate
- 6-Aminocaproic acid
- Sulfamic acid monosodium salt
- 4-Amino-benzenesulfonic acid monosodium salt
- Sulfanilic acid
- Sulfamic acid
- 1-AMINO-8-NAPHTHOL-2,4-DISULFONIC ACID MONOSODIUM SALT
- 4-acetamido-5-hydroxynaphthalene-2,7-disulfonic acid
- BLACK PN
- 8-AMINO-1-NAPHTHOL-3,6-DISULFONIC ACID,1-AMINO-8-NAPHTHOL-3,6-DISULFONIC ACID
- 8-Amino-1-naphthol-3,6-disulfonic acid monosodium salt monohydrate
- Trypan Blue
- 6-Amino-1-naphthol-3,5-disulfonic acid,3-amino-8-naphthol-4,6-disulfonic acid,2-amino-5-naphthol-1,7-disulfonic acid
- 8-AMINO-1-NAPHTHOL-3,6-DISULFONIC ACID MONOSODIUM SALT N-HYDRATE,4-AMINO-5-NAPHTHOL-2,7-DISULFONIC ACID MONOSODIUM SALT HYDRATE
- LIGNIN PINK