Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Organic Chemistry >  Amides >  Sulfonic acids amino compound >  N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea

N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea

Basic information Safety Supplier Related

N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Basic information

Product Name:
N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea
Synonyms:
  • K ACID
  • EUROPEAN K-ACID
  • 1 AMINO 8 HYDROXY 4:6 DISULFONIC ACID
  • 1-AMINO-8-NAPHTHOL-4,6-DISULFONIC ACID
  • 4-amino-5-hydroxynaphthalene-1,7-disulfonic acid
  • 4-amino-5-hydroxynaphthalene-1,7-disulphonic acid
  • 1-amino-8-naphtho-4,6-Disulfonic acid
  • 1-Amino-8-Naphthol-4£6-disulfonic acid/European K Acid
CAS:
130-23-4
MF:
C10H9NO7S2
MW:
319.31
EINECS:
204-982-3
Product Categories:
  • Intermediates of Dyes and Pigments
Mol File:
130-23-4.mol
More
Less

N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Chemical Properties

Density 
1.880±0.06 g/cm3(Predicted)
pka
-0.83±0.40(Predicted)
Water Solubility 
20g/L at 26.4℃
LogP
-2.33
CAS DataBase Reference
130-23-4(CAS DataBase Reference)
More
Less

N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Usage And Synthesis

Chemical Properties

1-Amino-8-hydroxynaphthalene-4,6-disulfonic acid [130-23-4]. (4-amino-5-hydroxynaphthalene-1,7-disulfonic acid), K acid, C10H9NO7S2, Mr 319.3: the acid sodium salt of 1-Amino-8-hydroxynaphthalene-4,6-disulfonic acid is very soluble in water, but the acid potassium salt is less soluble and is more easily salted out. K acid couples under acid and alkaline conditions in a similar manner to H acid.

Uses

Azo dye intermediate.

Uses

The N-substituted derivatives of K acid, such as N-acetyl, N-benzoyl, N-(2,5-dichlorobenzoyl), and N-benzyl, are used as monoazo coupling components in special cases where an improvement in dye properties over the H acid analogue is demonstrable.

Production Methods

1-Aminonaphthalene-4,6,8-trisulfonic acid paste is heated with sodium hydroxide liquor in an autoclave at 170℃ for 12 h, after which the mixture is added to excess dilute hydrochloric acid. After heating to remove sulfur dioxide, the product (including ca. 8 % of the isomeric 5-amino-2-hydroxynaphthalene-4,8-disulfonic acid) is completely precipitated by cooling and is isolated in 86 % yield. Purification of crude K acid may be effected by dissolving it in aqueous alkali and filtering off the less soluble 5,2,4,8-isomer before reprecipitating.

Flammability and Explosibility

Not classified

N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Preparation Products And Raw materials

Raw materials

N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl ureaSupplier

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280 17798518460
Email
cfzhang@aikonchem.com
Shanghai Meishui Chemical Technology Co., Ltd
Tel
021-60549325 18616193163
Chengdu HuaXia Chemical Reagent Co. Ltd
Tel
400-1166-196 13458535857
Email
cdhxsj@163.com
Shanghai Synchem Pharma Co., ltd
Tel
21-619849051-1 18521059765
Email
synchempharma@aliyun.com
Zhengzhou Acme Chemical Co., Ltd.
Tel
0371-0371-55629727 13323845623
Email
2885676761@qq.com