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ChemicalBook >  Product Catalog >  Catalyst and Auxiliary >  Catalyst >  (RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene

(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene

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(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene Basic information

Product Name:
(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
Synonyms:
  • (RP)-1-[(R)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
  • (R)-(-)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane,Min.97%
  • Taniaphos SL-T001-1, (2S)-1-[(R)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS)
  • (R)-(-)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane, min. 97%
  • (R)-(+)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-
    diphenylphosphinophenyl)methane, min. 97%
  • (R)-1-Diphenylphosphino-2-[(R)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene
  • (RP)-1-[(R)-alpha-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene optical purity ee: >=99%
  • (2S)-1-[(R)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene
CAS:
1003012-96-1
MF:
C45H45FeNP2
MW:
717.638022
Product Categories:
  • organometallic complex
Mol File:
1003012-96-1.mol
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(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene Chemical Properties

alpha 
+312° ±15° (c 0.5, CHCl3)
storage temp. 
2-8°C
form 
Powder
color 
orange
Stability:
store cold
InChIKey
DEHRMLQYTSYVBC-VROLVAQFSA-N
SMILES
[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
CAS DataBase Reference
1003012-96-1
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Safety Information

WGK Germany 
3
HS Code 
29319090
Storage Class
11 - Combustible Solids
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(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene Usage And Synthesis

Reactions

  1. Ligand for copper-catalyzed asymmetric allylic alkylation of halocrotonates
  2. Ligand for silver-catalyzed asymmetric 1,3-dipolar cycloadditions of α-iminonitriles
  3. Ligand for copper-catalyzed enantioselective reductive couplings of alkenylazaarenes with ketones
  4. Ligand for copper-catalyzed chiral Mannich-type reactions of γ-butenolides and N-thiophosphinoyl ketimines
  5. Ligand for palladium-catalyzed asymmetric borylation
  6. Ligand for copper-catalyzed enantiodivergent hydroboration of bicyclic alkenes

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferroceneSupplier

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