Bromocyclohexane Chemical Properties

Melting point:

-57°C

Boiling point:

166-167 °C (lit.)

Density 

1.324 g/mL at 25 °C (lit.)

vapor density 

5.62 (vs air)

refractive index 

n20/D 1.495(lit.)

Flash point:

145 °F

storage temp. 

Sealed in dry,Room Temperature

solubility 

Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride.

form 

Liquid

Specific Gravity

approximate 1.33 (20℃)

color 

Clear colorless to light yellow

Odor

Unpleasant Odor

Water Solubility 

insoluble

Sensitive 

Air & Light Sensitive

Merck 

14,2730

BRN 

1098373

Dielectric constant

7.9（25℃）

Stability:

Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.

InChI

1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2

InChIKey

AQNQQHJNRPDOQV-UHFFFAOYSA-N

SMILES

BrC1CCCCC1

CAS DataBase Reference

108-85-0(CAS DataBase Reference)

NIST Chemistry Reference

Cyclohexane, bromo-(108-85-0)

EPA Substance Registry System

Cyclohexane, bromo- (108-85-0)

Safety Information

Hazard Codes 

Xn

Risk Statements 

36/37/38-20-18-52

Safety Statements 

23-24/25-37/39-26

WGK Germany 

3

RTECS 

GU7171700

F 

8

TSCA 

TSCA listed

HS Code 

29035990

Storage Class

10 - Combustible liquids

Hazard Classifications

Aquatic Chronic 2

MSDS

• Language:English Provider:Bromocyclohexane
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Bromocyclohexane Usage And Synthesis

Chemical Properties

colourless liquid

Uses

Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.

Preparation

Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.

Synthesis Reference(s)

Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020

General Description

Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.

Purification Methods

Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]

Bromocyclohexane(108-85-0)Related Product Information

• Cyclopropyl bromide
• Methylcyclohexane
• Cyclohexylbenzene
• Tricyclohexyl phosphine
• Molasses
• Ethidium bromide
• Rocuronium bromide
• Cyclohexanecarboxylic acid
• Cyclamic acid
• Ethylcyclohexane
• 1-Bromododecane
• Dimidium bromide
• Sodium bromate
• Cyclohexanemethanol
• Chlorocyclohexane
• Allyl bromide
• Isocyanatocyclohexane
• Vecuronium bromide