Bromocyclohexane
Bromocyclohexane Basic information
- Product Name:
- Bromocyclohexane
- Synonyms:
-
- BROMOCYCLOHEXANE FOR SYNTHESIS
- BROMOCYCLOHEXANE
- Cyelohexyl bromide
- CYCLOHEXYL BROMIDE
- 1-Bromocyclohexane
- bromo-cyclohexan
- Bromocylohexane
- Cyclohexane,bromo-
- CAS:
- 108-85-0
- MF:
- C6H11Br
- MW:
- 163.06
- EINECS:
- 203-622-2
- Product Categories:
-
- Alkyl
- Building Blocks
- Pharmaceutical Intermediates
- Halogen compounds
- Chemical Synthesis
- Halogenated Hydrocarbons
- Organic Building Blocks
- Mol File:
- 108-85-0.mol
Bromocyclohexane Chemical Properties
- Melting point:
- -57°C
- Boiling point:
- 166-167 °C (lit.)
- Density
- 1.324 g/mL at 25 °C (lit.)
- vapor density
- 5.62 (vs air)
- refractive index
- n20/D 1.495(lit.)
- Flash point:
- 145 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride.
- form
- Liquid
- Specific Gravity
- approximate 1.33 (20℃)
- color
- Clear colorless to light yellow
- Odor
- Unpleasant Odor
- Water Solubility
- insoluble
- Sensitive
- Air & Light Sensitive
- Merck
- 14,2730
- BRN
- 1098373
- Dielectric constant
- 7.9(25℃)
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
- InChIKey
- AQNQQHJNRPDOQV-UHFFFAOYSA-N
- CAS DataBase Reference
- 108-85-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Cyclohexane, bromo-(108-85-0)
- EPA Substance Registry System
- Cyclohexane, bromo- (108-85-0)
Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-20-18-52
- Safety Statements
- 23-24/25-37/39-26
- WGK Germany
- 3
- RTECS
- GU7171700
- F
- 8
- TSCA
- Yes
- HS Code
- 29035990
MSDS
- Language:English Provider:Bromocyclohexane
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
Bromocyclohexane Usage And Synthesis
Chemical Properties
colourless liquid
Uses
Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.
Preparation
Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.
Synthesis Reference(s)
Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020
General Description
Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.
Purification Methods
Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]
Bromocyclohexane Preparation Products And Raw materials
Raw materials
Preparation Products
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Bromocyclohexane(108-85-0)Related Product Information
- Cyclopropyl bromide
- Methylcyclohexane
- Cyclohexylbenzene
- Tricyclohexyl phosphine
- Molasses
- Ethidium bromide
- Rocuronium bromide
- Cyclohexanecarboxylic acid
- Cyclamic acid
- Ethylcyclohexane
- 1-Bromododecane
- Dimidium bromide
- Sodium bromate
- Cyclohexanemethanol
- Chlorocyclohexane
- Allyl bromide
- Isocyanatocyclohexane
- Vecuronium bromide