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DECAHYDRO-2-NAPHTHOL

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DECAHYDRO-2-NAPHTHOL Basic information

Product Name:
DECAHYDRO-2-NAPHTHOL
Synonyms:
  • TRANS DECAHYDRO BETA NAPHTHOL
  • .beta.-Naphthol, decahydro
  • 2-Decalinol
  • 2-Hydroxydecalin
  • decahydro-2-naphthaleno
  • Decahydro-2-naphthalenol
  • decahydro-2-naphthol,mixtureofisomers
  • Decahydro-beta-naphthol
CAS:
825-51-4
MF:
C10H18O
MW:
154.25
EINECS:
212-545-3
Mol File:
825-51-4.mol
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DECAHYDRO-2-NAPHTHOL Chemical Properties

Boiling point:
109 °C/14 mmHg (lit.)
Density 
0.996 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
refractive index 
n20/D 1.5(lit.)
Flash point:
>230 °F
Water Solubility 
Insoluble in water
form 
powder to lump to clear liquid
Melting point:
99-100 °C
pka
15.34±0.20(Predicted)
color 
White or Colorless to Light yellow
Odor
at 100.00 %. clean rose minty muguet
Odor Type
floral
BRN 
773927
LogP
2.934 (est)
CAS DataBase Reference
825-51-4(CAS DataBase Reference)
EPA Substance Registry System
2-Naphthalenol, decahydro- (825-51-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
2
RTECS 
QK4240000
HS Code 
29071590

MSDS

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DECAHYDRO-2-NAPHTHOL Usage And Synthesis

Chemical Properties

white to light yellow weak paste. Mild, sweet, slightly camphoraceous-woody, also warm and mildly spicy odor of fair tenacity. The odor has been compared to that of Dihydrocarveol. Practically insoluble in water, soluble in alcohol and oils.

Uses

This alcohol has been used, and is still used on a modest scale, in perfume compositions, mostly in connection with woody and camphoraceous fragrance types, including the lonones, Cyclohexylderivatives, etc.

Production Methods

Decahydro-2-naphthol is produced by catalytic hydrogenation of befa-Naphthol. The reaction yields a mixture of cis- and tram-isomers, but the perfumers generally prefer the tram-isomer, or a material primarily consisting of that isomer.

Synthesis Reference(s)

Tetrahedron Letters, 22, p. 941, 1981 DOI: 10.1016/0040-4039(81)89014-4

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