(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Basic information
- Product Name:
- (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
- Synonyms:
-
- SF110065
- (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
- (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
- (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d
- (11bS)-4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
- (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin
- (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide,99%e.e.
- (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate
- CAS:
- 864943-22-6
- MF:
- C48H29O4P
- MW:
- 700.72
- Mol File:
- 864943-22-6.mol
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(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Chemical Properties
- Melting point:
- 390-400°C
- Density
- 1.46±0.1 g/cm3(Predicted)
- storage temp.
- -20°C
- pka
- 1.11±0.20(Predicted)
- optical activity
- [α]22/D 44.0°, c = 1 in DMSO
- CAS DataBase Reference
- 864943-22-6
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(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Usage And Synthesis
Uses
Catalyst for:
- Asymmetric hydrogenation cascade
- Enantioselective Friedel-Crafts reaction
- Asymmetric hydrogenation of 2-substituted quinolines
- Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
- Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
- Asymmetric transfer hydrogenation of substituted quinoxalines
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxideSupplier
Shanghai Suifu Chemical Technology CO.,LTD. Gold
- Tel
- +86-021-33738187 +86-17736114707
- suifuchemical@163.com
Daicel Chiral Technologies (China)CO.,LTD
- Tel
- 021-50460086-9 15921403865
- han_yajun@dctc.daicel.com
Tianjin Derchemist Science & Technology Co., Ltd.
- Tel
- 22-58627059 13920586291
- zdcomcon@126.com
Shanghai Topbiochem Technology Co., Ltd
- Tel
- +86-21-60341587
- sales@topbiochem.com
Bide Pharmatech Ltd.
- Tel
- 400-1647117 15221909166
- product02@bidepharm.com
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(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide(864943-22-6)Related Product Information
- R-4-oxide-4-hydroxy-2,6-bis(4-Methoxyphenyl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
- (R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
- Ir(I)/(S)-t-Bu-PHOX
- S-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
- (S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
- R-4-oxide-4-hydroxy-2,6-di-2-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
- (R)-3,3'-Dibromo-2,2'-bis(meth
- (R)-3,3'-DIBROMO-2,2'-DIMETHOXY-1,1'-BINAPHTHYL
- R-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol
- R-3,3'-di-9-phenanthrenyl-1,1'-Binaphthalene]-2,2'-diol
- R-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol
- R-2,2'-bis(methoxymethoxy)-3,3'-diphenyl-1,1'-Binaphthalene
- R-3,3'-diiodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene
- (R)-NOBIN
- R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
- R-3,3'-bis[4-(trifluoroMethyl)phenyl]-[1,1'-Binaphthalene]-2,2'-diol
- R-4-oxide-2,6-di-9-anthracenyl-8,9,10,11,12,13,14,15-octahydro-4-hydroxy--Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
- (11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin