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RuPhos Pd G3

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RuPhos Pd G3 Basic information

Product Name:
RuPhos Pd G3
Synonyms:
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [RuPhos Palladacycle]
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%
  • RuPhos Pd G3 95%
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • (2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
  • RuPhos Pd G3
  • RuPhos-G3-Palladacycle
  • RuPhos-Pd-G3
CAS:
1445085-77-7
MF:
C43H57NO5PPdS-
MW:
837.375141
Product Categories:
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd
Mol File:
1445085-77-7.mol
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RuPhos Pd G3 Chemical Properties

Melting point:
188-196°C (decomposition)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
white
InChIKey
GYTUQNMMIUJBSP-UHFFFAOYSA-N
CAS DataBase Reference
1445085-77-7
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-52/53
Safety Statements 
26-61
WGK Germany 
3
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RuPhos Pd G3 Usage And Synthesis

Reaction

  1. Palladium catalyst used for facile, C-N cross-coupling reactions.
  2. A practical synthesis of indoles via a Pd-catalyzed C-N ring formation.

Uses

RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:

  • Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.
  • Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.
  • Suzuki-Miyaura-cross-coupling of aminothiophenes.

General Description

RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

RuPhos Pd G3Supplier

xinxiang runyu material co.,Ltd Gold
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15690792173 15690792173
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sales@runvmat.com
WuHan Taiyukaishang Chemical Co., Ltd. Gold
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027-027-87680032 18963957250
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taiyuchem@163.com
Beijing Guofang Dingsheng Technology Co., Ltd. Gold
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18610472091 18610472091
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gfdskj@163.com
Wu Han Lbpchem Chemical Co., Ltd. Gold
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02763499399 13797220777
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Wuhan Jiade Ruifeng New Materials Co., Ltd Gold
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18271874579; 18271874579
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