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ChemicalBook >  Product Catalog >  Organic Chemistry >  Carboxylic acids and derivatives >  Cyclic carboxylic acids >  Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4

Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4

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Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4 Basic information

Product Name:
Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4
Synonyms:
  • Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4
  • Rh2(S-?BTPCP)?4
  • Tetrakis[(S)-[(1S)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II)
CAS:
1345974-63-1
MF:
C88H68Br4O8Rh2
MW:
1778.90372
Mol File:
1345974-63-1.mol
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Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4 Chemical Properties

storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
solid
color 
green
CAS DataBase Reference
1345974-63-1
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Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4 Usage And Synthesis

Reactions

  1. Chiral catalyst used for the enantioselective formation of cyclopropanes from the reaction of aryls with styryl diazoacetates.
  2. Chiral catalyst used for the asymmetric synthesis of bicyclo[1.1.0]butane rings via the rhodium-catalyzed decomposition of 2-diazo-5-arylpent-4-enoates.
  3. Reaction of vinyldiazoacetates with nitrones to form 2.5-dihydroisooxazoles, 

Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4Supplier

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