METHYL PHENYLPROPIOLATE Chemical Properties

Melting point:

26°C

Boiling point:

109-112 °C/2 mmHg (lit.)

Density 

1.086 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.5590(lit.)

Flash point:

>230 °F

storage temp. 

Inert atmosphere,Room Temperature

form 

Liquid After Melting

color 

Clear colorless to pale yellow

BRN 

472813

InChIKey

JFGWPXKGINUNDH-UHFFFAOYSA-N

CAS DataBase Reference

4891-38-7(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/38

Safety Statements 

26-36

WGK Germany 

3

HS Code 

29163900

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

METHYL PHENYLPROPIOLATE Usage And Synthesis

Chemical Properties

clear colorless to pale yellow liquid

Uses

Methyl phenylpropiolate may be used in the synthesis of:

• bicyclohexadienes
• cis-methyl cinnamate
• (E)-alkyl 3-(dialkoxyphosphoryl)-3-phenylacrylate derivatives

Synthesis Reference(s)

The Journal of Organic Chemistry, 52, p. 4859, 1987 DOI: 10.1021/jo00231a007
Tetrahedron Letters, 21, p. 849, 1980 DOI: 10.1016/S0040-4039(00)71522-X

General Description

Organoiron carbonyl complexes are obtained by reacting methyl phenylpropiolate with Fe₂(CO)₉.

METHYL PHENYLPROPIOLATE(4891-38-7)Related Product Information

• METHYL PHENYLPROPIOLATE
• ETHYL PHENYLPROPIOLATE
• Methyl propionate
• Phenylpropiolic acid
• Methyl propiolate
• Propiolic Acid
• P-TOLYL-PROPYNOIC ACID ETHYL ESTER
• (4-METHOXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• (3-TRIFLUOROMETHYL-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• (3-NITRO-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• M-TOLYL-PROPYNOIC ACID ETHYL ESTER
• (3-CHLORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• (4-CHLORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• (4-TRIFLUOROMETHYL-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• (3-METHOXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• (3-FLUORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• (4-FLUORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER
• (4-HYDROXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER