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B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE

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B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Basic information

Product Name:
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE
Synonyms:
  • R-ALPINE-BORANE(R)
  • B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE
  • (R)-B-isopinocampheyl-9-borabicyclo[3.3.1]nonane
  • R-2,7,7-trimethylnorpinanborabicyclo(3.3.1)nonane
  • R-alpine-borane (0.5M soln. in thf)
  • R-Alpine-Borane? (R)-2,6,6-trimethyl-4-(9-borabicyclo[3.3.1]nonan-9-yl)bicyclo[3.1.1]heptane
  • R-ALPINE-BORANE
  • R-ALPINE-BORANE 97%
CAS:
73624-47-2
MF:
C18H31B
MW:
258.25
Product Categories:
  • API intermediates
Mol File:
73624-47-2.mol
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B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Chemical Properties

Boiling point:
>55 °C(lit.)
alpha 
-3 º (NEAT)
Density 
0.896 g/mL at 25 °C
Flash point:
1 °F
optical activity
[α]21/D -22°, c = 12 in THF
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Safety Information

Hazard Codes 
F,Xn
Risk Statements 
11-19-22-36/37/38-17-40-36/37
Safety Statements 
16-26-27-36/37/39-24-6-36/37
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
HazardClass 
4.3
PackingGroup 
III

MSDS

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B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Usage And Synthesis

Uses

R-Alpine-Borane? solution may be used to prepare:

  • (R)-5-(Benzyloxy)pent-3-y-2-ol, an intermediate for the stereoselective total synthesis of (-)-stagonolide D.
  • (R)-1-(p-Tolyl)-1-pentyn-3-ol, an intermediate for the enatioselective synthesis of (R)-incrustoporin.
  • N-(tert-Butyloxycarbonyl)-(4S)-[4-2H]-1-L-homoserine tert-butyl ester, an intermediate for synthesizing (4S)-[4-2H]-L-homoserine.

General Description

R-Alpine-Borane? is a chiral reducing agent, synthesized from (+)-α-pinene via hydroboration.

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANESupplier

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