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Silver mesylate

Basic information Safety Supplier Related

Silver mesylate Basic information

Product Name:
Silver mesylate
Synonyms:
  • SMS
  • SILVER MESYLATE
  • SILVER METHANESULFONATE
  • methanesulfonicacid,silver(1+)salt
  • METHANESULFONIC ACID, SILVER SALT
  • METHYLSULFONIC ACID SILVER SALT
  • methanesulfonicacid,silver(1++)salt
  • silver methanesulphonate
CAS:
2386-52-9
MF:
CH3AgO3S
MW:
202.97
EINECS:
219-199-2
Product Categories:
  • Ag
  • Organic-metal salt
Mol File:
2386-52-9.mol
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Silver mesylate Chemical Properties

Melting point:
252-256 °C (lit.)
Density 
1.405 at 20℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
color 
White to beige or light gray
PH
1 at 20℃ and 10g/L
Water Solubility 
Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hexane and methylcyclopentane.
Sensitive 
Light Sensitive
InChIKey
MLKQJVFHEUORBO-UHFFFAOYSA-M
Surface tension
77.8mN/m at 1g/L and 20℃
Dissociation constant
1.9 at 20℃
CAS DataBase Reference
2386-52-9(CAS DataBase Reference)
EPA Substance Registry System
Methanesulfonic acid, silver(1+) salt (2386-52-9)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-36/37/39-22
RIDADR 
1759
WGK Germany 
3
RTECS 
PB2685000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28432900

MSDS

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Silver mesylate Usage And Synthesis

Chemical Properties

white to beige or light grey crystalline powder

Uses

Gold Catalysts—21st Century'Gold Rush' Catalyst for: .Heterocyclization reactions . CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,?-unsaturated ketones and esters

Uses

Silver methanesulfonate is used as a catalyst for heterocyclization reactions. Further, it is used in the synthesis of unsaturated ketones and esters.

Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of SO,. See also SULFONATES and SILVER COMPOUNDS

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