Methyl tiglate Chemical Properties

Melting point:

37.22°C (estimate)

Boiling point:

137-138 °C758 mm Hg(lit.)

Density 

0.95 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.436(lit.)

Flash point:

95 °F

storage temp. 

Flammables area

form 

clear liquid

color 

Colorless to Almost colorless

Odor

at 10.00 % in dipropylene glycol. ethereal rum

Odor Type

ethereal

Water Solubility 

Soluble in alcohol, water 3813 mg/L @ 25°C (est).

Merck 

14,9433

BRN 

1720455

Stability:

Stable. Flammable. Incompatible with strong oxidising agents.

LogP

1.869 (est)

CAS DataBase Reference

6622-76-0(CAS DataBase Reference)

NIST Chemistry Reference

Methyl tiglate(6622-76-0)

EPA Substance Registry System

2-Butenoic acid, 2-methyl-, methyl ester, (2E)- (6622-76-0)

Safety Information

Risk Statements 

10

Safety Statements 

16

RIDADR 

UN 3272 3/PG 3

WGK Germany 

2

RTECS 

EM9254600

TSCA 

Yes

HS Code 

2915.60.5000

HazardClass 

3

PackingGroup 

III

MSDS

• Language:English Provider:Methyl 2-methylcrotonate
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Methyl tiglate Usage And Synthesis

Chemical Properties

colourless liquid

Uses

Methyl Tiglate is a useful reactant in elaboration of conjugagted alkenes initiated by insertion into a vinylic C-H bond.

Definition

ChEBI: Methyl tiglate is a fatty acid ester.

Synthesis Reference(s)

Journal of the American Chemical Society, 108, p. 3016, 1986 DOI: 10.1021/ja00271a034

Methyl tiglate(6622-76-0)Related Product Information

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