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2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl

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2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Basic information

Product Name:
2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl
Synonyms:
  • 2-DIMETHYLAMINO-2'-(DIPHENYLPHOSPHINO)BIPHENYL
  • 2-(DIPHENYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)BIPHENYL
  • 2-Diphenylphosphino-2
  • PhDave-Phos 97%
  • PhDavePhos
  • 2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl,98%
  • (N,N-DIMETHYLAMINO)BIPHENYL
  • [1,1''-BIPHENYL]-2-AMINE, 2''-(DIPHENYLPHOSPHINO)-N,N-DIMETHYL-
CAS:
240417-00-9
MF:
C26H24NP
MW:
381.45
EINECS:
607-309-5
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Phosphines
  • Biphenyl & Diphenyl ether
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts
Mol File:
240417-00-9.mol
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2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Chemical Properties

Melting point:
126-128 °C
Boiling point:
514.6±43.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
pka
4.96±0.18(Predicted)
form 
Powder, Crystals, Crystalline Powder and/or Chunks
color 
White to yellow
Water Solubility 
insoluble
InChIKey
JGFXUYLYPITYGR-UHFFFAOYSA-N
CAS DataBase Reference
240417-00-9
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-36/37/39
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29310099

MSDS

  • Language:English Provider:ACROS
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2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Usage And Synthesis

Reaction

  1. Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of aryl bromides.
  2. Ligand used for the Cu-catalyzed phosphorylation of alcohols.
  3. Ligand for Pd-catalyzed C-H benzylation.
  4. Ligand for palladium-catalyzed [4 + 2] benzannulation reaction.

Chemical Properties

white to yellow powder, crystals, crystalline

Uses

suzuki reaction

2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenylSupplier

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