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6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE

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6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE Basic information

Product Name:
6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE
Synonyms:
  • MELIBIOSE MONOHYDRATE
  • D(+)-MELIBIOSE MONOHYDRATE
  • D-MELIBIOSE MONOHYDRATE
  • ALPHA-D-(+)-MELIBIOSE MONOHYDRATE
  • MELIBIOSE MONOHYDRATE FOR BIOCHEMISTRY 98+%
  • D-(+)-MELIBIOSE MONOHYDRATE FOR MICROBIOLOGY 99+%
  • D (+ )MELIBIOSE FOR BACTERIOLOGY
  • D(+)-Melibiose monohydrate, 99+%
CAS:
66009-10-7
MF:
C12H24O12
MW:
360.31
EINECS:
209-568-6
Mol File:
66009-10-7.mol
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6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE Chemical Properties

Melting point:
176-181 °C
solubility 
H2O: 0.1 g/mL, clear, colorless
form 
Crystalline Powder
color 
White
Water Solubility 
Soluble in water
Merck 
14,5820
CAS DataBase Reference
66009-10-7
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Safety Information

Safety Statements 
24/25
WGK Germany 
3
3-10
HS Code 
29389090

MSDS

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6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE Usage And Synthesis

Chemical Properties

white odorless crystalline powder

Purification Methods

Melibiose crystallises as a hydrate from water or aqueous EtOH. The anomer is obtained by recrystallising 1g from a mixture of 0.35mL of H2O and 0.2mL of EtOH. It crystallises easily with m 179o and mutarotates from [] D 20 +166o to +142.3o (220minutes, c 4, H2O). Crystallisation from MeOH gives the anhydrous form which hydrates to the monohydrate in air. The anomer dihydrate m 85-86o mutarotates from [] D 20 +123.5o to +143.1o (c 4, H2O for anhydrous). [Fletcher & Diehl J Am Chem Soc 74 5774 1952, Beilstein 1 7 III/IV 3075, 17/7 V 206.]

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6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE(66009-10-7)Related Product Information