Diphenyliodonium hexafluorophosphate Chemical Properties

Melting point:

140-144 °C(lit.)

storage temp. 

Keep in dark place,Inert atmosphere,Room temperature

solubility 

Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.

form 

Crystalline

color 

White to Almost white

Sensitive 

Light Sensitive

BRN 

4343861

InChI

InChI=1S/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-7(2,3,4,5)6/h1-10H;/q+1;-1

InChIKey

DSSRLRJACJENEU-UHFFFAOYSA-N

SMILES

[I+](C1C=CC=CC=1)C1C=CC=CC=1.[P+5]([F-])([F-])([F-])([F-])([F-])[F-]

CAS DataBase Reference

58109-40-3(CAS DataBase Reference)

EPA Substance Registry System

Iodonium, diphenyl-, hexafluorophosphate(1-) (58109-40-3)

Safety Information

Hazard Codes 

C,Xi

Risk Statements 

34

Safety Statements 

26-36/37/39-45

RIDADR 

UN 1759 8/PG 3

WGK Germany 

3

F 

8-10-21

Hazard Note 

Irritant

TSCA 

Yes

HazardClass 

6.1

PackingGroup 

III

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Diphenyliodonium hexafluorophosphate Usage And Synthesis

Uses

Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

Diphenyliodonium hexafluorophosphate(58109-40-3)Related Product Information

• Diphenyl diselenide
• O-Diphenylphosphinylhydroxylamine
• tert-Butylchlorodiphenylsilane
• Potassium hexafluorophosphate
• Chlorodiphenylphosphine
• Diphenylmethane
• Sodium hexafluorophosphate
• Lithium hexafluorophosphate
• Biphenyl
• Bis(4-methylphenyl)iodonium hexafluorophosphate
• Bis(4-tert-butylphenyl)iodonium hexafluorophosphate
• Hexafluorophosphate
• DIPHENYLIODONIUM IODIDE
• Hexafluorophosphoric acid
• diphenyliodonium hexafluorophosphate(1-) I-oxide
• Diphenyliodonium hexafluorophosphate