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Diphenyliodonium hexafluorophosphate

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Diphenyliodonium hexafluorophosphate Basic information

Product Name:
Diphenyliodonium hexafluorophosphate
Synonyms:
  • iodonium diphenyl hexafluorophosphate
  • DIHP
  • DIPHENYLIODINIUM HEXAFLUOROPHOSPHATE
  • DIPHENYLIODONIUM HEXAFLUOROPHOSPHATE
  • DIHFP
  • diphenyliodoniuM hexafluorophosphate(V)
  • DPIHFP
  • Iodonium,diphenyl-,hexafluorophosphate(1-)(1:1)
CAS:
58109-40-3
MF:
C12H10F6IP
MW:
426.08
EINECS:
261-134-5
Product Categories:
  • Diphenyliodonium Compounds
  • Functional Materials
  • Hypervalent Iodine Compounds
  • Iodonium Sulfonium & Oxonium Compounds
  • Photopolymerization Initiators
  • Synthetic Organic Chemistry
  • Cationic PhotoinitiatorsMicro/Nanoelectronics
  • FluoridesSelf Assembly&Contact Printing
  • Electronic Chemicals
  • Organic Photoinitiators
  • Photoacid Generators (PAGs)
  • Hypervalent Iodine
  • Oxidation
  • Synthetic Reagents
  • Photoresists
  • Polymerization Initiators
Mol File:
58109-40-3.mol
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Diphenyliodonium hexafluorophosphate Chemical Properties

Melting point:
140-144 °C(lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.
form 
Crystalline
color 
White to Almost white
Sensitive 
Light Sensitive
BRN 
4343861
CAS DataBase Reference
58109-40-3(CAS DataBase Reference)
EPA Substance Registry System
Iodonium, diphenyl-, hexafluorophosphate(1-) (58109-40-3)
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Safety Information

Hazard Codes 
C,Xi
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 1759 8/PG 3
WGK Germany 
3
8-10-21
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29319090

MSDS

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Diphenyliodonium hexafluorophosphate Usage And Synthesis

Uses

Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

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