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Tetrabutylammonium azide

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Tetrabutylammonium azide Basic information

Product Name:
Tetrabutylammonium azide
Synonyms:
  • TETRA-N-BUTYLAMMONIUM AZIDE
  • TETRABUTYLAMMONIUM AZIDE
  • n,n,n-tributyl-1-butanaminiuazide
  • N,N,N-Tributyl-1-butanaminium azide
  • Tetra-n-butylammonium azide, 90+%
  • Tetrabutylammonium nitride
  • 1-Butanaminium, N,N,N-tributyl-, azide
  • 1-Butanaminium, N,N,N-tributyl-, azide (1:1)
CAS:
993-22-6
MF:
C16H36N4
MW:
284.48
Product Categories:
  • Ammonium Polyhalides, etc. (Quaternary)
  • Quaternary Ammonium Compounds
  • Azidation/Diazo TransferChemical Ligation
  • Azide Sources
  • Click Chemistry
  • C-X Bond Formation (Non-Halogen)
  • Synthetic Reagents
Mol File:
993-22-6.mol
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Tetrabutylammonium azide Chemical Properties

Melting point:
84-88 °C (lit.)
storage temp. 
2-8°C
Water Solubility 
Soluble in water
form 
powder to crystal
color 
White to Light yellow
Sensitive 
Hygroscopic
CAS DataBase Reference
993-22-6
EPA Substance Registry System
1-Butanaminium, N,N,N-tributyl-, azide (993-22-6)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
11-50/53-36/37/38-32-25
Safety Statements 
15-36/37/39-45-61-60-26
RIDADR 
1325
WGK Germany 
3
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29239000
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Tetrabutylammonium azide Usage And Synthesis

Uses

Tetrabutylammonium azide can be used as a reagent for the synthesis of:

  • Heteroarylannulated bicyclic morpholines
  • Cyanimide-based inhibitors of cathepsin C
  • Trimethylene carbonate
  • Aerobic oxidative transformation of primary azides to nitriles
  • Substitution reactions at tetracoordinate boron


It is also used as a catalyst for cyclic carbonate formation.

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