(+)-Dimethyl L-tartrate
(+)-Dimethyl L-tartrate Basic information
- Product Name:
- (+)-Dimethyl L-tartrate
- Synonyms:
-
- Butanedioic acid, 2,3-dihydroxy- [R-(R*,R*)]-, dimethyl ester
- Dimethyl (2R,3R)-2,3-dihydroxybutanedioate
- (+)-Tartaric acid dimethyl
- (2R,3R)-2,3-Dihydroxybutanedioic acid dimethyl ester
- L-(+)-Tartaric acid dimethyl
- (+)-Dimethyl L-tartrate,99%
- L-DiMethyl L-tartrate
- L-(+)-Tartaric acid diMethyl ester, 99%, ee: 99%
- CAS:
- 608-68-4
- MF:
- C6H10O6
- MW:
- 178.14
- EINECS:
- 210-166-8
- Product Categories:
-
- Chiral Compound
- FINE Chemical & INTERMEDIATES
- Chiral Compounds
- chiral
- Chiral Building Blocks
- Esters (Chiral)
- Synthetic Organic Chemistry
- CHIRAL CHEMICALS
- Hydroxy Acids & Deriv.
- Mol File:
- 608-68-4.mol
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(+)-Dimethyl L-tartrate Chemical Properties
- Melting point:
- 57-60 °C (dec.) (lit.)
- alpha
- 21 º (c=10, H2O)
- Boiling point:
- 163 °C/23 mmHg (lit.)
- Density
- 1.238 g/mL at 25 °C (lit.)
- refractive index
- 21 ° (C=2.5, H2O)
- Flash point:
- >230 °F
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- 11.44±0.20(Predicted)
- form
- Crystals
- color
- White
- Specific Gravity
- 1.3046 (50/4℃)
- optical activity
- [α]22/D +21°, c = 2.5 in H2O
- Water Solubility
- Soluble in water.
- BRN
- 1726256
- LogP
- -1.350 (est)
- CAS DataBase Reference
- 608-68-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Butanedioic acid, 2,3-dihydroxy- [R-(R*,R*)]-, dimethyl ester(608-68-4)
- EPA Substance Registry System
- Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, dimethyl ester (608-68-4)
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 24/25-36/37-26
- WGK Germany
- 3
- TSCA
- Yes
- HS Code
- 29181300
MSDS
- Language:English Provider:L-(+)-Tartaric acid dimethyl ester
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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(+)-Dimethyl L-tartrate Usage And Synthesis
Chemical Properties
Colorless to light yellow liqui
Uses
(+)-Dimethyl L-tartrate is used as a starting reagent in the synthesis of (+)-Monomorine I, a pyrrolidine-based alkaloid that is a trail pheromone of the Pharaoh’s ant (Monomorium pharaonis).
Uses
(+)-Dimethyl L-tartrate can react with sulfur tetrafluoride to form dimethyl meso-2,3-difluorosuccinate.
It may be used in the synthesis of the following chiral ligands for use in asymmetric synthesis:
- (2R, 3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol
- (-)-(4S,5R)-4-(2-pyridyl)-5-(diphenylphosphino)methyl-2,2-dimethyl-1,3-dioxolane (PYDIPHOS)
- (4R,5R)-α,α,α′,α′-2,2-hexaphenyl-4,5-dimethanol-1,3-dioxolane
(+)-Dimethyl L-tartrateSupplier
Chengdu Likai Chiral Tech Co., LTD. Gold
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(+)-Dimethyl L-tartrate(608-68-4)Related Product Information
- L(+)-Tartaric acid
- Dimethyl oxalate
- N,N-Dimethylformamide
- Dimethyl phosphite
- Dimethyl ether
- D(-)-Tartaric acid
- Dimethyl adipate
- Dimethyl malonate
- DL-Tartaric acid
- Dimethyl carbonate
- Dimethyl sulfate
- Dimethyl phthalate
- ETHANE
- Tylosin tartrate
- Dimethyl fumarate
- Dimethyl sulfoxide
- L(+)-Diethyl L-tartrate
- 2,3-Di-O-para-toluoyl-D-tartaric acid