Borane-trimethylamine complex
Borane-trimethylamine complex Basic information
- Product Name:
- Borane-trimethylamine complex
- Synonyms:
-
- Borane trimethylamine complex,Trimethylamine borane
- Borane-triMethylaMine coMplex, 98% 100GR
- Borane triMethylaMine coMplex 97%
- NSC 10220
- NSC 145941
- NSC 53323
- Borane - Trimethylamine Complex TMAB
- BorancetriMethylaMine coMplex
- CAS:
- 75-22-9
- MF:
- C3H12BN
- MW:
- 72.95
- EINECS:
- 200-850-4
- Product Categories:
-
- B (Classes of Boron Compounds)
- Boranes
- Reduction
- Synthetic Organic Chemistry
- Mol File:
- 75-22-9.mol
Borane-trimethylamine complex Chemical Properties
- Melting point:
- 92-94 °C(lit.)
- Boiling point:
- 172 °C(lit.)
- Density
- 0.81
- Flash point:
- 64°C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder, Crystals and/or Chunks
- color
- White
- Water Solubility
- decomposes
- Sensitive
- Moisture Sensitive
- BRN
- 3905060
- InChIKey
- KQVSXUGMDCAISO-UHFFFAOYSA-N
- CAS DataBase Reference
- 75-22-9(CAS DataBase Reference)
- NIST Chemistry Reference
- Boron, (N,N-dimethylmethanamine)trihydro-(75-22-9)
- EPA Substance Registry System
- Boron, (N,N-dimethylmethanamine)trihydro-, (T-4)- (75-22-9)
Safety Information
- Hazard Codes
- F,Xn,Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 14-16-26-36-36/37/39-33-39
- RIDADR
- UN 1325 4.1/PG 2
- WGK Germany
- 3
- RTECS
- PA0525000
- F
- 10-21
- TSCA
- Yes
- HazardClass
- 4.1
- PackingGroup
- II
- HS Code
- 29420000
MSDS
- Language:English Provider:Borane-trimethylamine complex
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
Borane-trimethylamine complex Usage And Synthesis
Chemical Properties
white crystalline powder
Uses
Reducing agent for the preparation of plate-type palladium-zinc oxide catalys, reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents. Catalyst for regioselective reductive opening of benzylidene acetal glycosides and polarity reversal.
Purification Methods
It is sublimed using equipment described in Burg and Schlesinger [J Am Chem Soc 59 780 1937I]. Its vapour pressure is 86mm at 100o. It forms colourless hexagonal crystals varying from needles to short lumps, which are slightly soluble in H2O (1.48% at 30o), EtOH (1%), hexane (0.74%) but very soluble in Et2O, *C6H6 and AcOH. It is stable at 125o. [Burg & Schlesinger J Am Chem Soc 59 780 1937, Brown et al. J Am Chem Soc 104 325 1942, Beilstein 4 IV 140.]
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Borane-trimethylamine complex(75-22-9)Related Product Information
- Borane-tetrahydrofuran complex
- Lambda Cyhalotric Acid
- (Trifluoromethyl)trimethylsilane
- BORANE-N,N-DIISOPROPYLETHYLAMINE COMPLEX
- 4-METHYL-MORPHOLINEBORANE
- Borane ammonia complex
- BORANE-ISOAMYL SULFIDE COMPLEX
- Trimethylamine hydrochloride
- Trimethylamine
- trimethylamine oxide
- 1,4-Butanediol dimethacrylate
- INTERMEDIATES
- Trifluoromethanesulfonamide
- Trifluoromethanesulfonic anhydride
- Zinc trifluoromethanesulfonate
- Borane-triethylamine complex
- trichloro(N,N-dimethyloctylamine)boron
- (Methoxycarbonyl)borane trimethylamine complex, Trimethylamine-carbomethoxyborane